Grouped product items

SKU

Size

Availability

Price

Qty

A475120-10g

10g

In stock

$114.90

A475120-50g

50g

In stock

$361.90

Basic Description

Synonyms	Aluminum trifluoromethanesulfonate\|74974-61-1\|ALUMINIUM TRIFLATE\|ALUMINUM TRIS(TRIFLUOROMETHANESULFONATE)\|Aluminium trifluoromethanesulphonate\|MFCD00143596\|ALUMINIUM TRIFLUOROMETHANESULFONATE\|aluminum;trifluoromethanesulfonate\|Aluminum triflate\|FKOASGGZYS
Specifications & Purity	99.9% trace metals basis
Product Description	Description Aluminum trifluoromethanesulfonate (aluminum triflate or Al(OTf)3) can be employed as a catalyst:In the regioselective synthesis of cyclic ethers by cycloisomerization of unsaturated alcohols.In the conversion of saccharides into 5-hydroxymethylfurfural (5-HMF).Along with Pd(OAc)2/BINAP for the methoxycarbonylation reaction of phenylacetylene.

Names and Identifiers

Pubchem Sid	488192919
Pubchem Sid Url	https://pubchem.ncbi.nlm.nih.gov/substance/488192919
IUPAC Name	aluminum;trifluoromethanesulfonate
INCHI	InChI=1S/3CHF3O3S.Al/c32-1(3,4)8(5,6)7;/h3(H,5,6,7);/q;;;+3/p-3
InChi Key	FKOASGGZYSYPBI-UHFFFAOYSA-K
Canonical SMILES	C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Al+3]
Isomeric SMILES	C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Al+3]
PubChem CID	2737634
Molecular Weight	474.19

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

9 results found

Lot Number	Certificate Type	Date	Item
E2409390	Certificate of Analysis	Apr 19, 2024	A475120
E2409391	Certificate of Analysis	Apr 19, 2024	A475120
E2409392	Certificate of Analysis	Apr 19, 2024	A475120
E2409399	Certificate of Analysis	Apr 19, 2024	A475120
B2428029	Certificate of Analysis	Mar 30, 2023	A475120
D2311131	Certificate of Analysis	Mar 30, 2023	A475120
D2311184	Certificate of Analysis	Mar 30, 2023	A475120
D2311185	Certificate of Analysis	Mar 30, 2023	A475120
D2311187	Certificate of Analysis	Mar 30, 2023	A475120

Chemical and Physical Properties

Solubility	Insoluble in water.
Sensitivity	Moisture sensitive.
Melt Point(°C)	300 °C (lit.)

Safety and Hazards(GHS)

Pictogram(s)	GHS05
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.

Alternative Products

References

1. Dennis M Whitfield. (2012-04-25) Plausible Transition States for glycosylation reactions.. Carbohydrate research, 356 (180-190). [PMID:22525097]
2. Sandro Keller,Carolyn Vargas,Huaying Zhao,Grzegorz Piszczek,Chad A Brautigam,Peter Schuck. (2012-04-26) High-precision isothermal titration calorimetry with automated peak-shape analysis.. Analytical chemistry, 84 ((11)): (5066-5073). [PMID:22530732]
3. Dennis M Whitfield. (2012-05-01) Complications of modeling glycosylation reactions: can the anomeric conformation of a donor determine the glycopyranosyl oxacarbenium ring conformation?. Carbohydrate research, 356 (191-195). [PMID:22542073]
4. Shiqiang Yan,Ning Ding,Wei Zhang,Peng Wang,Yingxia Li,Ming Li. (2012-05-09) An efficient and recyclable catalyst for the cleavage of tert-butyldiphenylsilyl ethers.. Carbohydrate research, 354 (6-20). [PMID:22565030]
5. Danqing Zheng,Shaoyu Li,Jie Wu. (2012-05-24) An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate.. Organic letters, 14 ((11)): (2655-2657). [PMID:22616758]
6. Yu Liu,Michael P Doyle. (2012-06-27) Michael addition/pericyclization/rearrangement--a multicomponent strategy for the synthesis of substituted resorcinols.. Organic & biomolecular chemistry, 10 ((31)): (6388-6394). [PMID:22733346]
7. Luka S Kovacevic,Christopher Idziak,Augustinas Markevicius,Callum Scullion,Michael J Corr,Alan R Kennedy,Tell Tuttle,John A Murphy. (2012-07-19) Superelectrophilic amidine dications: dealkylation by triflate anion.. Angewandte Chemie (International ed. in English), 51 ((34)): (8516-8519). [PMID:22807275]
8. Dominika Bratkowska,Núria Fontanals,Sylwia Ronka,Andrzej W Trochimczuk,Francesc Borrull,Rosa M Marcé. (2012-08-07) Comparison of different imidazolium supported ionic liquid polymeric phases with strong anion-exchange character for the extraction of acidic pharmaceuticals from complex environmental samples.. Journal of separation science, 35 ((15)): (1953-1958). [PMID:22865758]
9. Yusuke Imazaki,Eiji Shirakawa,Ryota Ueno,Tamio Hayashi. (2012-08-25) Ruthenium-catalyzed transformation of aryl and alkenyl triflates to halides.. Journal of the American Chemical Society, 134 ((36)): (14760-14763). [PMID:22916734]
10. Akio Saito,Nao Hyodo,Yuji Hanzawa. (2012-09-15) Synthesis of highly substituted oxazoles through iodine(III)-mediated reactions of ketones with nitriles.. Molecules (Basel, Switzerland), 17 ((9)): (11046-11055). [PMID:22976468]
11. Atsushi Kinbara,Takehiro Yamagishi,Naoko Hanzawa,Etsuko Kawashima,Hiroaki Miyaoka. (2012-09-26) Synthesis of phenol derivatives from cyclohex-2-enones bearing an alkyne through Lewis acid-catalyzed enolization and intramolecular Alder-Rickert reaction.. The Journal of organic chemistry, 77 ((20)): (8999-9005). [PMID:23003109]
12. Yu Hsien Lin,Bhaswati Ghosh,Kwok-Kong Tony Mong. (2012-10-02) In situ formation of β-glycosyl imidinium triflate from participating thioglycosyl donors: elaboration to disarmed-armed iterative glycosylation.. Chemical communications (Cambridge, England), 48 ((88)): (10910-10912). [PMID:23023321]
13. Yan-ping Zhu,Feng-cheng Jia,Mei-cai Liu,Liu-ming Wu,Qun Cai,Yang Gao,An-xin Wu. (2012-10-13) I2-CF3SO3H synergistic promoted sp3 C-H bond diarylation of aromatic ketones.. Organic letters, 14 ((20)): (5378-5381). [PMID:23057842]
14. Dahan Eom,Sangjune Park,Youngchul Park,Taekyu Ryu,Phil Ho Lee. (2012-10-26) Synthesis of indenes via Brønsted acid catalyzed cyclization of diaryl- and alkyl aryl-1,3-dienes.. Organic letters, 14 ((21)): (5392-5395). [PMID:23094690]
15. Yasuyuki Muto,Yuta Murai,Yasuko Sakihama,Yasuyuki Hashidoko,Makoto Hashimoto. (2012-11-08) Effective Friedel-Crafts acylation of biotin acid chloride in trifluoromethanesulfonic acid.. Bioscience, biotechnology, and biochemistry, 76 ((11)): (2162-2164). [PMID:23132579]
16. Fergus R Knight,Rebecca A M Randall,Lucy Wakefield,Alexandra M Z Slawin,J Derek Woollins. (2012-11-10) Investigating silver coordination to mixed chalcogen ligands.. Molecules (Basel, Switzerland), 17 ((11)): (13307-13329). [PMID:23138535]
17. Su-Xia Xu,Lu Hao,Tao Wang,Zong-Cang Ding,Zhuang-Ping Zhan. (2012-11-29) Chemoselective synthesis of substituted pyrazoles through AgOTf-catalyzed cascade propargylic substitution-cyclization-aromatization.. Organic & biomolecular chemistry, 11 ((2)): (294-298). [PMID:23188378]
18. B V Subba Reddy,M Ramana Reddy,Y Gopal Rao,J S Yadav,B Sridhar. (2013-01-18) Cu(OTf)2-catalyzed synthesis of 2,3-disubstituted indoles and 2,4,5-trisubstituted pyrroles from α-diazoketones.. Organic letters, 15 ((3)): (464-467). [PMID:23323540]
19. Krystyna Poreba,Joanna Wietrzyk. (2013-01-30) The synthesis of 3,5,6,7-tetrasubstituted isoxazolo[4,5-b]pyridines and an evaluation of their in vitro antiproliferative activity.. Advances in clinical and experimental medicine : official organ Wroclaw Medical University, 21 ((5)): (563-571). [PMID:23356192]
20. Jeong Hyeon Park,Chan Yi Park,Hyun Seung Song,Yun Suk Huh,Geon Hee Kim,Chan Pil Park. (2013-02-05) Green diacetoxylation of alkenes in a microchemical system.. Organic letters, 15 ((4)): (752-755). [PMID:23373522]
21. Xinxin Yu,Feixue Zou,Ying Li,Lu Lu,Xirong Huang,Yinbo Qu. (2013-02-14) Effect of three trifluoromethanesulfonate ionic liquids on the activity, stability and conformation of laccase.. International journal of biological macromolecules, 56 (62-68). [PMID:23403026]
22. Fumiya Urabe,Shunsuke Nagashima,Keisuke Takahashi,Jun Ishihara,Susumi Hatakeyama. (2013-04-13) Total synthesis of (-)-cinatrin C1 based on an In(OTf)3-catalyzed Conia-Ene reaction.. The Journal of organic chemistry, 78 ((8)): (3847-3857). [PMID:23578072]
23. Lihui Zhu,Zhi-Guo Xi,Jian Lv,Sanzhong Luo. (2013-08-21) In(III)/PhCO2H binary acid catalyzed tandem [2 + 2] cycloaddition and Nazarov reaction between alkynes and acetals.. Organic letters, 15 ((17)): (4496-4499). [PMID:23947688]
24. Hua-Dong Xu,Zhi-Hong Jia,Ke Xu,Hao Zhou,Mei-Hua Shen. (2014-12-17) One-pot protocol to functionalized benzopyrrolizidine catalyzed successively by Rh2(OAc)4 and Cu(OTf)2: a transition metal-Lewis acid catalysis relay.. Organic letters, 17 ((1)): (66-69). [PMID:25496025]
25. Zaher Slim,Erik J Menke. (2020-05-22) Comparing Computational Predictions and Experimental Results for Aluminum Triflate in Tetrahydrofuran.. The journal of physical chemistry. B, 124 ((24)): (5002-5008). [PMID:32437612]
26. Shaochen Zhang,Juan Del Pozo,Filippo Romiti,Yucheng Mu,Sebastian Torker,Amir H Hoveyda. (2019-04-06) Delayed catalyst function enables direct enantioselective conversion of nitriles to NH2-amines.. Science (New York, N.Y.), 364 ((6435)): (45-51). [PMID:30948544]

Solution Calculators

Molarity Calculator

Determine the necessary mass, volume, or concentration for preparing a solution.

Dilution Calculator

Determine the dilution needed to prepare a stock solution.

Aluminum trifluoromethanesulfonate - 99.9% trace metals basis, high purity , CAS No.74974-61-1