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2-(Trimethylsilyl)-2,3-pentadiene , CAS No.77494-35-0
Basic Description Synonyms Trimethyl(penta-2,3-dien-2-yl)silane | DTXSID60455294 | 2-(Trimethylsilyl)-2,3-pentadiene Storage Temp Store at -20°C Shipped In Ice chest + Ice pads Product Description
Description
Reactant for:Oxidative cyclization with chlorine to give chloro- and acetoxybenziodoxaboroles and a self-assembled tetrameric macrocyclic structurePreparation of allylic alcohols or enone derivatives using boronic acid as catalystCatalyst for:Preparation of acylsulfoximines via N-acylation of sulfoximines with aliphatic acidsDirect amide bond formationRegioselective preparation of substituted triazole derivatives via dipolar cycloaddition of unsaturated carboxylic acids with azides
Names and Identifiers INCHI InChI=1S/C8H16Si/c1-6-7-8(2)9(3,4)5/h6H,1-5H3 InChi Key JGOGDIIEKVYPFO-UHFFFAOYSA-N Canonical SMILES CC=C=C(C)[Si](C)(C)C Isomeric SMILES CC=C=C(C)[Si](C)(C)C WGK Germany 3 PubChem CID 11105454 Molecular Weight 140.3
Certificates(CoA,COO,BSE/TSE and Analysis Chart) Chemical and Physical Properties Flash Point(°F) 15.8 °F Flash Point(°C) -9 °C
Safety and Hazards(GHS) Pictogram(s) GHS02 Signal Danger Hazard Statements H225: Highly Flammable liquid and vapor
Precautionary Statements P280: Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378: In case of fire: Use ... to extinguish.
P210: Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.
P501: Dispose of contents/container to ...
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P403+P235: Store in a well-ventilated place. Keep cool.
P303+P361+P353: IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].
P241: Use explosion-proof [electrical/ventilating/lighting/.../] equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
WGK Germany 3 RIDADR UN1993BF3/PGII
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