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Bis(dimethylamino)phosphoryl Chloride - >93.0%(GC), high purity , CAS No.1605-65-8
Basic Description Synonyms 1605-65-8|Bis(dimethylamino)phosphoryl Chloride|N,N,N',N'-Tetramethylphosphorodiamidic chloride|Phosphorodiamidic chloride, tetramethyl-|Bis(N,N-dimethylamino)phosphinic chloride|Bis(dimethylamido)phosphoric chloride|Bis(dimethylamino)phosphorylchloride|b Specifications & Purity >93.0%(GC) Storage Temp Store at 2-8°C,Argon charged Shipped In Wet ice Product Description N,N,N′,N′-Tetramethylphosphorodiamidic chloride was used in the synthesis of (-)-allohedycaryol and C2-symmetric binaphthyl phosphortriamide. It was also used in total synthesis of neohedycaryol.
Names and Identifiers IUPAC Name N-[chloro(dimethylamino)phosphoryl]-N-methylmethanamine INCHI InChI=1S/C4H12ClN2OP/c1-6(2)9(5,8)7(3)4/h1-4H3 InChi Key WYLQARGYFXBZMD-UHFFFAOYSA-N Canonical SMILES CN(C)P(=O)(N(C)C)Cl Isomeric SMILES CN(C)P(=O)(N(C)C)Cl WGK Germany 3 PubChem CID 74150 Molecular Weight 170.58 Beilstein 471430 Reaxy-Rn 471430
Chemical and Physical Properties Sensitivity Moisture sensitive Refractive Index 1.4679 Flash Point(°F) 246°F Flash Point(°C) 119℃ Boil Point(°C) 246-247℃
Safety and Hazards(GHS) Pictogram(s) GHS05 Signal Danger Hazard Statements H314: Causes severe skin burns and eye damage
H318: Causes serious eye damage
Precautionary Statements P280: Wear protective gloves/protective clothing/eye protection/face protection.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P264+P265: Wash hands [and …] thoroughly after handling. Do not touch eyes.
P305+P354+P338: IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P317: Get emergency medical help.
P302+P361+P354: IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.
P316: Get emergency medical help immediately.
WGK Germany 3 Reaxy-Rn 471430
References 1. Vladimir N. Zhabinskii, Adriaan J. Minnaard, Joannes B. P. A. Wijnberg, Aede de Groot,. (1996-06-14) Relative and Absolute Configuration of Allohedycaryol. Enantiospecific Total Synthesis of Its Enantiomer.. The Journal of organic chemistry, 61 ((12)): ( 4022-4027 ). [PMID:11667277 ]
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