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Bis(triphenylphosphine)nickel(II) dichloride - 99.99% trace metals basis, high purity , CAS No.14264-16-5
Basic Description
Synonyms | 14264-16-5|Bis(triphenylphosphine)nickel(II)chloride|Bis(triphenylphosphine)nickel(II) dichloride|dichloronickel;triphenylphosphane|NiCl2(PPh3)2|Dichlorobis(triphenylphosphine)nickel(II)|Bis(triphenylphosphine)nickel(II) chloride|dichloronickel; triphenyl |
Specifications & Purity | 99.99% trace metals basis |
Grade | PrimorTrace™ |
Product Description | Application Ni(PPh 3 ) 2 Cl 2 may be used to undertake nickel assisted phosphination of biaryl O,N triflates with chlorodiphenylphosphine. |
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Names and Identifiers
IUPAC Name | dichloronickel;triphenylphosphane |
INCHI | InChI=1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2 |
InChi Key | ZBRJXVVKPBZPAN-UHFFFAOYSA-L |
Canonical SMILES | C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ni]Cl |
Isomeric SMILES | C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ni]Cl |
WGK Germany | 3 |
RTECS | QR6170000 |
PubChem CID | 498315 |
Molecular Weight | 654.17 |
Reaxy-Rn | 14619310 |
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Chemical and Physical Properties
Safety and Hazards(GHS)
Pictogram(s) | GHS08, GHS07 |
Signal | Danger |
Hazard Statements | H412:Harmful to aquatic life with long lasting effects H317:May cause an allergic skin reaction H350:May cause cancer |
Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P270:Do not eat, drink or smoke when using this product. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P203:Obtain, read and follow all safety instructions before use. P301+P317:IF SWALLOWED: Get medical help. P318:if exposed or concerned, get medical advice. |
WGK Germany | 3 |
RTECS | QR6170000 |
Reaxy-Rn | 14619310 |
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