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2-(2-Bromoethyl)-1,3-dioxane - 98%, high purity , CAS No.33884-43-4
Basic Description Synonyms 3-Bromopropionaldehyde trimethylene acetal | 1,3-Dioxane, 2-(2-bromoethyl)-; 2-(2-bromoethyl)-3-dioxane;3-Bromopropionaldehyde trimethylene acetal | AKOS015836230 | 2-(2-Bromoethyl)-1,3-dioxane, 98% | FT-0608433 | WMDHQEHPOVOEOG-UHFFFAOYSA- | MFCD00006567 Specifications & Purity ≥98% Storage Temp Store at 2-8°C,Protected from light,Argon charged Shipped In Wet ice Product Description application：
2-(2-Bromoethyl)-1,3-dioxane was used in the synthesis of ketone adducts 2-[3-oxo-4(S)-(triphenylmethyl) amino-6-methylheptyl]-1,3-dioxane and 2-[3-oxo-4(S)-(triphenylmethyl)amino-6-methylheptyl]-1,3-dioxolane.
Names and Identifiers IUPAC Name 2-(2-bromoethyl)-1,3-dioxane INCHI InChI=1S/C6H11BrO2/c7-3-2-6-8-4-1-5-9-6/h6H,1-5H2 InChi Key WMDHQEHPOVOEOG-UHFFFAOYSA-N Canonical SMILES C1COC(OC1)CCBr Isomeric SMILES C1COC(OC1)CCBr WGK Germany 3 PubChem CID 520656 Molecular Weight 195.05 Beilstein 1421628 Reaxy-Rn 1421628
Chemical and Physical Properties Solubility ethanol: soluble 50 (μg/mL) Sensitivity Light Sensitive；Air Sensitive；Heat sensitive Refractive Index 1.481 Flash Point(°F) 206.6 °F Flash Point(°C) 96°C Boil Point(°C) 67-70°C
Safety and Hazards(GHS) Pictogram(s) GHS07 Signal Warning Hazard Statements H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: wash with plenty of water.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P362+P364: Take off contaminated clothing and wash it before reuse.
P264+P265: Wash hands [and …] thoroughly after handling. Do not touch eyes.
P337+P317: If eye irritation persists: Get medical help.
P332+P317: If skin irritation occurs: Get medical help.
P319: Get medical help if you feel unwell.
WGK Germany 3 Reaxy-Rn 1421628
References 1. Kristin M Brinner, Jonathan A Ellman,. (2005-05-27) A rapid and general method for the asymmetric synthesis of 2-substituted pyrrolidines using tert-butanesulfinamide.. Organic & biomolecular chemistry, 3 ((11)): ( 2109-2113 ). [PMID:15917897 ]
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