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(−)-1-(9-Fluorenyl)ethyl chloroformate solution - 18mM in acetone, high purity , CAS No.154479-90-0

for chiral derivatization

18mM in acetone

CAS#: 154479-90-0
Formula: C₁₆H₁₃ClO₂
Molecular Weight: 272.73
MDL number: MFCD00043429
PubChem CID: 115102

Item Number

F466381

Grouped product items
SKU	Size	Availability	Price	Qty
F466381-1ml	1ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$724.90

Basic Description

Synonyms	(+)-1-(9H-Fluoren-9-yl)ethyl carbonochloridate \| 1-(9H-fluoren-9-yl)ethyl carbonochloridate \| Carbonochloridic acid, 1-(9H-fluoren-9-yl)ethyl ester, (+)- \| 1-(9-Fluorenyl)ethyl chloroformate \| (-)-1-(9H-Fluoren-9-yl)ethyl carbonochloridate \| FT-0738928 \|
Specifications & Purity	for chiral derivatization, 18mM in acetone
Storage Temp	Store at 2-8°C
Shipped In	Wet ice
Grade	for chiral derivatization
Product Description	Description (-)-1-(9-Fluorenyl)ethyl chloroformate is mostly used as an in-capillary derivatization agent for the separation of amino acid (AA) derivatives by micellar electrokinetic chromatography (MEKC).

Names and Identifiers

IUPAC Name	1-(9H-fluoren-9-yl)ethyl carbonochloridate
INCHI	InChI=1S/C16H13ClO2/c1-10(19-16(17)18)15-13-8-4-2-6-11(13)12-7-3-5-9-14(12)15/h2-10,15H,1H3
InChi Key	SFRVOKMRHPQYGE-UHFFFAOYSA-N
Canonical SMILES	CC(C1C2=CC=CC=C2C3=CC=CC=C13)OC(=O)Cl
Isomeric SMILES	CC(C1C2=CC=CC=C2C3=CC=CC=C13)OC(=O)Cl
WGK Germany	2
PubChem CID	115102
UN Number	1090
Packing Group	II
Molecular Weight	272.73

Flash Point(°F)

-2.2 °F

Flash Point(°C)

-19 °C

Safety and Hazards(GHS)

Pictogram(s)	GHS06, GHS05
Signal	Danger
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H225:Highly Flammable liquid and vapor H336:May cause drowsiness or dizziness
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P330:Rinse mouth. P301+P316:IF SWALLOWED: Get emergency medical help immediately. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	2
Class	3
RIDADR	UN1090-class3-PG2-Acetone，solution

References

1. Radu-Cristian Moldovan,Ede Bodoki,Anne-Catherine Servais,Jacques Crommen,Radu Oprean,Marianne Fillet. (2017-08-02) (+) or (-)-1-(9-fluorenyl)ethyl chloroformate as chiral derivatizing agent: A review.. Journal of chromatography. A, 1513 (1-17). [PMID:28756893]
2. Radu-Cristian Moldovan,Ede Bodoki,Anne-Catherine Servais,Bezhan Chankvetadze,Jacques Crommen,Radu Oprean,Marianne Fillet. (2018-06-19) Capillary electrophoresis-mass spectrometry of derivatized amino acids for targeted neurometabolomics - pH mediated reversal of diastereomer migration order.. Journal of chromatography. A, 1564 (199-206). [PMID:29910088]
3. Radu-Cristian Moldovan,Ede Bodoki,Anne-Catherine Servais,Jacques Crommen,Radu Oprean,Marianne Fillet. (2019-01-15) Selectivity evaluation of phenyl based stationary phases for the analysis of amino acid diastereomers by liquid chromatography coupled with mass spectrometry.. Journal of chromatography. A, 1590 (80-87). [PMID:30639061]
4. Shiro Kato,Yuki Masuda,Morichika Konishi,Tadao Oikawa. (2015-05-20) Enantioselective analysis of D- and L-amino acids from mouse macrophages using high performance liquid chromatography.. Journal of pharmaceutical and biomedical analysis, 116 (101-104). [PMID:25982753]
5. Radu-Cristian Moldovan,Ede Bodoki,Timea Kacsó,Anne-Catherine Servais,Jacques Crommen,Radu Oprean,Marianne Fillet. (2016-08-25) A micellar electrokinetic chromatography-mass spectrometry approach using in-capillary diastereomeric derivatization for fully automatized chiral analysis of amino acids.. Journal of chromatography. A, 1467 (400-408). [PMID:27554025]

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(−)-1-(9-Fluorenyl)ethyl chloroformate solution - 18mM in acetone, high purity , CAS No.154479-90-0

Basic Description

Names and Identifiers

Certificates

Certificate of Analysis(COA)

Chemical and Physical Properties

Safety and Hazards(GHS)

Related Documents

References

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