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2-Bromo-6-(trimethylsilyl)phenyl triflate - 95%, high purity , CAS No.1092542-31-8
Basic Description Synonyms 1092542-31-8|2-Bromo-6-(trimethylsilyl)phenyl triflate|(2-bromo-6-trimethylsilylphenyl) trifluoromethanesulfonate|2-Bromo-6-(trimethylsilyl)phenyltriflate|2-?Bromo-?6-?(trimethylsilyl)?phenyl triflate|2-Bromo-6-(trimethylsilyl)phenyl triflate, 95%|A929742 Specifications & Purity 95% Storage Temp Store at 2-8°C,Argon charged Shipped In Wet ice Product Description Description
Bromosilyltriflate has been shown to be a useful precursor for the generation of a bromobenzyne intermediate. The bromobenzyne intermediate can be generated in the presence of cesium or potassium fluoride and can be trapped with various dipolariphiles.Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of ArynesContinuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors
Names and Identifiers IUPAC Name (2-bromo-6-trimethylsilylphenyl) trifluoromethanesulfonate INCHI InChI=1S/C10H12BrF3O3SSi/c1-19(2,3)8-6-4-5-7(11)9(8)17-18(15,16)10(12,13)14/h4-6H,1-3H3 InChi Key ZNKAHJCGEPVEBA-UHFFFAOYSA-N Canonical SMILES C[Si](C)(C)C1=C(C(=CC=C1)Br)OS(=O)(=O)C(F)(F)F Isomeric SMILES C[Si](C)(C)C1=C(C(=CC=C1)Br)OS(=O)(=O)C(F)(F)F PubChem CID 100912265 Molecular Weight 377.25
Chemical and Physical Properties Sensitivity Moisture sensitive Refractive Index n/D 1.492
Safety and Hazards(GHS) Pictogram(s) GHS05 Signal Danger Hazard Statements H314: Causes severe skin burns and eye damage
Precautionary Statements P280: Wear protective gloves/protective clothing/eye protection/face protection.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P305+P354+P338: IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P302+P361+P354: IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.
P316: Get emergency medical help immediately.
RIDADR UN32658/PGII
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