(Acetylacetonato)dicarbonylrhodium(I) - 99%, high purity , CAS No.14874-82-9

1 Citations

Item Number

A118542

Grouped product items
SKU	Size	Availability	Price
A118542-100mg	100mg	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$467.90
A118542-250mg	250mg	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$926.90
A118542-500mg	500mg	In stock	$1,476.90

Discover (Acetylacetonato)dicarbonylrhodium(I) by Aladdin Scientific in 99% for only $467.90. Available - in Ligands at Aladdin Scientific. Tags: .

Basic Description

Synonyms	CARAC \| Rh(CO)2acac
Specifications & Purity	≥99%
Storage Temp	Room temperature,Argon charged
Shipped In	Normal
Product Description	(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds. A catalyst for various carbonylation reactions Product class M-O, Homogeneous Catalysts, Acetylacetonate Ligands Reaction type Carbonylation, Hydroformylation, Reduction Chemical properties Chemical formula C7H7O4Rh Empirical formula Rh(CO)2(acac) Molecular weight 258.04 Metal Rh Theoretical metal content 40 Physical state crystalline Color green

Names and Identifiers

INCHI	1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
InChi Key	BZCAWKOPWNIDOC-FGSKAQBVSA-M
Canonical SMILES	[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]
Isomeric SMILES	CC(=[OH+])CC(=[OH+])C.[C-]#[O+].[C-]#[O+].[Rh]
WGK Germany	3
PubChem CID	84819248
UN Number	3467
Molecular Weight	258.03

Certificates

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5 results found

Lot Number	Certificate Type	Date	Item
A1911136	Certificate of Analysis	Nov 11, 2022	A118542
J1810100	Certificate of Analysis	Aug 09, 2022	A118542
F2424490	Certificate of Analysis	Jun 08, 2022	A118542
G2220243	Certificate of Analysis	Jun 08, 2022	A118542
K2310045	Certificate of Analysis	May 10, 2021	A118542

Solubility

Solubility in water: insoluble in water;Soluble in acetone

Sensitivity

Air Sensitive

Melt Point(°C)

154-156°C

Safety and Hazards(GHS)

Pictogram(s)	GHS06, GHS09, GHS02
Signal	Warning
Hazard Statements	H319:Causes serious eye irritation H317:May cause an allergic skin reaction H228:Flammable solid
Precautionary Statements	P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.
WGK Germany	3

Citations of This Product

1. Jian Ruan, Youkai Jiang, Yaheng Zhang, Luhaibo Zhao, Jie Zhang, Zhiyong Tang. (2022) Towards more efficient hydroformylation of long-chain alkenes in aqueous biphasic system using microbubbles. Asia-Pacific Journal of Chemical Engineering, 18 (1): (e2842). [PMID:]

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Basic Description