Click Here for 5% Off Your First Aladdin Purchase!

1-Hexadecanethiol - >97.0%(GC), high purity , CAS No.2917-26-2

  • ≥97%(GC)
Item Number
H140650
Grouped product items
SKUSizeAvailabilityPrice Qty
H140650-1ml
1ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$9.90
H140650-5ml
5ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$10.90
H140650-25ml
25ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$15.90
H140650-100ml
100ml
In stock
$39.90
H140650-500ml
500ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$133.90
View related series
Material synthetic block Thiols

Basic Description

Synonyms1-HEXADECANETHIOL|hexadecane-1-thiol|2917-26-2|Hexadecanethiol|Cetyl mercaptan|n-Hexadecanethiol|n-Hexadecyl mercaptan|Hexadecyl mercaptan|1-Cetanethiol|QR98QIO1QL|1-Hexadecane-d33-thiol|NSC-57866|hexadecylthiol|n-hexadecylthiol|1-Mercaptohexadecane|21895
Specifications & Purity>97.0%(GC)
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

1-Hexadecanethiol is used to prepare thiol-functionalized 1.5 nm gold nanoparticles via a ligand exchange process with triphenylphosphine-stabilized nanoparticles. Used in the formation of hydrophobic self-assembled monolayers (SAMs). Due to the length of the alkane chain, the resulting monolayer is highly ordered.
Used in the study of nanoparticles and self-assembled monolayers.

Names and Identifiers

IUPAC Name hexadecane-1-thiol
INCHI InChI=1S/C16H34S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h17H,2-16H2,1H3
InChi Key ORTRWBYBJVGVQC-UHFFFAOYSA-N
Canonical SMILES CCCCCCCCCCCCCCCCS
Isomeric SMILES CCCCCCCCCCCCCCCCS
WGK Germany 3
PubChem CID 18015
UN Number 3334(international aviation)
Molecular Weight 258.51
Beilstein 1748495

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

10 results found

Lot NumberCertificate TypeDateItem
L2311122Certificate of AnalysisNov 24, 2023 H140650
L2311123Certificate of AnalysisNov 24, 2023 H140650
L2311124Certificate of AnalysisNov 24, 2023 H140650
A2305525Certificate of AnalysisNov 25, 2022 H140650
A2305530Certificate of AnalysisNov 25, 2022 H140650
A2305531Certificate of AnalysisNov 25, 2022 H140650
A2305535Certificate of AnalysisNov 25, 2022 H140650
A2305538Certificate of AnalysisNov 25, 2022 H140650
A2305540Certificate of AnalysisNov 25, 2022 H140650
J1816066Certificate of AnalysisAug 08, 2022 H140650

Chemical and Physical Properties

SolubilitySoluble in methanol, benzene, ether, acetone and ethyl acetate. Not miscible or difficult to mix in water.
SensitivityAir Sensitive.
Refractive Index1.462
Flash Point(°F)215.6 °F
Flash Point(°C)102 °C
Boil Point(°C)189 °C/10 mmHg
Melt Point(°C)18-20℃

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H319:Causes serious eye irritation

H413:May cause long lasting harmful effects to aquatic life

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P501:Dispose of contents/container to ...

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

WGK Germany 3
Class 9

Related Documents

References

1. J Christopher Love,Daniel B Wolfe,Michael L Chabinyc,Kateri E Paul,George M Whitesides.  (2002-02-21)  Self-assembled monolayers of alkanethiolates on palladium are good etch resists..  Journal of the American Chemical Society,  124  ((8)): (1576-1577).  [PMID:11853422]
2. L Svobodová,M Snejdárková,K Tóth,R E Gyurcsanyi,T Hianik.  (2004-04-28)  Properties of mixed alkanethiol-dendrimer layers and their applications in biosensing..  Bioelectrochemistry (Amsterdam, Netherlands),  63  ((1-2)): (285-289).  [PMID:15110289]
3. X Torrelles,E Barrena,C Munuera,J Rius,S Ferrer,C Ocal.  (2004-10-06)  New insights in the c(4 x 2) reconstruction of hexadecanethiol on Au(111) revealed by grazing incidence X-ray diffraction..  Langmuir : the ACS journal of surfaces and colloids,  20  ((21)): (9396-9402).  [PMID:15461535]
4. Mohammad R Shadnam,Sean E Kirkwood,Robert Fedosejevs,A Amirfazli.  (2005-04-20)  Direct patterning of self-assembled monolayers on gold using a laser beam..  Langmuir : the ACS journal of surfaces and colloids,  20  ((7)): (2667-2676).  [PMID:15835135]
5. Han-Cheol Kwon,Andrew A Gewirth.  (2006-07-21)  AFM force measurements between SAM-modified tip and SAM-modified substrate in alkaline solution..  The journal of physical chemistry. B,  109  ((20)): (10213-10222).  [PMID:16852238]
6. Hiroshi Yamada,Mitsuko Ogata,Tohru Koike.  (2006-08-23)  Scanning electrochemical microscope observation of defects in a hexadecanethiol monolayer on gold with shear force-based tip-substrate positioning..  Langmuir : the ACS journal of surfaces and colloids,  22  ((18)): (7923-7927).  [PMID:16922585]
7. Shuhong Liu,Jeffrey B-H Tok,Jason Locklin,Zhenan Bao.  (2006-12-29)  Assembly and alignment of metallic nanorods on surfaces with patterned wettability..  Small (Weinheim an der Bergstrasse, Germany),  ((12)): (1448-1453).  [PMID:17193004]
8. Catarina Gonçalves,José A Martins,Francisco M Gama.  (2007-02-13)  Self-assembled nanoparticles of dextrin substituted with hexadecanethiol..  Biomacromolecules,  ((2)): (392-398).  [PMID:17291062]
9. Kishan Rijal,Raj Mutharasan.  (2007-05-08)  Method for measuring the self-assembly of alkanethiols on gold at femtomolar concentrations..  Langmuir : the ACS journal of surfaces and colloids,  23  ((12)): (6856-6863).  [PMID:17480109]
10. Louis Hodgson,Eugene W L Chan,Klaus M Hahn,Muhammad N Yousaf.  (2007-07-13)  Combining surface chemistry with a FRET-based biosensor to study the dynamics of RhoA GTPase activation in cells on patterned substrates..  Journal of the American Chemical Society,  129  ((30)): (9264-9265).  [PMID:17625860]
11. Yue Li,Cuncheng Li,Sung Oh Cho,Guotao Duan,Weiping Cai.  (2007-08-21)  Silver hierarchical bowl-like array: synthesis, superhydrophobicity, and optical properties..  Langmuir : the ACS journal of surfaces and colloids,  23  ((19)): (9802-9807).  [PMID:17705510]
12. Jasbir N Patel,Bozena Kaminska,Bonnie Gray,Byron D Gates.  (2007-11-16)  Effect of self-assembled monolayers (SAMs) in binding glucose oxidase for electro-enzymatic glucose sensor with gold electrodes..  Conference proceedings : ... Annual International Conference of the IEEE Engineering in Medicine and Biology Society. IEEE Engineering in Medicine and Biology Society. Annual Conference,  2007  (2677-2680).  [PMID:18002546]
13. Gaoshan Jing,Susan F Perry,Svetlana Tatic-Lucic.  (2010-06-24)  Precise cell patterning using cytophobic self-assembled monolayer deposited on top of semi-transparent gold..  Biomedical microdevices,  12  ((5)): (935-948).  [PMID:20571865]
14. Sílvia A Ferreira,Paula Pereira,Paula Sampaio,Paulo J G Coutinho,Francisco M Gama.  (2011-06-11)  Supramolecular assembled nanogel made of mannan..  Journal of colloid and interface science,  361  ((1)): (97-108).  [PMID:21658701]
15. Chang-Beom Kim,Honggu Chun,JaeHun Chung,Kwang Ho Lee,Jeong Hoon Lee,Ki-Bong Song,Sang-Hoon Lee.  (2011-08-05)  In situ curing of sliding SU-8 droplet over a microcontact printed pattern for tunable fabrication of a polydimethylsiloxane nanoslit..  Analytical chemistry,  83  ((18)): (7221-7226).  [PMID:21812411]
16. Hyewon Kim,Randy P Carney,Javier Reguera,Quy K Ong,Xiang Liu,Francesco Stellacci.  (2012-05-11)  Synthesis and characterization of Janus gold nanoparticles..  Advanced materials (Deerfield Beach, Fla.),  24  ((28)): (3857-3863).  [PMID:22573487]
17. Matthew K Strulson,Joshua A Maurer.  (2012-09-01)  Mechanistic insight into patterned supported lipid bilayer self-assembly..  Langmuir : the ACS journal of surfaces and colloids,  28  ((38)): (13652-13659).  [PMID:22935058]
18. Chunyan Xing,Haiyan Qiao,Yongjun Li,Xi Ke,Zhe Zhang,Bailin Zhang,Jilin Tang.  (2012-09-08)  Fractal self-assembly of single-stranded DNA on hydrophobic self-assembled monolayers..  The journal of physical chemistry. B,  116  ((38)): (11594-11599).  [PMID:22954149]
19. Tihamér Geyer,Philip Born,Tobias Kraus.  (2012-09-26)  Switching between crystallization and amorphous agglomeration of alkyl thiol-coated gold nanoparticles..  Physical review letters,  109  ((12)): (128302-128302).  [PMID:23005995]
20. Xi Ke,Jilin Tang.  (2013-02-26)  A simple method for fabricating patterned curvilinear microstructures in poly(dimethylsiloxane) by selective wetting..  Chemphyschem : a European journal of chemical physics and physical chemistry,  14  ((5)): (946-951).  [PMID:23436571]
21. Hao Yu,Irena Yzeiri,Binyang Hou,Chiu-Hao Chen,Wei Bu,Petr Vanysek,Yu-Sheng Chen,Binhua Lin,Petr Král,Mark L Schlossman.  (2014-10-08)  Electric Field Effect on Phospholipid Monolayers at an Aqueous-Organic Liquid-Liquid Interface..  The journal of physical chemistry. B,  119  ((29)): (9319-9334).  [PMID:25289837]
22. Christopher G England,M Clarke Miller,Ashani Kuttan,John O Trent,Hermann B Frieboes.  (2015-03-11)  Release kinetics of paclitaxel and cisplatin from two and three layered gold nanoparticles..  European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V,  92  (120-129).  [PMID:25753197]
23. Christopher G England,Justin S Huang,Kurtis T James,Guandong Zhang,André M Gobin,Hermann B Frieboes.  (2015-06-06)  Detection of Phosphatidylcholine-Coated Gold Nanoparticles in Orthotopic Pancreatic Adenocarcinoma using Hyperspectral Imaging..  PloS one,  10  ((6)): (e0129172-e0129172).  [PMID:26046360]
24. Alif Chebbi,Najla Mhiri,Fatma Rezgui,Najoua Ammar,Amina Maalej,Sami Sayadi,Mohamed Chamkha.  (2015-06-19)  Biodegradation of malodorous thiols by a Brevibacillus sp. strain isolated from a Tunisian phosphate factory..  FEMS microbiology letters,  362  ((14)):   [PMID:26085487]
25. Jenny K Hedlund,Amy V Walker.  (2019-05-10)  Polytype control of MoS2 using chemical bath deposition..  The Journal of chemical physics,  150  ((17)): (174701-174701).  [PMID:31067898]
26. Liping Ding,Yanqing Wang,Jinxin Xiong,Huiying Lu,Mingjian Zeng,Peng Zhu,Haiyan Ma.  (2019-12-15)  Plant-Inspired Layer-by-Layer Self-Assembly of Super-Hydrophobic Coating for Oil Spill Cleanup..  Polymers,  11  ((12)):   [PMID:31835501]
27. M N Yousaf,B T Houseman,M Mrksich.  (2001-05-17)  Using electroactive substrates to pattern the attachment of two different cell populations..  Proceedings of the National Academy of Sciences of the United States of America,  98  ((11)): (5992-5996).  [PMID:11353818]
28. Gerd H Woehrle,Leif O Brown,James E Hutchison.  (2005-02-17)  Thiol-functionalized, 1.5-nm gold nanoparticles through ligand exchange reactions: scope and mechanism of ligand exchange..  Journal of the American Chemical Society,  127  ((7)): (2172-2183).  [PMID:15713095]
29. Jialin Wang,Roe-Hoan Yoon.  (2008-06-26)  AFM forces measured between gold surfaces coated with self-assembled monolayers of 1-hexadecanethiol..  Langmuir : the ACS journal of surfaces and colloids,  24  ((15)): (7889-7896).  [PMID:18576609]
30. François Huber,Hans Peter Lang,Martin Hegner,Michel Despont,Ute Drechsler,Christoph Gerber.  (2008-12-03)  Analyzing refractive index changes and differential bending in microcantilever arrays..  The Review of scientific instruments,  79  ((8)): (086110-086110).  [PMID:19044391]
31. Dana M Rosu,Jason C Jones,Julia W P Hsu,Karen L Kavanagh,Dimiter Tsankov,Ulrich Schade,Norbert Esser,Karsten Hinrichs.  (2008-12-25)  Molecular orientation in octanedithiol and hexadecanethiol monolayers on GaAs and Au measured by infrared spectroscopic ellipsometry..  Langmuir : the ACS journal of surfaces and colloids,  25  ((2)): (919-923).  [PMID:19105790]
32. Anastasia Delattre,Stéphanie Pouget,Jean-François Jacquot,Yves Samson,Peter Reiss.  (2010-03-10)  Stable colloidal solutions of high-temperature-annealed L10 FePt nanoparticles..  Small (Weinheim an der Bergstrasse, Germany),  ((8)): (932-936).  [PMID:20213650]
33. Sho Fujii,Katsuaki Kobayashi,Katsuhiko Kanaizuka,Tetsuaki Okamoto,Shoichi Toyabe,Eiro Muneyuki,Masa-Aki Haga.  (2010-06-12)  Observation of DNA pinning at laser focal point on Au surface and its application to single DNA nanowire and cross-wire formation..  Bioelectrochemistry (Amsterdam, Netherlands),  80  ((1)): (26-30).  [PMID:20537962]
34. Ryo Nishikiori,Kotaro Watanabe,Koichi Kato.  (2015-07-15)  Antibody Arrays for Quality Control of Mesenchymal Stem Cells..  ACS applied materials & interfaces,  ((30)): (16828-16836).  [PMID:26172315]
35. Andreas Mark,Nicolas Helfricht,Astrid Rauh,Matthias Karg,Georg Papastavrou.  (2019-09-24)  The Next Generation of Colloidal Probes: A Universal Approach for Soft and Ultra-Small Particles..  Small (Weinheim an der Bergstrasse, Germany),  15  ((43)): (e1902976-e1902976).  [PMID:31544313]

Solution Calculators