| SKU | Size | Availability | Price | Qty |
|---|---|---|---|---|
| E467121-25g | 25g | Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding. | $324.90 |
| Synonyms | FT-0647411 | 1-ethylpiperidine;phosphonous acid | 1-ethylpiperidine phosphonite | AKOS015856620 | DTXSID50467482 | 1-Ethylpiperidine hypophosphite, 95% | 1-Ethylpiperidine hypophosphite | 1-Ethylpiperidinehypophosphite |
|---|---|
| Specifications & Purity | ≥95% |
| Storage Temp | Store at 2-8°C |
| Shipped In | Wet ice |
| Product Description | 1-Ethylpiperidine hypophosphite promotes the carbon-carbon bond forming radical reactions in both aqueous and organic media. EPHP plays an important role of a good chain carrier during the radical addition ofgem-dihalocompounds to electron-deficient olefins. It has been reported as a suitable radical reducing agent for organic halides.Reagent for:Synthesis of spiroketals via intramolecular iodoetherificationA facile radical cyclization diverted to a rearrangement-cyclization with baseRadical deoxygenationSynthesis of allylic H-phosphinates1-Ethylpiperidine hypophosphite (EPHP) may be used in the following studies:As water-soluble chain carrier for the efficient radical cyclization in water for various hydrophobic substrates.In the main radical-cyclisation step for the synthesis of the phytotoxic metabolite alboatrin and its epimer.Preparation of bifunctional pentafluorophenyl/2,4,6-trichlorophenyl sulfonates.Chemoselective radical reduction of the iodine atom in 1-deoxy-1-halo-1-iodo-alditols. |
| IUPAC Name | 1-ethylpiperidine;phosphonous acid |
|---|---|
| INCHI | InChI=1S/C7H15N.H3O2P/c1-2-8-6-4-3-5-7-8;1-3-2/h2-7H2,1H3;1-3H |
| InChi Key | BNCZSWZTYPTERM-UHFFFAOYSA-N |
| Canonical SMILES | CCN1CCCCC1.OPO |
| Isomeric SMILES | CCN1CCCCC1.OPO |
| WGK Germany | 3 |
| PubChem CID | 11492035 |
| Molecular Weight | 179.2 |
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| Flash Point(°F) | 132.8 °F |
|---|---|
| Flash Point(°C) | 56 °C |
| Pictogram(s) | GHS07, GHS02 |
|---|---|
| Signal | Warning |
| Hazard Statements | H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H302:Harmful if swallowed H228:Flammable solid H312:Harmful in contact with skin H332:Harmful if inhaled |
| Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P317:Get emergency medical help. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell. |
| WGK Germany | 3 |
| RIDADR | UN1325-class4.1-PG2-Flammablesolids，organic，n.o.s.，HI:all |
| 1. Y Kita,H Nambu,N G Ramesh,G Anilkumar,M Matsugi. (2001-05-12) A novel and efficient methodology for the C-C bond forming radical cyclization of hydrophobic substrates in water.. Organic letters, 3 ((8)): (1157-1160). [PMID:11348183] |
| 2. Urara Hasegawa,Naoya Tateishi,Hiroshi Uyama,André J van der Vlies. (2015-06-24) Hydrolysis-Sensitive Dithiolethione Prodrug Micelles.. Macromolecular bioscience, 15 ((11)): (1512-1522). [PMID:26102371] |
| 3. Yunjiang Jiang,Wan Zheng,Liangju Kuang,Hairong Ma,Hongjun Liang. (2017-08-02) Hydrophilic Phage-Mimicking Membrane Active Antimicrobials Reveal Nanostructure-Dependent Activity and Selectivity.. ACS infectious diseases, 3 ((9)): (676-687). [PMID:28758395] |
