3-Phenyl-1H-inden-1-ylidene[bis(i-butylphobane)]ruthenium(II) dichloride - 95%, high purity , CAS No.894423-99-5

Item Number

P282788

• Synonyms: Umicore Grubbs Catalyst M110;Dichloro(3-phenyl-1H-inden-1-ylidene)bis(isobutylphobane)ruthenium(II), Dichlorobis(9-isobutyl-9-phosphabicyclo[3.3.1]nonane)(3-phenyl-1H-inden-1-ylidene)ruthenium(II), Grubbs Catalyst® M11
• Specifications & Purity: 95%
• Legal Information: Sold in collaboration with Umicore for research purposes only. Patent US 10,518,716.

Product Description

Product class
M-P, Homogeneous Catalysts, Grubbs Catalyst® 1st Generation, Phosphorus Ligands - Achiral

Reaction type
Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties

Chemical formula

C39H56Cl2P2Ru

Empirical formula

Ru(iBu-phobane)2(Ind)Cl2

Molecular weight

758.79

Metal

Ru

Theoretical metal content

13

Physical state

powder

Color

brown

Applications & references

Total synthesis of macrocyclic HCV protease inhibitor with RCM as key step.

Reference: US2009 0163706

Ring opening metathesis polymerization.

Reference: Adv. Synth. Catal. 2010, 352, 1934 (DOI: 10.1002/adsc.201000207)

Ring closing metathesis forming heterocycles.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Enyne cycloisomerization.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Ethenolysis of methyl oleate.

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B)

Self metathesis of terminal alkenes.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)