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Bis(1,5-cyclooctadiene)nickel(0) - 96%, high purity , CAS No.1295-35-8

11 Citations

≥96%

CAS#: 1295-35-8 View More⌵
Molecular Weight: 275.06
MDL number: MFCD00058902
PubChem CID: 6433264

Item Number

B115561

Grouped product items
SKU	Size	Availability	Price	Qty
B115561-1g	1g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$113.90	+-
B115561-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$435.90	+-
B115561-10g	10g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$783.90	+-

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Element classified compounds (2022) Transition metal compounds (230)

Basic Description

Synonyms	Bis(1,5-cyclooctadiene)nickel (0) \| CS-0035192 \| Bis(cyclooctadiene)nickel(0) \| bis((1Z,5Z)-cycloocta-1,5-diene) nickel \| Ni(COD)2 \| Bis((1,2,5,6-eta)-1,5-cyclooctadiene)nickel \| A805947 \| MFCD00058902 \| Nickel, bis((1,2,5,6-eta)-1,5-cyclooctadiene)- \| Bi
Specifications & Purity	≥96%
Storage Temp	Store at -20°C,Argon charged
Shipped In	Ice chest + Ice pads
Product Description	Reactant for: • Oxidative addition reactions Catalyst for: • Asymmetric α-arylation and heteroarylation of ketones with chloroarenes • Cross-coupling reactions • Regioselective and stereoselective carboxylation/cyclization of allenyl aldehydes under a carbon dioxide atmosphere • Methyl carboxylation of homopropargylic alcohols • Stereoselective borylative ketone-diene coupling • Cycloaddition of benzamides with internal alkynes

AI Insight

Names and Identifiers

IUPAC Name	(1Z,5Z)-cycloocta-1,5-diene;nickel
INCHI	InChI=1S/2C8H12.Ni/c21-2-4-6-8-7-5-3-1;/h21-2,7-8H,3-6H2;/b2*2-1-,8-7-;
InChi Key	JRTIUDXYIUKIIE-KZUMESAESA-N
Canonical SMILES	C1CC=CCCC=C1.C1CC=CCCC=C1.[Ni]
Isomeric SMILES	C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.[Ni]
WGK Germany	3
RTECS	QR6135000
PubChem CID	6433264
UN Number	1325
Packing Group	II
Molecular Weight	275.06
Reaxy-Rn	11341079

Certificates（CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):

Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

14 results found

Lot Number	Certificate Type	Date	Item
F2307214	Certificate of Analysis	Mar 19, 2024	B115561
F2307220	Certificate of Analysis	Mar 19, 2024	B115561
D23061356	Certificate of Analysis	Jan 11, 2024	B115561
K2218219	Certificate of Analysis	Aug 18, 2023	B115561
K2218224	Certificate of Analysis	Aug 18, 2023	B115561
A2203245	Certificate of Analysis	Jul 12, 2023	B115561
F2307219	Certificate of Analysis	May 30, 2023	B115561
D23061349	Certificate of Analysis	Dec 27, 2022	B115561
D23061358	Certificate of Analysis	Dec 27, 2022	B115561
D23061372	Certificate of Analysis	Dec 27, 2022	B115561
K2218191	Certificate of Analysis	Nov 04, 2022	B115561
A2203238	Certificate of Analysis	Oct 20, 2022	B115561
A2203249	Certificate of Analysis	Oct 20, 2022	B115561
H1913180	Certificate of Analysis	Apr 14, 2022	B115561

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Chemical and Physical Properties

Solubility	Soluble in benzene, toluene, terahydrofuran, ether, dimethyl formamide, hexamethylphosphoramide, N-methylpyrrolidinone. Insoluble in water.
Sensitivity	Light & Air & Moisture & heat Sensitive
Melt Point(°C)	60°C
Molecular Weight	275.050 g/mol
XLogP3
Hydrogen Bond Donor Count	0
Hydrogen Bond Acceptor Count	0
Rotatable Bond Count	0
Exact Mass	274.123 Da
Monoisotopic Mass	274.123 Da
Topological Polar Surface Area	0.000 Å²
Heavy Atom Count	17
Formal Charge	0
Complexity	72.600
Isotope Atom Count	0
Defined Atom Stereocenter Count	0
Undefined Atom Stereocenter Count	0
Defined Bond Stereocenter Count	4
Undefined Bond Stereocenter Count	0
The total count of all stereochemical bonds	4
Covalently-Bonded Unit Count	3

Safety and Hazards(GHS)

Pictogram(s)	GHS08, GHS07, GHS02
Signal	Danger
Hazard Statements	H351:Suspected of causing cancer H317:May cause an allergic skin reaction H334:May cause allergy or asthma symptoms or breathing difficulties if inhaled H228:Flammable solid H350:May cause cancer
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P240:Ground/bond container and receiving equipment. P284:[In case of inadequate ventilation] Wear respiratory protection. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P203:Obtain, read and follow all safety instructions before use. P318:if exposed or concerned, get medical advice. P342+P316:If experiencing respiratory symptoms: Get emergence medical help immediately.
WGK Germany	3
RTECS	QR6135000
Reaxy-Rn	11341079
Class	4.1
RIDADR	UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all

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Citations of This Product(11)

How to Cite Aladdin Scientific Products?

1. Yang Zhang, Rui Feng, Zhuo Chen, Tingting Zhao, Yanyun Ju, Shengliao Yan, Shaokun Song, Guanghui Zhao, Lijie Dong. (2021) Significantly enhancing energy storage performances of flexible dielectric film by introducing poly(1,4-anthraquinone). EUROPEAN POLYMER JOURNAL, 152 (110486). [PMID:] [10.1016/j.eurpolymj.2021.110486]
2. Jialing Kang, Mengjia Wang, Chenbao Lu, Changchun Ke, Pan Liu, Jinhui Zhu, Feng Qiu, Xiaodong Zhuang. (2020) Platinum Atoms and Nanoparticles Embedded Porous Carbons for Hydrogen Evolution Reaction. Materials, 13 (7): (1513). [PMID:32224913] [10.3390/ma13071513]
3. Xin Min, Xiaodong Fan. (2019) A New Strategy for the Synthesis of Hydroxyl Terminated Polystyrene-b-Polybutadiene-b-Polystyrene Triblock Copolymer with High Cis-1, 4 Content. Polymers, 11 (4): (598). [PMID:30960582] [10.3390/polym11040598]
4. Danyang Zhao, Yuyang Tian, Xiaofei Jing, Yun Lu, Guangshan Zhu. (2018) PAF-1@cellulose nanofibril composite aerogel for highly-efficient removal of bisphenol A. Journal of Materials Chemistry A, 7 (1): (157-164). [PMID:] [10.1039/C8TA09644A]
5. Zhen Wang, Sen Yan, Huang-Chen Cui, Guang Cheng, Hui Ma, Qing-Mei Zhang, Qing-Pu Zhang, Jun-Min Liu, Bien Tan, Chun Zhang. (2018) Porous Organic Polymer from Aggregation-Induced Emission Macrocycle for White-Light Emission. MACROMOLECULES, 51 (19): (7863–7871). [PMID:] [10.1021/acs.macromol.8b01632]
6. Jiajia Niu, Xiaolei Zhao, Yuanyuan Jin, Guotao Yang, Zhonghao Li, Juanjuan Wang, Ruiqi Zhao, Zhongyue Li. (2018) Determination of aromatic amines in the urine of smokers using a porous organic framework (JUC-Z2)-coated solid-phase microextraction fiber. JOURNAL OF CHROMATOGRAPHY A, 1555 (37). [PMID:29728266] [10.1016/j.chroma.2018.04.059]
7. Yang Tang, Song-Qing Zhao, Na Liu, Zong-Quan Wu. (2018) Facile synthesis of stereoregular helical poly(phenyl isocyanide)s and poly(3-hexylthiophene)-block-poly(phenyl isocyanide) copolymer using chiral π-allylnickel complexes as initiators. POLYMER, 142 (52). [PMID:] [10.1016/j.polymer.2018.03.024]
8. Ji Pinjun, Guo Lihua, Hu Xiaohui, Li Weimin. (2017) Ethylene polymerization by salicylaldimine Nickel(II) complexes derived from arylnaphthylamine. JOURNAL OF POLYMER RESEARCH, 24 (2): (1-9). [PMID:] [10.1007/s10965-017-1190-y]
9. Xiaohui Hu, Shengyu Dai, Changle Chen. (2016) Ethylene polymerization by salicylaldimine nickel(II) complexes containing a dibenzhydryl moiety. DALTON TRANSACTIONS, 45 (4): (1496-1503). [PMID:26673739] [10.1039/C5DT04408A]
10. Mingxue Wu, Gang Chen, Ping Liu, Weihong Zhou, Qiong Jia. (2015) Preparation of porous aromatic framework/ionic liquid hybrid composite coated solid-phase microextraction fibers and their application in the determination of organochlorine pesticides combined with GC-ECD detection. ANALYST, 141 (1): (243-250). [PMID:26579991] [10.1039/C5AN01372K]
11. Yuan-Yuan Zhu, Ting-Ting Yin, Xue-Liang Li, Ming Su, Ya-Xin Xue, Zhi-Peng Yu, Na Liu, Jun Yin, Zong-Quan Wu. (2014) Synthesis and Chiroptical Properties of Helical Polyallenes Bearing Chiral Amide Pendants. MACROMOLECULES, 47 (20): (7021–7029). [PMID:] [10.1021/ma5019022]

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19. Yang Zhang, Rui Feng, Zhuo Chen, Tingting Zhao, Yanyun Ju, Shengliao Yan, Shaokun Song, Guanghui Zhao, Lijie Dong. (2021) Significantly enhancing energy storage performances of flexible dielectric film by introducing poly(1,4-anthraquinone). EUROPEAN POLYMER JOURNAL, 152 (110486). [PMID:] [10.1016/j.eurpolymj.2021.110486]
20. Jialing Kang, Mengjia Wang, Chenbao Lu, Changchun Ke, Pan Liu, Jinhui Zhu, Feng Qiu, Xiaodong Zhuang. (2020) Platinum Atoms and Nanoparticles Embedded Porous Carbons for Hydrogen Evolution Reaction. Materials, 13 (7): (1513). [PMID:32224913] [10.3390/ma13071513]
21. Xin Min, Xiaodong Fan. (2019) A New Strategy for the Synthesis of Hydroxyl Terminated Polystyrene-b-Polybutadiene-b-Polystyrene Triblock Copolymer with High Cis-1, 4 Content. Polymers, 11 (4): (598). [PMID:30960582] [10.3390/polym11040598]
22. Danyang Zhao, Yuyang Tian, Xiaofei Jing, Yun Lu, Guangshan Zhu. (2018) PAF-1@cellulose nanofibril composite aerogel for highly-efficient removal of bisphenol A. Journal of Materials Chemistry A, 7 (1): (157-164). [PMID:] [10.1039/C8TA09644A]
23. Zhen Wang, Sen Yan, Huang-Chen Cui, Guang Cheng, Hui Ma, Qing-Mei Zhang, Qing-Pu Zhang, Jun-Min Liu, Bien Tan, Chun Zhang. (2018) Porous Organic Polymer from Aggregation-Induced Emission Macrocycle for White-Light Emission. MACROMOLECULES, 51 (19): (7863–7871). [PMID:] [10.1021/acs.macromol.8b01632]
24. Jiajia Niu, Xiaolei Zhao, Yuanyuan Jin, Guotao Yang, Zhonghao Li, Juanjuan Wang, Ruiqi Zhao, Zhongyue Li. (2018) Determination of aromatic amines in the urine of smokers using a porous organic framework (JUC-Z2)-coated solid-phase microextraction fiber. JOURNAL OF CHROMATOGRAPHY A, 1555 (37). [PMID:29728266] [10.1016/j.chroma.2018.04.059]
25. Yang Tang, Song-Qing Zhao, Na Liu, Zong-Quan Wu. (2018) Facile synthesis of stereoregular helical poly(phenyl isocyanide)s and poly(3-hexylthiophene)-block-poly(phenyl isocyanide) copolymer using chiral π-allylnickel complexes as initiators. POLYMER, 142 (52). [PMID:] [10.1016/j.polymer.2018.03.024]
26. Ji Pinjun, Guo Lihua, Hu Xiaohui, Li Weimin. (2017) Ethylene polymerization by salicylaldimine Nickel(II) complexes derived from arylnaphthylamine. JOURNAL OF POLYMER RESEARCH, 24 (2): (1-9). [PMID:] [10.1007/s10965-017-1190-y]
27. Xiaohui Hu, Shengyu Dai, Changle Chen. (2016) Ethylene polymerization by salicylaldimine nickel(II) complexes containing a dibenzhydryl moiety. DALTON TRANSACTIONS, 45 (4): (1496-1503). [PMID:26673739] [10.1039/C5DT04408A]
28. Mingxue Wu, Gang Chen, Ping Liu, Weihong Zhou, Qiong Jia. (2015) Preparation of porous aromatic framework/ionic liquid hybrid composite coated solid-phase microextraction fibers and their application in the determination of organochlorine pesticides combined with GC-ECD detection. ANALYST, 141 (1): (243-250). [PMID:26579991] [10.1039/C5AN01372K]
29. Yuan-Yuan Zhu, Ting-Ting Yin, Xue-Liang Li, Ming Su, Ya-Xin Xue, Zhi-Peng Yu, Na Liu, Jun Yin, Zong-Quan Wu. (2014) Synthesis and Chiroptical Properties of Helical Polyallenes Bearing Chiral Amide Pendants. MACROMOLECULES, 47 (20): (7021–7029). [PMID:] [10.1021/ma5019022]

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