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3,5-Dibromosalicylaldehyde - 98%, high purity , CAS No.90-59-5

  • ≥98%
Item Number
D106540
Grouped product items
SKUSizeAvailabilityPrice Qty
D106540-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$27.90
D106540-25g
25g
Available within 1-2 weeks(?)
Item is derived from our semi-finished stock and is processed in 1-2 weeks.
$98.90
D106540-100g
100g
In stock
$355.90
D106540-500g
500g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$1,600.90
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View related series
aldehyde Non heterocyclic block

Basic Description

Synonyms3,5-DIBROMOSALICYLALDEHYDE|3,5-Dibromo-2-hydroxybenzaldehyde|90-59-5|Dalyde|Benzaldehyde, 3,5-dibromo-2-hydroxy-|3,5-Dibromosalicylaldeyde|2-Hydroxy-3,5-dibromobenzaldehyde|MFCD00003318|Salicylaldehyde, 3,5-dibromo-|7A260PBI3A|NSC-6221|4,6-Dibromo-2-formy
Specifications & Purity≥98%
Storage TempProtected from light,Argon charged
Shipped InNormal
Note5g,10g,卖完停产，不再备货
Product Description

Product Description

3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes.

Product Application
3,5-Dibromosalicylaldehyde was used in the synthesis of Schiff base, 15N-Labeled N-(3,5-dibromosalicylidene)-methylamine. It was used as reactant for synthesis of Schiff base ligands which forms mononuclear complexes with copper(II), nickel(II), zinc(II) and cobalt(II).

Associated Targets

ERN1 Tchem Serine/threonine-protein kinase/endoribonuclease IRE1 0 Activities

Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)

Names and Identifiers

Pubchem Sid488180249
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488180249
IUPAC Name 3,5-dibromo-2-hydroxybenzaldehyde
INCHI InChI=1S/C7H4Br2O2/c8-5-1-4(3-10)7(11)6(9)2-5/h1-3,11H
InChi Key JHZOXYGFQMROFJ-UHFFFAOYSA-N
Canonical SMILES C1=C(C=C(C(=C1C=O)O)Br)Br
Isomeric SMILES C1=C(C=C(C(=C1C=O)O)Br)Br
WGK Germany 3
RTECS CU5609000
PubChem CID 7024
Molecular Weight 279.91
Beilstein 8,55
Reaxy-Rn 1424739

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

13 results found

Lot NumberCertificate TypeDateItem
K2124389Certificate of AnalysisAug 18, 2023 D106540
K2124396Certificate of AnalysisAug 18, 2023 D106540
K2124448Certificate of AnalysisAug 18, 2023 D106540
K1920143Certificate of AnalysisJun 06, 2023 D106540
F2117026Certificate of AnalysisMar 15, 2023 D106540
I1525022Certificate of AnalysisJan 04, 2023 D106540
E2310132Certificate of AnalysisDec 12, 2022 D106540
E2310146Certificate of AnalysisDec 12, 2022 D106540
E2310156Certificate of AnalysisDec 12, 2022 D106540
E2310473Certificate of AnalysisDec 12, 2022 D106540
E2310474Certificate of AnalysisDec 12, 2022 D106540
L2008001Certificate of AnalysisSep 20, 2022 D106540
L2216803Certificate of AnalysisJun 21, 2021 D106540

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Chemical and Physical Properties

SolubilitySoluble in methanol 25 mg/mL. Insoluble in water.
SensitivityLight & Air sensitive.
Melt Point(°C)80-84°C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H400:Very toxic to aquatic life

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3
RTECS CU5609000
Reaxy-Rn 1424739
Merck Index 3027

Related Documents

 SDS

 Specification Sheet

Alternative Products

  1. 3,5-Dibromosalicylaldoxime
    3,5-Dibromosalicylaldoxime

    Starting at $20.90

References

1. Shasad Sharif,Gleb S Denisov,Michael D Toney,Hans-Heinrich Limbach.  (2006-03-09)  NMR studies of solvent-assisted proton transfer in a biologically relevant Schiff base: toward a distinction of geometric and equilibrium H-bond isotope effects..  Journal of the American Chemical Society,  128  ((10)): (3375-3387).  [PMID:16522119]
2. Z Rozwadowski.  (2006-06-03)  Deuterium isotope effect on 13C chemical shifts of tetrabutylammonium salts of Schiff bases amino acids..  Magnetic resonance in chemistry : MRC,  44  ((9)): (881-886).  [PMID:16741983]
3. Yongming Cui,Xiongwei Dong,Yuguang Li,Zuowen Li,Wu Chen.  (2012-11-13)  Synthesis, structures and urease inhibition studies of Schiff base metal complexes derived from 3,5-dibromosalicylaldehyde..  European journal of medicinal chemistry,  58  (323-331).  [PMID:23142672]
4. M Reed,S H Morris,A B Owczarczyk,N W Lukacs.  (2015-02-12)  Deficiency of autophagy protein Map1-LC3b mediates IL-17-dependent lung pathology during respiratory viral infection via ER stress-associated IL-1..  Mucosal immunology,  8  ((5)): (1118-1130).  [PMID:25669150]
5. Qing Liu,Jiahui Lin,Juan Liu,Wu Chen,Yongming Cui.  (2016-06-23)  Synthesis, Characterization and X-Ray Crystal Structures of cis-Dioxomolybdenum(VI) Complexes of Similar Tridentate Aroylhydrazone Schiff Bases with Catalytic Epoxidation Activity..  Acta chimica Slovenica,  63  ((2)): (279-286).  [PMID:27333550]
6. Haibo Ni,Qin Rui,Yitian Xu,Jun Zhu,Fan Gao,Baoqi Dang,Di Li,Rong Gao,Gang Chen.  (2018-03-09)  RACK1 upregulation induces neuroprotection by activating the IRE1-XBP1 signaling pathway following traumatic brain injury in rats..  Experimental neurology,  304  (102-113).  [PMID:29518365]

Solution Calculators

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