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1,5,7-Triazabicyclo[4.4.0]dec-5-ene - 98%, high purity , CAS No.5807-14-7
Basic Description Synonyms 5807-14-7|1,5,7-Triazabicyclo[4.4.0]dec-5-ene|1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidine|2,3,4,6,7,8-Hexahydro-1H-pyrimido[1,2-a]pyrimidine|Triazabicyclodecene|1,3,4,6,7,8-Hexahydro-2H-pyrimido(1,2-a)pyrimidine|3,4,6,7,8,9-hexahydro-2H-pyrimido[1, Specifications & Purity 98% Storage Temp Argon charged Shipped In Normal Product Description 1,5,7-triazobicyclic [4.4.0] deca-5-ene, a bicyclic guanidine base, has been found to be an excellent catalyst for Michael Michael type reactions. It can form a 1:1 complex with Lasalitinic acid, and its crystal structure has been studied by X-ray diffraction, FT-IR spectroscopy, and 1H NMR.
Application 1,5,7-triazabicyclic [4.4.0] dec-5-ene can be used as an organic catalyst for ester ammonolysis. It can be used as a catalyst for directly adding P (O) - H bonds (dialkyl phosphites and diphenylphosphates) to various activated olefins. Polymer loaded 1,5,7-triazobicyclic [4.4.0] deca-5-ene (PTBD) can be used as a base and reagent scavenger for the synthesis of aryl ethers from phenols and alkyl or aryl halides.
Names and Identifiers IUPAC Name 3,4,6,7,8,9-hexahydro-2H-pyrimido[1,2-a]pyrimidine INCHI InChI=1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9) InChi Key FVKFHMNJTHKMRX-UHFFFAOYSA-N Canonical SMILES C1CNC2=NCCCN2C1 Isomeric SMILES C1CNC2=NCCCN2C1 WGK Germany 3 PubChem CID 79873 Molecular Weight 139.20 Beilstein 3242 Reaxy-Rn 3242
Chemical and Physical Properties Sensitivity Moisture Sensitive;Air Sensitive Melt Point(°C) 130 °C
Safety and Hazards(GHS) Pictogram(s) GHS05 Signal Danger Hazard Statements H314: Causes severe skin burns and eye damage
H318: Causes serious eye damage
Precautionary Statements P280: Wear protective gloves/protective clothing/eye protection/face protection.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P264+P265: Wash hands [and …] thoroughly after handling. Do not touch eyes.
P305+P354+P338: IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P317: Get emergency medical help.
P302+P361+P354: IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.
P316: Get emergency medical help immediately.
WGK Germany 3 Reaxy-Rn 3242
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