Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine. Bismuth(III) chloride may be used as a catalyst in the following processes: · Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols. · Preparation of thiiranes from oxiranes using ammonium thiocyanate. · Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates. · Allylation of secondary benzyl alcohols with allyltrimethylsilane. · [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles.
1.Yunqing Zhu, Lang Fan, Bo Yang, Jianzhong Du,. (2014-04-09) Multifunctional homopolymer vesicles for facile immobilization of gold nanoparticles and effective water remediation.. ACS nano, 8 ((5)):( 5022-5031 ). [PMID:24708437]
2.Jie-Ling Xie,Zhao-Qian Huang,Bin Wang,Wei-Jun Chen,Wen-Xiu Lu,Xin Liu,Jun-Ling Song. (2019-03-23) New lead-free perovskite Rb7Bi3Cl16 nanocrystals with blue luminescence and excellent moisture-stability.. Nanoscale, 11 ((14)):(6719-6726). [PMID:30900701]
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