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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution - 1.0M in THF, high purity , CAS No.898838-07-8

  • 1.0M in THF
Item Number
T466154
Grouped product items
SKUSizeAvailabilityPrice Qty
T466154-100ml
100ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$181.90
T466154-500ml
500ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$634.90

Basic Description

SynonymsDTXSID30635642 | 2,2,6,6-tetramethylpiperidinylmagnesium chloride lithium chloride | lithium magnesium 2,2,6,6-tetramethylpiperidin-1-ide dichloride | JHBZAAACZVPPRQ-UHFFFAOYSA-L | TMPMgCl·LiCl
Specifications & Purity1.0M in THF
Storage TempStore at 2-8°C,Protected from light,Argon charged
Shipped InWet ice
Product Description

Description

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.Selective Deprotonations using Knochel-Hauser-Base

Names and Identifiers

IUPAC Name lithium;magnesium;2,2,6,6-tetramethylpiperidin-1-ide;dichloride
INCHI InChI=1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
InChi Key JHBZAAACZVPPRQ-UHFFFAOYSA-L
Canonical SMILES [Li+].CC1(CCCC([N-]1)(C)C)C.[Mg+2].[Cl-].[Cl-]
Isomeric SMILES [Li+].CC1(CCCC([N-]1)(C)C)C.[Mg+2].[Cl-].[Cl-]
PubChem CID 25150783
Molecular Weight 242.40

Certificates

C of A & Other Certificates(BSE/TSE, COO)

Find and download the COA for your product by matching the lot number on the packaging.

4 results found

Lot NumberCertificate TypeDateItem
H2406671Certificate of AnalysisJul 26, 2024 T466154
H2406675Certificate of AnalysisJul 26, 2024 T466154
H2406676Certificate of AnalysisJul 26, 2024 T466154
H2406682Certificate of AnalysisJul 26, 2024 T466154

Chemical and Physical Properties

Sensitivitymoisture&light&air sensitive

Related Documents

References

1. Hiroki Iguchi,Chisato Higashi,Yuichi Funasaki,Keisuke Fujita,Atsunori Mori,Akira Nakasuga,Tatsuo Maruyama.  (2017-01-07)  Rational and practical exfoliation of graphite using well-defined poly(3-hexylthiophene) for the preparation of conductive polymer/graphene composite..  Scientific reports,  (39937-39937).  [PMID:28059127]

Solution Calculators