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(Acetylacetonato)dicarbonylrhodium(I) - 99.95% metals basis, high purity , CAS No.14874-82-9

1 Citations

≥99.95% metals basis

CAS#: 14874-82-9
Formula: Rh(CO)₂(C₅H₇O₂)
Molecular Weight: 258.03
EC Number: 238-947-9
MDL number: MFCD00009884
PubChem CID: 84819248
PubChem SID: 488202386

Item Number

A293954

Grouped product items
SKU	Size	Availability	Price	Qty
A293954-500mg	500mg	In stock	$1,819.90

Discover (Acetylacetonato)dicarbonylrhodium(I) by Aladdin Scientific in 99.95% metals basis for only $1,819.90. Available - in Ligands at Aladdin Scientific. Tags: .

Basic Description

Synonyms	CARAC \| Rh(CO)2acac
Specifications & Purity	≥99.95% metals basis
Storage Temp	Room temperature,Argon charged
Shipped In	Normal
Product Description	(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds. A catalyst for various carbonylation reactions Product class M-O, Homogeneous Catalysts, Acetylacetonate Ligands Reaction type Carbonylation, Hydroformylation, Reduction Chemical properties Chemical formula C7H7O4Rh Empirical formula Rh(CO)2(acac) Molecular weight 258.04 Metal Rh Theoretical metal content 40 Physical state crystalline Color green Metal purity 99.95

Names and Identifiers

Pubchem Sid	488202386
INCHI	1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
InChi Key	BZCAWKOPWNIDOC-FGSKAQBVSA-M
Canonical SMILES	[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]
Isomeric SMILES	CC(=[OH+])CC(=[OH+])C.[C-]#[O+].[C-]#[O+].[Rh]
WGK Germany	3
PubChem CID	84819248
UN Number	3467
Molecular Weight	258.03

Certificates

Certificate of Analysis(COA)

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3 results found

Lot Number	Certificate Type	Date	Item
K2215265	Certificate of Analysis	Oct 15, 2022	A293954
K2215296	Certificate of Analysis	Oct 15, 2022	A293954
D2213008	Certificate of Analysis	Mar 24, 2022	A293954

Solubility

Solubility in water: insoluble in water;Soluble in acetone

Sensitivity

Air Sensitive

Melt Point(°C)

154-156°C

Safety and Hazards(GHS)

Pictogram(s)	GHS06, GHS09, GHS02
Signal	Warning
Hazard Statements	H319:Causes serious eye irritation H317:May cause an allergic skin reaction H228:Flammable solid
Precautionary Statements	P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.
WGK Germany	3

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Jian Ruan, Youkai Jiang, Yaheng Zhang, Luhaibo Zhao, Jie Zhang, Zhiyong Tang. (2022) Towards more efficient hydroformylation of long-chain alkenes in aqueous biphasic system using microbubbles. Asia-Pacific Journal of Chemical Engineering, 18 (1): (e2842). [PMID:]

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