Basic Description

Synonyms	(Z)-4-hydroxypent-3-en-2-one;manganese \| Acetylacetone manganese(ii)salt \| MFCD00000022 \| Manganese(2+);(E)-4-oxopent-2-en-2-olate \| Manganese(II) acetylacetonate \| AKOS002375112 \| Mn(acac)2 \| E76385
Specifications & Purity	≥97%
Shipped In	Normal
Product Description	Manganese(II) acetylacetonate (Mn(acac)2) is a transition metal acetylacetonate that is trimeric in hydrocarbon solvents. It is monomeric and tetrahedral in its vapor state. It shows Mn-O bond energy of 65 kcal mol-1. It can be used with potassium permanganate in preparation of manganese triad (Mn(acac)3)

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Names and Identifiers

Pubchem Sid	488197724
Pubchem Sid Url	https://pubchem.ncbi.nlm.nih.gov/substance/488197724
IUPAC Name	(Z)-4-hydroxypent-3-en-2-one;manganese
INCHI	InChI=1S/2C5H8O2.Mn/c21-4(6)3-5(2)7;/h23,6H,1-2H3;/b2*4-3-;
InChi Key	VNNDVNZCGCCIPA-FDGPNNRMSA-N
Canonical SMILES	CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Mn]
Isomeric SMILES	C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.[Mn]
RTECS	OO9350000
PubChem CID	11780020
Molecular Weight	253.16(as Anhydrous)

Certificates（CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):

Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

12 results found

Lot Number	Certificate Type	Date	Item
G2425130	Certificate of Analysis	Mar 26, 2024	B152272
G2425131	Certificate of Analysis	Mar 26, 2024	B152272
H2413442	Certificate of Analysis	Mar 26, 2024	B152272
B2520018	Certificate of Analysis	Sep 03, 2022	B152272
E2330067	Certificate of Analysis	Sep 03, 2022	B152272
E2330078	Certificate of Analysis	Sep 03, 2022	B152272
K2209334	Certificate of Analysis	Sep 03, 2022	B152272
K2209343	Certificate of Analysis	Sep 03, 2022	B152272
K2209344	Certificate of Analysis	Sep 03, 2022	B152272
K2209353	Certificate of Analysis	Sep 03, 2022	B152272
K2209354	Certificate of Analysis	Sep 03, 2022	B152272
K2307246	Certificate of Analysis	Sep 03, 2022	B152272

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Chemical and Physical Properties

Solubility	Slightly soluble in water; Slightly soluble in Acetone,Alcohol
Sensitivity	Moisture sensitive.
Melt Point(°C)	248-250°C

Safety and Hazards(GHS)

Pictogram(s)	GHS08, GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H351:Suspected of causing cancer H302:Harmful if swallowed H312:Harmful in contact with skin H332:Harmful if inhaled
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P203:Obtain, read and follow all safety instructions before use. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P318:if exposed or concerned, get medical advice. P317:Get emergency medical help. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell.
RTECS	OO9350000

Reviews

Citations of This Product(5)

How to Cite Aladdin Scientific Products?

1. Yan Lin, Kaian Sun, Xiaomeng Chen, Chen Chen, Yuan Pan, Xiyou Li, Jun Zhang. (2021) High-precision regulation synthesis of Fe-doped Co2P nanorod bundles as efficient electrocatalysts for hydrogen evolution in all-pH range and seawater. Journal of Energy Chemistry, 55 (92). [PMID:] [10.1016/j.jechem.2020.06.073]
2. Weien Lai, Peng Huang, Beatriz Pelaz, Pablo del Pino, Qian Zhang. (2017) Enhanced All-Optical Modulation of Terahertz Waves on the Basis of Manganese Ferrite Nanoparticles. Journal of Physical Chemistry C, 121 (39): (21634–21640). [PMID:] [10.1021/acs.jpcc.7b07756]
3. Qian Zhang, Ting Yin, Guo Gao, Joseph G. Shapter, Weien Lai, Peng Huang, Wen Qi, Jie Song, Daxiang Cui. (2017) Multifunctional Core@Shell Magnetic Nanoprobes for Enhancing Targeted Magnetic Resonance Imaging and Fluorescent Labeling in Vitro and in Vivo. ACS Applied Materials & Interfaces, 9 (21): (17777–17785). [PMID:28488429] [10.1021/acsami.7b04288]
4. Chuan Ding, Yanwei Zeng, Liangliang Cao, Rongjie Li, Yuan Zhang, Longfei Zhao. (2016) Dopant-induced shape evolution of polyhedral magnetite nanocrystals and their morphology/component-dependent high-rate electrochemical performance for lithium-ion batteries. RSC Advances, 6 (58): (53331-53338). [PMID:] [10.1039/C6RA06257A]
5. Yang Zhang, Jinchao Shen, Hong Yang, Yan Yang, Zhiguo Zhou, Shiping Yang. (2015) A highly selective magnetic sensor for Cd2+ in living cells with (Zn, Mn)-doped iron oxide nanoparticles. SENSORS AND ACTUATORS B-CHEMICAL, 207 (887). [PMID:] [10.1016/j.snb.2014.10.074]

References

1. Yan Lin, Kaian Sun, Xiaomeng Chen, Chen Chen, Yuan Pan, Xiyou Li, Jun Zhang. (2021) High-precision regulation synthesis of Fe-doped Co2P nanorod bundles as efficient electrocatalysts for hydrogen evolution in all-pH range and seawater. Journal of Energy Chemistry, 55 (92). [PMID:] [10.1016/j.jechem.2020.06.073]
2. Weien Lai, Peng Huang, Beatriz Pelaz, Pablo del Pino, Qian Zhang. (2017) Enhanced All-Optical Modulation of Terahertz Waves on the Basis of Manganese Ferrite Nanoparticles. Journal of Physical Chemistry C, 121 (39): (21634–21640). [PMID:] [10.1021/acs.jpcc.7b07756]
3. Qian Zhang, Ting Yin, Guo Gao, Joseph G. Shapter, Weien Lai, Peng Huang, Wen Qi, Jie Song, Daxiang Cui. (2017) Multifunctional Core@Shell Magnetic Nanoprobes for Enhancing Targeted Magnetic Resonance Imaging and Fluorescent Labeling in Vitro and in Vivo. ACS Applied Materials & Interfaces, 9 (21): (17777–17785). [PMID:28488429] [10.1021/acsami.7b04288]
4. Chuan Ding, Yanwei Zeng, Liangliang Cao, Rongjie Li, Yuan Zhang, Longfei Zhao. (2016) Dopant-induced shape evolution of polyhedral magnetite nanocrystals and their morphology/component-dependent high-rate electrochemical performance for lithium-ion batteries. RSC Advances, 6 (58): (53331-53338). [PMID:] [10.1039/C6RA06257A]
5. Yang Zhang, Jinchao Shen, Hong Yang, Yan Yang, Zhiguo Zhou, Shiping Yang. (2015) A highly selective magnetic sensor for Cd2+ in living cells with (Zn, Mn)-doped iron oxide nanoparticles. SENSORS AND ACTUATORS B-CHEMICAL, 207 (887). [PMID:] [10.1016/j.snb.2014.10.074]

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SKU	Size	Availability	Price	Qty
B152272-5g	5g	5	$22.90	+-
B152272-25g	25g	4	$85.90	+-
B152272-100g	100g	2	$307.90	+-
B152272-250g	250g	2	$692.90	+-
B152272-500g	500g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$1,246.90	+-

Bis(2,4-pentanedionato)manganese Dihydrate - 97%, high purity , CAS No.14024-58-9