2-(Diphenylphosphino)ethylamine - 95%, high purity , CAS No.4848-43-5

Item Number

D102803

Grouped product items
SKU	Size	Availability	Price
D102803-250mg	250mg	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$40.90
D102803-1g	1g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$125.90
D102803-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$564.90

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Basic Description

Synonyms	2-(Diphenylphosphino)ethylamine\|4848-43-5\|(2-Aminoethyl)diphenylphosphine\|2-(diphenylphosphino)ethanamine\|2-diphenylphosphanylethanamine\|MFCD00233831\|2-(Diphenylphosphino) ethylamine\|Ethanamine, 2-(diphenylphosphino)-\|NSC118384\|NH2(CH2)2PPh2\|2-diphenylpho
Specifications & Purity	95%
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice
Product Description	2-(Diphenylphosphino)ethylamine is a phosphine ligand that has a bidentate structure with the phosphorus atom donating two lone pair electrons to coordinate with metal atoms. It is used as a reactant to synthesize active catalyst for the selective hydrogenation of amides. In addition, it is also used as a precursor to synthesize other phosphine ligands. Application： 2-(Diphenylphosphino)ethylamine can be used as a bidentate ligand in the nickel catalyst system for the reductive [2+2] cycloaddition reaction to synthesize cyclobutenes from alkynes.

Names and Identifiers

IUPAC Name	2-diphenylphosphanylethanamine
INCHI	InChI=1S/C14H16NP/c15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14/h1-10H,11-12,15H2
InChi Key	RXEPBCWNHKZECN-UHFFFAOYSA-N
Canonical SMILES	C1=CC=C(C=C1)P(CCN)C2=CC=CC=C2
Isomeric SMILES	C1=CC=C(C=C1)P(CCN)C2=CC=CC=C2
WGK Germany	3
PubChem CID	273264
Molecular Weight	229.26
Beilstein	644931

Certificates

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6 results found

Lot Number	Certificate Type	Date	Item
I2403330	Certificate of Analysis	Aug 23, 2024	D102803
I2403332	Certificate of Analysis	Aug 23, 2024	D102803
I2403334	Certificate of Analysis	Aug 23, 2024	D102803
H2308361	Certificate of Analysis	Jul 12, 2023	D102803
H2308362	Certificate of Analysis	Jul 12, 2023	D102803
H2308369	Certificate of Analysis	Jul 12, 2023	D102803

Solubility

Insoluble in water.

Sensitivity

Moisture & Air Sensitive

Safety and Hazards(GHS)

Pictogram(s)	GHS05
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	3

References

1. Youngwon Kim,Jinwook Lee,You-Hwa Son,Sang-Un Choi,Mahboob Alam,Soonheum Park. (2020-02-08) Novel nickel(II), palladium(II), and platinum(II) complexes having a pyrrolyl-iminophosphine (PNN) pincer: Synthesis, crystal structures, and cytotoxic activity.. Journal of inorganic biochemistry, 205 (111015-111015). [PMID:32032825]

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Basic Description