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5′-O-tert-Butyldimethylsilylthymidine - 97%, high purity , CAS No.40733-28-6
Basic Description
Synonyms | 5'-O-[(1,1-Dimethylethyl)dimethylsilyl]thymidine | 5'-O-tert-Butyldimethylsilylthymidine | 5'-O-TERT-BUTYLDIMETHYLSILYL-THYMIDINE | D86090 | CS-0159276 | 1-((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-hydroxytetrahydrofuran-2-yl)-5-methylpyrimid |
Specifications & Purity | 97% |
Storage Temp | Store at 2-8°C,Protected from light |
Shipped In | Wet ice |
Product Description |
5'-O-TBDMS-dT is a protective and modifying nucleoside Application:
5'-O-(tert-Butyldimethylsilyl)thymidine is used as pharmaceutical intermediate.
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Names and Identifiers
IUPAC Name | 1-[(2R,4S,5R)-5-[[tert-butyl(dimethyl)silyl]oxymethyl]-4-hydroxyoxolan-2-yl]-5-methylpyrimidine-2,4-dione |
INCHI | InChI=1S/C16H28N2O5Si/c1-10-8-18(15(21)17-14(10)20)13-7-11(19)12(23-13)9-22-24(5,6)16(2,3)4/h8,11-13,19H,7,9H2,1-6H3,(H,17,20,21)/t11-,12+,13+/m0/s1 |
InChi Key | IJWIJLIIOKZJMS-YNEHKIRRSA-N |
Canonical SMILES | CC1=CN(C(=O)NC1=O)C2CC(C(O2)CO[Si](C)(C)C(C)(C)C)O |
Isomeric SMILES | CC1=CN(C(=O)NC1=O)[C@H]2C[C@@H]([C@H](O2)CO[Si](C)(C)C(C)(C)C)O |
PubChem CID | 10251259 |
Molecular Weight | 356.49 |
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Chemical and Physical Properties
Sensitivity | Light Sensitive |
Safety and Hazards(GHS)
Pictogram(s) | GHS07 |
Signal | Warning |
Hazard Statements | H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation |
Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell. |
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