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Ammonium ceric nitrate - Analytical Reagent,99.0%, high purity , CAS No.16774-21-3

  • AR
  • ≥99%
Item Number
A105050
Grouped product items
SKUSizeAvailabilityPrice Qty
A105050-25g
25g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$29.90
A105050-100g
100g
In stock
$56.90
A105050-250g
250g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$108.90
A105050-500g
500g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$167.90

Basic Description

Specifications & PurityAR, ≥99%
Biochemical and Physiological MechanismsUsually used as an oxidant for many functional groups (alcohols, phenols, and ethers) as well as C-H bonds, especially those that are benzylic.
Storage TempArgon charged
Shipped InNormal
GradeAR
Product Description

Ammonium cerium(IV) nitrate is a very strong oxidizing agent. Ammonium cerium(IV) nitrate is useful as an oxidant for many functional groups (alcohols, phenols, and ethers) as well as C-H bonds, especially those that are benzylic.
A strongly oxidizing cerium preparation

Names and Identifiers

WGK Germany 3
UN Number 3085
Packing Group II
Molecular Weight 548.22

Certificates

Certificate of Analysis(COA)

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To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

33 results found

Lot NumberCertificate TypeDateItem
H2414469Certificate of AnalysisAug 27, 2024 A105050
H2414230Certificate of AnalysisAug 27, 2024 A105050
H2414228Certificate of AnalysisAug 27, 2024 A105050
H2414229Certificate of AnalysisAug 27, 2024 A105050
F2406113Certificate of AnalysisJun 20, 2024 A105050
F2406112Certificate of AnalysisJun 20, 2024 A105050
F2406117Certificate of AnalysisJun 20, 2024 A105050
E2422508Certificate of AnalysisMay 28, 2024 A105050
E2422504Certificate of AnalysisMay 28, 2024 A105050
E2422530Certificate of AnalysisMay 28, 2024 A105050
E2422502Certificate of AnalysisMay 28, 2024 A105050
C2428247Certificate of AnalysisApr 03, 2024 A105050
C2428248Certificate of AnalysisApr 03, 2024 A105050
C2428246Certificate of AnalysisApr 03, 2024 A105050
A2402387Certificate of AnalysisJan 12, 2024 A105050
A2402386Certificate of AnalysisJan 12, 2024 A105050
A2402385Certificate of AnalysisJan 10, 2024 A105050
I2328046Certificate of AnalysisOct 16, 2023 A105050
I2328035Certificate of AnalysisOct 16, 2023 A105050
I2328040Certificate of AnalysisOct 16, 2023 A105050
I2328045Certificate of AnalysisOct 16, 2023 A105050
D2311199Certificate of AnalysisApr 18, 2023 A105050
D2311198Certificate of AnalysisApr 18, 2023 A105050
D2311136Certificate of AnalysisApr 18, 2023 A105050
A2305075Certificate of AnalysisJan 16, 2023 A105050
A2305056Certificate of AnalysisJan 16, 2023 A105050
G2222036Certificate of AnalysisJul 27, 2022 A105050
G2222037Certificate of AnalysisJul 27, 2022 A105050
H2031100Certificate of AnalysisJul 12, 2022 A105050
A2219195Certificate of AnalysisJan 24, 2022 A105050
A2219192Certificate of AnalysisJan 24, 2022 A105050
A2219191Certificate of AnalysisJan 24, 2022 A105050
A2219190Certificate of AnalysisJan 24, 2022 A105050

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Chemical and Physical Properties

SolubilityWater and alcohol
SensitivityMoisture sensitive
Melt Point(°C)>400 °C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS05,   GHS07,   GHS03
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H302:Harmful if swallowed

H317:May cause an allergic skin reaction

H272:May intensify fire; oxidizer

H410:Very toxic to aquatic life with long lasting effects

H290:May be corrosive to metals

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P310:Immediately call a POISON CENTER or doctor/physician.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P220:Keep away from clothing and other combustible materials.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P221:Take any precaution to avoid mixing with combustibles/...

P270:Do not eat, drink or smoke when using this product.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P330:Rinse mouth.

P234:Keep only in original container.

P390:Absorb spillage to prevent material damage.

P301+P312:IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.

P406:Store in corrosive resistant/... container with a resistant inner liner.

WGK Germany 3
Class 5.1
Merck Index 1992

Related Documents

References

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2. Vijay Nair,Lakshmi Balagopal,Roshini Rajan,Jessy Mathew.  (2004-01-21)  Recent advances in synthetic transformations mediated by cerium(IV) ammonium nitrate..  Accounts of chemical research,  37  ((1)): (21-30).  [PMID:14730991]
3. Somak Paul,Narayanaswamy Jayaraman.  (2004-09-01)  Catalytic ceric ammonium nitrate mediated synthesis of 2-deoxy-1-thioglycosides..  Carbohydrate research,  339  ((13)): (2197-2204).  [PMID:15337447]
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11. Rasika Tankhiwale,S K Bajpai.  (2009-01-10)  Graft copolymerization onto cellulose-based filter paper and its further development as silver nanoparticles loaded antibacterial food-packaging material..  Colloids and surfaces. B, Biointerfaces,  69  ((2)): (164-168).  [PMID:19131217]
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13. Meng Zhou,Nathan D Schley,Robert H Crabtree.  (2010-08-25)  Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry..  Journal of the American Chemical Society,  132  ((36)): (12550-12551).  [PMID:20731395]
14. Amit H Haviv,Jean-Marc Grenèche,Jean-Paul Lellouche.  (2010-08-26)  Aggregation control of hydrophilic maghemite (gamma-Fe2O3) nanoparticles by surface doping using cerium atoms..  Journal of the American Chemical Society,  132  ((36)): (12519-12521).  [PMID:20735060]
15. Mazaahir Kidwai,Divya Bhatnagar,Rakesh Kumar,Pratibha Mehta Luthra.  (2010-10-12)  Synthesis of 2-oxo/thioxooctahydroquinazolin-5-one derivatives and their evaluation as anticancer agents..  Chemical & pharmaceutical bulletin,  58  ((10)): (1320-1323).  [PMID:20930397]
16. Yue Qi Ye,Hiroyuki Koshino,Naoki Abe,Takemichi Nakamura,Daisuke Hashizume,Shunya Takahashi.  (2010-11-13)  Synthesis of atromentin and its O-alkylated natural products..  Bioscience, biotechnology, and biochemistry,  74  ((11)): (2342-2344).  [PMID:21071857]
17. Myron M Johnson,Jeremy M Naidoo,Manuel A Fernandes,Edwin M Mmutlane,Willem A L van Otterlo,Charles B de Koning.  (2010-11-23)  CAN-mediated oxidations for the synthesis of xanthones and related products..  The Journal of organic chemistry,  75  ((24)): (8701-8704).  [PMID:21086958]
18. Y Suman Reddy,A P John Pal,Preeti Gupta,Alafia A Ansari,Yashwant D Vankar.  (2011-06-18)  Ceric ammonium nitrate-catalyzed azidation of 1,2-anhydro sugars: application in the synthesis of structurally diverse sugar-derived morpholine 1,2,3-triazoles and 1,4-oxazin-2-ones..  The Journal of organic chemistry,  76  ((15)): (5972-5984).  [PMID:21679000]
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20. Weibin Song,Min Lei,Kun Zhao,Lingjun Hu,Yuhui Meng,Dean Guo,Xuan Liu,Lihong Hu.  (2011-11-26)  Ceric ammonium nitrate-promoted oxidative coupling reaction for the synthesis and evaluation of a series of anti-tumor amide anhydrovinblastine analogs..  Bioorganic & medicinal chemistry letters,  22  ((1)): (387-390).  [PMID:22115594]
21. S Sudha,M A Pasha.  (2012-03-09)  Ultrasound assisted synthesis of tetrahydrobenzo[c]xanthene-11-ones using CAN as catalyst..  Ultrasonics sonochemistry,  19  ((5)): (994-998).  [PMID:22398382]
22. Mohammad Mahdi Najafpour,Atefeh Nemati Moghaddam.  (2012-07-19)  Nano-sized manganese oxide: a proposed catalyst for water oxidation in the reaction of some manganese complexes and cerium(IV) ammonium nitrate..  Dalton transactions (Cambridge, England : 2003),  41  ((34)): (10292-10297).  [PMID:22806229]
23. Xiaolin Yu,Shengrui Tong,Maofa Ge,Lingyan Wu,Junchao Zuo,Changyan Cao,Weiguo Song.  (2012-12-12)  Synthesis and characterization of multi-amino-functionalized cellulose for arsenic adsorption..  Carbohydrate polymers,  92  ((1)): (380-387).  [PMID:23218309]
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Solution Calculators