Click Here for 5% Off Your First Aladdin Purchase!

2,2,2-Trifluoroethyl methacrylate - contains 100 ppm MEHQ as inhibitor,98%, high purity , CAS No.352-87-4

  • ≥98%
  • contains 100 ppm MEHQ as inhibitor
Item Number
T107432
Grouped product items
SKUSizeAvailabilityPrice Qty
T107432-5ml
5ml
In stock
$9.90
T107432-25ml
25ml
In stock
$22.90
T107432-100ml
100ml
In stock
$77.90
T107432-500ml
500ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$271.90

Basic Description

Synonyms2,2,2-TRIFLUOROETHYL METHACRYLATE|352-87-4|Trifluoroethyl methacrylate|2,2,2-trifluoroethyl 2-methylprop-2-enoate|54802-79-8|2-Propenoic acid, 2-methyl-, trifluoroethyl ester|Methacrylic acid 2,2,2-trifluoroethyl ester|2-Propenoic acid, 2-methyl-, 2,2,2-t
Specifications & Puritycontains 100 ppm MEHQ as inhibitor,98%
Storage TempStore at 2-8°C
Shipped InWet ice
Product Description

2,2,2-Trifluoroethyl methacrylate (TFEMA) is a semifluorinated monomer that can be synthesized from methacryloyl chloride and 2,2,2-trifluoroethanol in presence of triethylamine. Its properties include chemical inertness, good wear resistance and low dielectric constant

TFEMA can be used in the preparation of poly(TFEMA), which can be used in the development of acrylic protective coatings


Names and Identifiers

IUPAC Name 2,2,2-trifluoroethyl 2-methylprop-2-enoate
INCHI InChI=1S/C6H7F3O2/c1-4(2)5(10)11-3-6(7,8)9/h1,3H2,2H3
InChi Key QTKPMCIBUROOGY-UHFFFAOYSA-N
Canonical SMILES CC(=C)C(=O)OCC(F)(F)F
Isomeric SMILES CC(=C)C(=O)OCC(F)(F)F
WGK Germany 2
PubChem CID 9608
UN Number 3272
Molecular Weight 168.11
Reaxy-Rn 4175872

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

27 results found

Lot NumberCertificate TypeDateItem
F2414323Certificate of AnalysisMay 29, 2024 T107432
F2414322Certificate of AnalysisMay 29, 2024 T107432
F2414226Certificate of AnalysisMay 29, 2024 T107432
F2414128Certificate of AnalysisMay 29, 2024 T107432
H2224111Certificate of AnalysisMay 08, 2024 T107432
A2403294Certificate of AnalysisDec 25, 2023 T107432
A2403293Certificate of AnalysisDec 25, 2023 T107432
A2403299Certificate of AnalysisDec 25, 2023 T107432
L2319284Certificate of AnalysisNov 24, 2023 T107432
L2319283Certificate of AnalysisNov 24, 2023 T107432
L2319173Certificate of AnalysisNov 24, 2023 T107432
L2107263Certificate of AnalysisSep 20, 2023 T107432
F2327874Certificate of AnalysisApr 26, 2023 T107432
F2327884Certificate of AnalysisApr 26, 2023 T107432
F23271053Certificate of AnalysisApr 26, 2023 T107432
F2327873Certificate of AnalysisApr 26, 2023 T107432
F2327857Certificate of AnalysisApr 26, 2023 T107432
K2314080Certificate of AnalysisApr 26, 2023 T107432
F2327807Certificate of AnalysisApr 26, 2023 T107432
F23271402Certificate of AnalysisApr 26, 2023 T107432
F23271054Certificate of AnalysisApr 26, 2023 T107432
D2324068Certificate of AnalysisAug 05, 2022 T107432
H2224110Certificate of AnalysisAug 05, 2022 T107432
H2224113Certificate of AnalysisAug 05, 2022 T107432
H2224444Certificate of AnalysisAug 05, 2022 T107432
F2205311Certificate of AnalysisJun 08, 2022 T107432
I1829059Certificate of AnalysisMay 07, 2022 T107432

more

Chemical and Physical Properties

SensitivityHeat and Light Sensitive
Refractive Indexn20/D 1.361
Flash Point(°F)25°C
Flash Point(°C)25°C
Boil Point(°C)59 °C/100 mmHg

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS02
Signal Danger
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H301:Toxic if swallowed

H225:Highly Flammable liquid and vapor

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P403+P235:Store in a well-ventilated place. Keep cool.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P271:Use only outdoors or in a well-ventilated area.

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P242:Use only non-sparking tools.

P243:Take precautionary measures against static discharge.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P316:IF SWALLOWED: Get emergency medical help immediately.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 2
Reaxy-Rn 4175872

Related Documents

References

1. Antonios M Douvas,Panagiota S Petrou,Sotirios E Kakabakos,Konstantinos Misiakos,Panagiotis Argitis,Evagelia Sarantopoulou,Zoe Kollia,Alkiviadis C Cefalas.  (2005-02-03)  157-nm Laser ablation of polymeric layers for fabrication of biomolecule microarrays..  Analytical and bioanalytical chemistry,  381  ((5)): (1027-1032).  [PMID:15688151]
2. Arda Yurtsever,Berna Saraçoğlu,Ali Tuncel.  (2009-01-22)  CEC with new monolithic stationary phase based on a fluorinated monomer, trifluoroethyl methacrylate..  Electrophoresis,  30  ((4)): (589-598).  [PMID:19156765]
3. Yoshinori Kadoma,Yoh Tamaki.  (2009-10-14)  Bonding durability against water of a fluorine-containing resin for precious metal alloys..  Dental materials journal,  28  ((5)): (642-648).  [PMID:19822997]
4. Sophia Chao-Wei Huang,Chi-Hui Cheng,Yun Chiu,Yi-Ching Lin,Jui-Che Lin.  (2017-09-04)  A facile novel fluorocarbon copolymer solution coating process for improving platelet compatibility of titanium..  Materials science & engineering. C, Materials for biological applications,  80  (584-593).  [PMID:28866204]
5. Young Hyun Kim,Hyang Moo Lee,Sung Wook Choi,In Woo Cheong.  (2017-09-25)  A study on amphiphilic fluorinated block copolymer in graphite exfoliation using supercritical CO.  Journal of colloid and interface science,  510  (162-171).  [PMID:28942166]
6. Garcia Cruz, et al..  (2020)  Design and fabrication of a smart sensor using in silico epitope mapping and electro-responsive imprinted polymer nanoparticles for determination of insulin levels in human plasma..  Biosensors And Bioelectronics,  169  (112536-112536).  [PMID:32980804]
7. Honglin Zhang,Zhiguo Zhang.  (2020-11-04)  Ratiometric Sensor Based on PtOEP-C6/Poly (St-TFEMA) Film for Automatic Dissolved Oxygen Content Detection..  Sensors (Basel, Switzerland),  20  ((21)):   [PMID:33138300]
8. Y Yokoyama,Y Kadoma,E Masuhara.  (1984-01-01)  [Properties of 2,2,2-Trifluoroethyl methacrylate copolymers]..  Iyo Kizai Kenkyujo hokoku. Reports of the Institute for Medical and Dental Engineering, Tokyo Medical and Dental University,  18  (1-9).  [PMID:6598491]
9. Yoshinori Kadoma.  (2010-09-10)  Kinetic polymerization behavior of fluorinated monomers for dental use..  Dental materials journal,  29  ((5)): (602-608).  [PMID:20827030]
10. Ryohei Koguchi,Katja Jankova,Noriko Tanabe,Yosuke Amino,Yuki Hayasaka,Daisuke Kobayashi,Tatsuya Miyajima,Kyoko Yamamoto,Masaru Tanaka.  (2019-05-02)  Controlling the Hydration Structure with a Small Amount of Fluorine To Produce Blood Compatible Fluorinated Poly(2-methoxyethyl acrylate)..  Biomacromolecules,  20  ((6)): (2265-2275).  [PMID:31042022]

Solution Calculators