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Benzyl 2,2,2-Trichloroacetimidate - >97.0%(GC), high purity , CAS No.81927-55-1

  • ≥97%(GC)
Item Number
B140280
Grouped product items
SKUSizeAvailabilityPrice Qty
B140280-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$27.90
B140280-10g
10g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$42.90
B140280-25g
25g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$82.90
B140280-100g
100g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$297.90

Discover Benzyl 2,2,2-Trichloroacetimidate by Aladdin Scientific in >97.0%(GC) for only $27.90. Available - in Ligands at Aladdin Scientific. Tags: C-X (non halogen) bonding reaction, Deprotection, Derivatization, Protection.

Basic Description

SynonymsBenzyl 2,2,2-trichloroacetimidate|81927-55-1|benzyl 2,2,2-trichloroethanimidate|Benzyl trichloroacetimidate|Benzyltrichloroacetimidate|benzyl trichloroacetoimidate|MFCD00000805|Trichloroacetimidic Acid Benzyl Ester|benzyl 2,2,2-trichloroethanecarboximidat
Specifications & Purity>97.0%(GC)
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

Benzyl 2,2,2-trichloroacetimidate was used as reagent during the synthesis of funiculosin dimethyl ether1 and (S)-3-(benzyloxy)-2-methylpropanal2. It was used in the acid-catalyzed benzylation of hydroxy groups3.

Names and Identifiers

IUPAC Name benzyl 2,2,2-trichloroethanimidate
INCHI InChI=1S/C9H8Cl3NO/c10-9(11,12)8(13)14-6-7-4-2-1-3-5-7/h1-5,13H,6H2
InChi Key HUZCTWYDQIQZPM-UHFFFAOYSA-N
Canonical SMILES C1=CC=C(C=C1)COC(=N)C(Cl)(Cl)Cl
Isomeric SMILES C1=CC=C(C=C1)COC(=N)C(Cl)(Cl)Cl
WGK Germany 3
PubChem CID 144968
Molecular Weight 252.52
Beilstein 2525375
Reaxy-Rn 2525375

Certificates

Certificate of Analysis(COA)

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5 results found

Lot NumberCertificate TypeDateItem
H1604086Certificate of AnalysisMar 08, 2024 B140280
H2301273Certificate of AnalysisJul 07, 2023 B140280
H2301284Certificate of AnalysisJul 07, 2023 B140280
H2231205Certificate of AnalysisJun 22, 2022 B140280
H2231206Certificate of AnalysisJun 22, 2022 B140280

Chemical and Physical Properties

SolubilityMiscible with cyclohexane/dichloromethane.
SensitivityHeat & Moisture &light sensitive
Refractive Index1.5430-1.5470
Flash Point(°F)235.4 °F
Flash Point(°C)113 °C
Boil Point(°C)150°C/1mmHg

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H302:Harmful if swallowed

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P317:IF SWALLOWED: Get medical help.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3
Reaxy-Rn 2525375

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