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Bis(trifluoromethane)sulfonimide lithium salt - 98%, high purity , CAS No.90076-65-6

  • ≥98%
Item Number
B434520
Grouped product items
SKUSizeAvailabilityPrice Qty
B434520-5g
5g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$24.90
B434520-10g
10g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$29.90
B434520-50g
50g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$109.90
B434520-250g
250g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$436.90

Basic Description

Synonyms90076-65-6|Lithium Bis(trifluoromethanesulfonyl)imide|Lithium bis((trifluoromethyl)sulfonyl)azanide|lithium bis(trifluoromethanesulphonyl)imide|Bis(trifluoromethane)sulfonimide lithium salt|Lithium bis((trifluoromethyl)sulfonyl)amide|Lithium Triflimide|Li
Specifications & Purity≥98%
Product Description

Application

Bis(trifluoromethane)sulfonimide lithium salt (Li-TFSI) can be used: As a chemical additive for improving the power conversion efficiencies in porphyrin-based organic solar cells. As a reagent in the preparation of imidazolium core bearing monomer ionic liquids to develop polymerized ionic liquids. For the preparation of a chiral imidazolium salt via anion metathesis of the corresponding triflate. In the synthesis of solid polymer electrolytes for lithium-ion batteries. In the synthesis of polyelectrolyte reusable homogenous catalysts, which are used in the Diels–Alder reactions between isoprene and a variety of dienophiles. Used in the preparation of electrolytes for lithium batteries and novel rare-earth Lewis acid catalysts.


Other Notes

For a review on fluorine containing nitrogen acids, see Coordination Chemistry Reviews.

Names and Identifiers

IUPAC Name lithium;bis(trifluoromethylsulfonyl)azanide
INCHI InChI=1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
InChi Key QSZMZKBZAYQGRS-UHFFFAOYSA-N
Canonical SMILES [Li+].C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
Isomeric SMILES [Li+].C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
WGK Germany 2
PubChem CID 3816071
UN Number 2923
Packing Group II
Molecular Weight 287.09
Beilstein 6625414
Reaxy-Rn 6625414

Certificates

Certificate of Analysis(COA)

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6 results found

Lot NumberCertificate TypeDateItem
E2423059Certificate of AnalysisJun 01, 2024 B434520
E2423057Certificate of AnalysisJun 01, 2024 B434520
E2423056Certificate of AnalysisMay 29, 2024 B434520
E2422265Certificate of AnalysisMar 23, 2024 B434520
A2412095Certificate of AnalysisFeb 01, 2024 B434520
A2412096Certificate of AnalysisJan 18, 2024 B434520

Chemical and Physical Properties

Melt Point(°C)231.0 to 237.0 °C

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS08,   GHS05
Signal Danger
Hazard Statements

H301:Toxic if swallowed

H311:Toxic in contact with skin

H373:Causes damage to organs through prolonged or repeated exposure

H314:Causes severe skin burns and eye damage

H412:Harmful to aquatic life with long lasting effects

Precautionary Statements

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P270:Do not eat, drink or smoke when using this product.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P330:Rinse mouth.

P361+P364:Take off immediately all contaminated clothing and wash it before reuse.

P301+P316:IF SWALLOWED: Get emergency medical help immediately.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

P319:Get medical help if you feel unwell.

WGK Germany 2
Reaxy-Rn 6625414
Class 6.1(8)
RIDADR UN 2923 6.1(8) / PGII

Related Documents

References

1. C Roux,W Gorecki,J Y Sanchez,M Jeannin,E Belorizky.  (1999-01-01)  Physical properties of [Formula: see text] polymer electrolytes: nuclear magnetic resonance investigation and comparison with [Formula: see text]..  Journal of physics. Condensed matter : an Institute of Physics journal,  ((38)): (7005-7017).  [PMID:22146538]
2. Yoshiyuki Gambe,Yan Sun,Itaru Honma.  (2015-03-10)  Development of bipolar all-solid-state lithium battery based on quasi-solid-state electrolyte containing tetraglyme-LiTFSA equimolar complex..  Scientific reports,  (8869-8869).  [PMID:25746860]
3. Lizhen Qiao,Xianzhe Shi,Xin Lu,Guowang Xu.  (2015-04-22)  Preparation and evaluation of surface-bonded tricationic ionic liquid silica as stationary phases for high-performance liquid chromatography..  Journal of chromatography. A,  1396  (62-71).  [PMID:25890438]
4. Soumyadip Choudhury,Mukesh Agrawal,Petr Formanek,Dieter Jehnichen,Dieter Fischer,Beate Krause,Victoria Albrecht,Manfred Stamm,Leonid Ionov.  (2015-05-28)  Nanoporous Cathodes for High-Energy Li-S Batteries from Gyroid Block Copolymer Templates..  ACS nano,  ((6)): (6147-6157).  [PMID:26014100]

Solution Calculators