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(4R,4''R,5S,5''S)-2,2''-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole] - 98%,99% ee, high purity , CAS No.157904-67-1
Basic Description Synonyms 157904-67-1|(4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole|(4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole]|Oxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4,5-diphenyl-, (4R,4'R,5S,5'S)-|(4R,5S Specifications & Purity 98%,99% ee Storage Temp Store at 2-8°C Shipped In Wet ice Product Description (4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene) or (4S,5R)-Bis-Phbox) can be used as a ligand: To prepare selective exo-catalysts for enantioselective 1,3-dipolar cycloaddition reactions. In the asymmetric aminooxygenation of alkenes in the presence of tetramethylaminopyridyl radical (TEMPO) as an oxidant and copper(II) triflate as a catalyst. In asymmetric aminofluorination of olefins using an iron catalyst.
Names and Identifiers IUPAC Name (4R,5S)-2-[2-[(4R,5S)-4,5-diphenyl-4,5-dihydro-1,3-oxazol-2-yl]propan-2-yl]-4,5-diphenyl-4,5-dihydro-1,3-oxazole INCHI InChI=1S/C33H30N2O2/c1-33(2,31-34-27(23-15-7-3-8-16-23)29(36-31)25-19-11-5-12-20-25)32-35-28(24-17-9-4-10-18-24)30(37-32)26-21-13-6-14-22-26/h3-22,27-30H,1-2H3/t27-,28-,29+,30+/m1/s1 InChi Key ZWWGNCSTEMMQOQ-XAZDILKDSA-N Canonical SMILES CC(C)(C1=NC(C(O1)C2=CC=CC=C2)C3=CC=CC=C3)C4=NC(C(O4)C5=CC=CC=C5)C6=CC=CC=C6 Isomeric SMILES CC(C)(C1=N[C@@H]([C@@H](O1)C2=CC=CC=C2)C3=CC=CC=C3)C4=N[C@@H]([C@@H](O4)C5=CC=CC=C5)C6=CC=CC=C6 PubChem CID 15358971 Molecular Weight 486.6
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