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Ammonium ceric nitrate - ≥99.99% metals basis, high purity , CAS No.16774-21-3

  • PrimorTrace™
  • ≥99.99% metals basis
Item Number
A105053
Grouped product items
SKUSizeAvailabilityPrice Qty
A105053-10g
10g
In stock
$44.90
A105053-50g
50g
In stock
$196.90
A105053-250g
250g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$616.90
View related series
High-Purity Salts

Basic Description

Specifications & Purity≥99.99% metals basis
Storage TempArgon charged
Shipped InNormal
GradePrimorTrace™
Product Description

Ammonium cerium(IV) nitrate is a very strong oxidizing agent. Ammonium cerium(IV) nitrate is useful as an oxidant for many functional groups (alcohols, phenols, and ethers) as well as C-H bonds, especially those that are benzylic.

Names and Identifiers

WGK Germany 3
UN Number 3085
Packing Group II
Molecular Weight 548.22

Certificates

Certificate of Analysis(COA)

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To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

13 results found

Lot NumberCertificate TypeDateItem
H2414231Certificate of AnalysisAug 01, 2024 A105053
H2414232Certificate of AnalysisAug 01, 2024 A105053
F2406118Certificate of AnalysisMay 08, 2024 A105053
C2428249Certificate of AnalysisMar 16, 2024 A105053
A2402397Certificate of AnalysisDec 15, 2023 A105053
J1522084Certificate of AnalysisJun 06, 2023 A105053
D2311130Certificate of AnalysisMar 25, 2023 A105053
K1829047Certificate of AnalysisSep 20, 2022 A105053
G2222033Certificate of AnalysisJun 17, 2022 A105053
G2222034Certificate of AnalysisJun 17, 2022 A105053
G2222035Certificate of AnalysisJun 17, 2022 A105053
A2219188Certificate of AnalysisJan 05, 2022 A105053
A2219194Certificate of AnalysisJan 05, 2022 A105053

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Chemical and Physical Properties

SolubilitySoluble in water and alcohol.
SensitivityMoisture & Heat sensitive
Melt Point(°C)>400 °C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS05,   GHS07,   GHS03
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H302:Harmful if swallowed

H317:May cause an allergic skin reaction

H272:May intensify fire; oxidizer

H410:Very toxic to aquatic life with long lasting effects

H290:May be corrosive to metals

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P310:Immediately call a POISON CENTER or doctor/physician.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P220:Keep away from clothing and other combustible materials.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P221:Take any precaution to avoid mixing with combustibles/...

P270:Do not eat, drink or smoke when using this product.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P330:Rinse mouth.

P234:Keep only in original container.

P390:Absorb spillage to prevent material damage.

P301+P312:IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.

P406:Store in corrosive resistant/... container with a resistant inner liner.

WGK Germany 3
Class 5.1
Merck Index 1992

Related Documents

References

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2. Vijay Nair,Lakshmi Balagopal,Roshini Rajan,Jessy Mathew.  (2004-01-21)  Recent advances in synthetic transformations mediated by cerium(IV) ammonium nitrate..  Accounts of chemical research,  37  ((1)): (21-30).  [PMID:14730991]
3. Somak Paul,Narayanaswamy Jayaraman.  (2004-09-01)  Catalytic ceric ammonium nitrate mediated synthesis of 2-deoxy-1-thioglycosides..  Carbohydrate research,  339  ((13)): (2197-2204).  [PMID:15337447]
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6. Aliasghar Jarrahpour,Maaroof Zarei.  (2007-11-06)  Synthesis of novel N-(4-ethoxyphenyl) azetidin-2-ones and their oxidative N-deprotection by ceric ammonium nitrate..  Molecules (Basel, Switzerland),  12  ((10)): (2364-2379).  [PMID:17978763]
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8. Naoki Surugaya,Shigeo Taguchi,Soichi Sato,Masaru Watahiki,Toshiaki Hiyama.  (2008-03-12)  Spectrophotometric determination of plutonium in highly radioactive liquid waste using an internal standardization technique with neodymium(III)..  Analytical sciences : the international journal of the Japan Society for Analytical Chemistry,  24  ((3)): (377-380).  [PMID:18332546]
9. David Kesselring,Karl Maurer,Kevin D Moeller.  (2008-08-06)  Microelectrode arrays and ceric ammonium nitrate: a simple strategy for developing new site-selective synthetic methods..  Journal of the American Chemical Society,  130  ((34)): (11290-11291).  [PMID:18680369]
10. Alexander M Jacobine,Weimin Lin,Bethany Walls,Charles K Zercher.  (2008-08-13)  Formation of gamma-lactones through CAN-mediated oxidative cleavage of hemiketals..  The Journal of organic chemistry,  73  ((18)): (7409-7412).  [PMID:18693768]
11. Rasika Tankhiwale,S K Bajpai.  (2009-01-10)  Graft copolymerization onto cellulose-based filter paper and its further development as silver nanoparticles loaded antibacterial food-packaging material..  Colloids and surfaces. B, Biointerfaces,  69  ((2)): (164-168).  [PMID:19131217]
12. D Subhas Bose,Mohd Idrees,N M Jakka,J Venkateswara Rao.  (2009-12-17)  Diversity-oriented synthesis of quinolines via Friedländer annulation reaction under mild catalytic conditions..  Journal of combinatorial chemistry,  12  ((1)): (100-110).  [PMID:20000618]
13. Meng Zhou,Nathan D Schley,Robert H Crabtree.  (2010-08-25)  Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry..  Journal of the American Chemical Society,  132  ((36)): (12550-12551).  [PMID:20731395]
14. Amit H Haviv,Jean-Marc Grenèche,Jean-Paul Lellouche.  (2010-08-26)  Aggregation control of hydrophilic maghemite (gamma-Fe2O3) nanoparticles by surface doping using cerium atoms..  Journal of the American Chemical Society,  132  ((36)): (12519-12521).  [PMID:20735060]
15. Mazaahir Kidwai,Divya Bhatnagar,Rakesh Kumar,Pratibha Mehta Luthra.  (2010-10-12)  Synthesis of 2-oxo/thioxooctahydroquinazolin-5-one derivatives and their evaluation as anticancer agents..  Chemical & pharmaceutical bulletin,  58  ((10)): (1320-1323).  [PMID:20930397]
16. Yue Qi Ye,Hiroyuki Koshino,Naoki Abe,Takemichi Nakamura,Daisuke Hashizume,Shunya Takahashi.  (2010-11-13)  Synthesis of atromentin and its O-alkylated natural products..  Bioscience, biotechnology, and biochemistry,  74  ((11)): (2342-2344).  [PMID:21071857]
17. Myron M Johnson,Jeremy M Naidoo,Manuel A Fernandes,Edwin M Mmutlane,Willem A L van Otterlo,Charles B de Koning.  (2010-11-23)  CAN-mediated oxidations for the synthesis of xanthones and related products..  The Journal of organic chemistry,  75  ((24)): (8701-8704).  [PMID:21086958]
18. Y Suman Reddy,A P John Pal,Preeti Gupta,Alafia A Ansari,Yashwant D Vankar.  (2011-06-18)  Ceric ammonium nitrate-catalyzed azidation of 1,2-anhydro sugars: application in the synthesis of structurally diverse sugar-derived morpholine 1,2,3-triazoles and 1,4-oxazin-2-ones..  The Journal of organic chemistry,  76  ((15)): (5972-5984).  [PMID:21679000]
19. Douglas B Grotjahn,Derek B Brown,Jessica K Martin,David C Marelius,Marie-Caline Abadjian,Hai N Tran,Gregory Kalyuzhny,Kenneth S Vecchio,Zephen G Specht,Sara A Cortes-Llamas,Valentin Miranda-Soto,Christoffel van Niekerk,Curtis E Moore,Arnold L Rheingold.  (2011-11-09)  Evolution of iridium-based molecular catalysts during water oxidation with ceric ammonium nitrate..  Journal of the American Chemical Society,  133  ((47)): (19024-19027).  [PMID:22059883]
20. Weibin Song,Min Lei,Kun Zhao,Lingjun Hu,Yuhui Meng,Dean Guo,Xuan Liu,Lihong Hu.  (2011-11-26)  Ceric ammonium nitrate-promoted oxidative coupling reaction for the synthesis and evaluation of a series of anti-tumor amide anhydrovinblastine analogs..  Bioorganic & medicinal chemistry letters,  22  ((1)): (387-390).  [PMID:22115594]
21. S Sudha,M A Pasha.  (2012-03-09)  Ultrasound assisted synthesis of tetrahydrobenzo[c]xanthene-11-ones using CAN as catalyst..  Ultrasonics sonochemistry,  19  ((5)): (994-998).  [PMID:22398382]
22. Mohammad Mahdi Najafpour,Atefeh Nemati Moghaddam.  (2012-07-19)  Nano-sized manganese oxide: a proposed catalyst for water oxidation in the reaction of some manganese complexes and cerium(IV) ammonium nitrate..  Dalton transactions (Cambridge, England : 2003),  41  ((34)): (10292-10297).  [PMID:22806229]
23. Xiaolin Yu,Shengrui Tong,Maofa Ge,Lingyan Wu,Junchao Zuo,Changyan Cao,Weiguo Song.  (2012-12-12)  Synthesis and characterization of multi-amino-functionalized cellulose for arsenic adsorption..  Carbohydrate polymers,  92  ((1)): (380-387).  [PMID:23218309]
24. Srijita Bharti,Sumit Mishra,Gautam Sen.  (2013-03-19)  Ceric ion initiated synthesis of polyacrylamide grafted oatmeal: Its application as flocculant for wastewater treatment..  Carbohydrate polymers,  93  ((2)): (528-536).  [PMID:23499093]
25. Adushan Pillay,Amanda L Rousseau,Manuel A Fernandes,Charles B de Koning.  (2012-08-24)  The synthesis of the pyranonaphthoquinones dehydroherbarin and anhydrofusarubin using Wacker oxidation methodology as a key step and other unexpected oxidation reactions with ceric ammonium nitrate and salcomine..  Organic & biomolecular chemistry,  10  ((38)): (7809-7819).  [PMID:22915091]

Solution Calculators