2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution - 1.0M in THF, high purity , CAS No.898838-07-8

Item Number

T466154

Grouped product items
SKU	Size	Availability	Price	Qty
T466154-100ml	100ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$181.90
T466154-500ml	500ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$634.90

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Basic Description

Synonyms	DTXSID30635642 \| 2,2,6,6-tetramethylpiperidinylmagnesium chloride lithium chloride \| lithium magnesium 2,2,6,6-tetramethylpiperidin-1-ide dichloride \| JHBZAAACZVPPRQ-UHFFFAOYSA-L \| TMPMgCl·LiCl
Specifications & Purity	1.0M in THF
Storage Temp	Store at 2-8°C,Protected from light,Argon charged
Shipped In	Wet ice
Product Description	Description 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.Selective Deprotonations using Knochel-Hauser-Base

Names and Identifiers

IUPAC Name	lithium;magnesium;2,2,6,6-tetramethylpiperidin-1-ide;dichloride
INCHI	InChI=1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
InChi Key	JHBZAAACZVPPRQ-UHFFFAOYSA-L
Canonical SMILES	[Li+].CC1(CCCC([N-]1)(C)C)C.[Mg+2].[Cl-].[Cl-]
Isomeric SMILES	[Li+].CC1(CCCC([N-]1)(C)C)C.[Mg+2].[Cl-].[Cl-]
PubChem CID	25150783
Molecular Weight	242.40

Certificates

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4 results found

Lot Number	Certificate Type	Date	Item
H2406671	Certificate of Analysis	Jul 26, 2024	T466154
H2406675	Certificate of Analysis	Jul 26, 2024	T466154
H2406676	Certificate of Analysis	Jul 26, 2024	T466154
H2406682	Certificate of Analysis	Jul 26, 2024	T466154

References

1. Hiroki Iguchi,Chisato Higashi,Yuichi Funasaki,Keisuke Fujita,Atsunori Mori,Akira Nakasuga,Tatsuo Maruyama. (2017-01-07) Rational and practical exfoliation of graphite using well-defined poly(3-hexylthiophene) for the preparation of conductive polymer/graphene composite.. Scientific reports, 7 (39937-39937). [PMID:28059127]

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Basic Description