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[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine] nickel (II) dichloride - 90%, high purity , CAS No.1034901-50-2

  • ≥90%
Item Number
B486513
Grouped product items
SKUSizeAvailabilityPrice Qty
B486513-500mg
500mg
In stock
$237.90
B486513-1g
1g
In stock
$400.90
B486513-5g
5g
In stock
$1,400.90
B486513-25g
25g
In stock
$4,900.90

Basic Description

Specifications & Purity90%
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

Description

[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine] nickel (II) dichloride can be used as a catalyst in:Decarboxylative arylation of oxo acids.Acylation of ethers.Cross-coupling of aryl bromides with alcohols.

Names and Identifiers

Pubchem Sid488203105
IUPAC Name 4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine;dichloronickel
INCHI InChI=1S/C18H24N2.2ClH.Ni/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;;;/h7-12H,1-6H3;2*1H;/q;;;+2/p-2
InChi Key PCWIKFRTCXESOT-UHFFFAOYSA-L
Canonical SMILES CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C.Cl[Ni]Cl
PubChem CID 156589138
Molecular Weight 398

Certificates

Certificate of Analysis(COA)

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8 results found

Lot NumberCertificate TypeDateItem
D23141219Certificate of AnalysisMar 22, 2023 B486513
D23141223Certificate of AnalysisMar 22, 2023 B486513
D23141224Certificate of AnalysisMar 22, 2023 B486513
D23141225Certificate of AnalysisMar 22, 2023 B486513
D23141230Certificate of AnalysisMar 22, 2023 B486513
D23141235Certificate of AnalysisMar 22, 2023 B486513
D23141240Certificate of AnalysisMar 22, 2023 B486513
D23141241Certificate of AnalysisMar 22, 2023 B486513

Chemical and Physical Properties

Flash Point(°F)Not applicable
Flash Point(°C)Not applicable
Melt Point(°C)>300℃

Safety and Hazards(GHS)

RIDADR NONH for all modes of transport

Related Documents

References

1. Wacharee Harnying,André Kaiser,Axel Klein,Albrecht Berkessel.  (2011-03-23)  Cr/Ni-catalyzed vinylation of aldehydes: a mechanistic study on the catalytic roles of nickel and chromium..  Chemistry (Weinheim an der Bergstrasse, Germany),  17  ((17)): (4765-4773).  [PMID:21425369]
2. Lingling Chu,Jeffrey M Lipshultz,David W C MacMillan.  (2015-05-28)  Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids..  Angewandte Chemie (International ed. in English),  54  ((27)): (7929-7933).  [PMID:26014029]
3. Martins S Oderinde,Adrian Varela-Alvarez,Brian Aquila,Daniel W Robbins,Jeffrey W Johannes.  (2015-07-04)  Effects of Molecular Oxygen, Solvent, and Light on Iridium-Photoredox/Nickel Dual-Catalyzed Cross-Coupling Reactions..  The Journal of organic chemistry,  80  ((15)): (7642-7651).  [PMID:26140623]
4. Zhongdong Sun,Naoya Kumagai,Masakatsu Shibasaki.  (2017-07-12)  Photocatalytic α-Acylation of Ethers..  Organic letters,  19  ((14)): (3727-3730).  [PMID:28696708]

Solution Calculators