Basic Description

Synonyms	tribromobismuthine \| TXKAQZRUJUNDHI-UHFFFAOYSA-K \| UNII-DT59198T2X \| Bismuth(III) bromide, anhydrous, beads, 99.999% trace metals basis \| BiBr3 \| Bismuth(III) bromide \| Q2614358 \| Bismuth(III) bromide, anhydrous, powder, 99.999% trace metals basis \| BISMU
Specifications & Purity	anhydrous, ≥99.998% metals basis, powder
Grade	anhydrous
Product Description	Application Catalyzes the formation of cyclic carbonates, which are important precursors for polycarbonates and other polymeric materials.

Names and Identifiers

IUPAC Name	tribromobismuthane
INCHI	InChI=1S/Bi.3BrH/h;3*1H/q+3;;;/p-3
InChi Key	TXKAQZRUJUNDHI-UHFFFAOYSA-K
Canonical SMILES	Br[Bi](Br)Br
Isomeric SMILES	Br[Bi](Br)Br
WGK Germany	3
PubChem CID	82232
UN Number	3260
Molecular Weight	448.69

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Chemical and Physical Properties

Boil Point(°C)	453°
Melt Point(°C)	218°

Safety and Hazards(GHS)

Pictogram(s)	GHS05
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	3
RIDADR	UN 3260 8 / PGII

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Zhijie Zhang, Xuesheng Wang, Huiling Tang, Deben Li, Jiayue Xu. (2023) Modulation of Fermi level gap and internal electric field over Cs3Bi2Br9@VO-In2O3 S-scheme heterojunction for boosted charge separation and CO2 photoconversion. CHINESE JOURNAL OF CATALYSIS, 55 (227). [PMID:] [10.1016/S1872-2067(23)64549-8]
2. Shuaiqi Zhao, Xiaolei Yang, Yumeng Ge, Hongbin Zhang, Jie Li, Keyu Han, Shiqing Xu, Gongxun Bai. (2023) Uniform incorporation of two-dimensional BiOBr into perovskite crystals and films to enhance photoluminescence. CERAMICS INTERNATIONAL, [PMID:] [10.1016/j.ceramint.2023.12.001]
3. Jiexiang Tong, Subin Xie, Jia-Tao Miao, Jing Luo, Ren Liu. (2024) A novel method to synthesize polyurethane-urea acrylate with high strength and toughness. PROGRESS IN ORGANIC COATINGS, 186 (16): (108006). [PMID:19706601] [10.1016/j.porgcoat.2023.108006]
4. Zhigang Li, Yuanjie Sun, Hongtao Zhao. (2023) Enhanced optical properties of lead-free double perovskite Cs2AgBiBr6 nanocrystals by doping of Na ions. SOLID STATE COMMUNICATIONS, 373-374 (115288). [PMID:] [10.1016/j.ssc.2023.115288]
5. An Hou, Liubing Fan, Yan Xiong, Jiawei Lin, Kunjie Liu, Mingyue Chen, Zhongnan Guo, Jing Zhao, Quanlin Liu. (2023) Zero-Dimensional Halides with ns2 Electron (Sb3+) Activation to Generate Broad Photoluminescence. INORGANIC CHEMISTRY, 62 (31): (12501–12509). [PMID:37478468] [10.1021/acs.inorgchem.3c01726]
6. Lan Ding, Yongping Ding, Fenghua Bai, Gonglai Chen, Shuwei Zhang, Xiaoxue Yang, Huiqin Li, Xiaojing Wang. (2023) In Situ Growth of Cs3Bi2Br9 Quantum Dots on Bi-MOF Nanosheets via Cosharing Bismuth Atoms for CO2 Capture and Photocatalytic Reduction. INORGANIC CHEMISTRY, 62 (5): (2289–2303). [PMID:36692474] [10.1021/acs.inorgchem.2c04041]
7. Jian Ma, Congjie Liang, Changjiang Yu, Huaming Li, Hui Xu, Yingjie Hua, Chongtai Wang. (2023) BiOBr microspheres anchored with Cu2O nanoparticles and rGO: A Z-scheme heterojunction photocatalyst for efficient reduction of Cr(VI) under visible light irradiation. APPLIED SURFACE SCIENCE, 609 (155247). [PMID:] [10.1016/j.apsusc.2022.155247]
8. Zihao Cui, Yaqiang Wu, Shuhui Zhang, Hui Fu, Guoqiang Chen, Zaizhu Lou, Xiaolei Liu, Qianqian Zhang, Zeyan Wang, Zhaoke Zheng, Hefeng Cheng, Yuanyuan Liu, Ying Dai, Baibiao Huang, Peng Wang. (2023) Insight into a strategy to improve charge carrier migration in lead-free bismuth-based halide perovskite for efficient selective oxidation of thioanisole under visible light. CHEMICAL ENGINEERING JOURNAL, 451 (138927). [PMID:] [10.1016/j.cej.2022.138927]
9. Lijun Wu, Song Zheng, Heng Lin, Shun Zhou, Ahmed Mahmoud Idris, Jin Wang, Sheng Li, Zhengquan Li. (2023) In-situ assembling 0D/2D Z-scheme heterojunction of Lead-free Cs2AgBiBr6/Bi2WO6 for enhanced photocatalytic CO2 reduction. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 629 (233). [PMID:36081204] [10.1016/j.jcis.2022.08.152]
10. Lan Ding, Fenghua Bai, Burenbayaer Borjigin, Yuning Li, Huiqin Li, Xiaojing Wang. (2022) Embedding Cs2AgBiBr6 QDs into Ce-UiO-66-H to in situ construct a novel bifunctional material for capturing and photocatalytic reduction of CO2. CHEMICAL ENGINEERING JOURNAL, 446 (137102). [PMID:] [10.1016/j.cej.2022.137102]
11. Zihao Cui, Peng Wang, Yaqiang Wu, Xiaolei Liu, Guoqiang Chen, Peng Gao, Qianqian Zhang, Zeyan Wang, Zhaoke Zheng, Hefeng Cheng, Yuanyuan Liu, Ying Dai, Baibiao Huang. (2022) Space-confined growth of lead-free halide perovskite Cs3Bi2Br9 in MCM-41 molecular sieve as an efficient photocatalyst for CO2 reduction at the gas−solid condition under visible light. APPLIED CATALYSIS B-ENVIRONMENTAL, 310 (121375). [PMID:] [10.1016/j.apcatb.2022.121375]
12. Anjli Sharma, Sanjeev Kumar Kanth, Shishi Xu, Ni Han, Lei Zhu, Lele Fan, Chao Liu, Qinfang Zhang. (2022) Visible light driven g-C3N4/Bi4NbO8X (XCl, Br) heterojunction photocatalyst for the degradation of organic pollutants. JOURNAL OF ALLOYS AND COMPOUNDS, 895 (162576). [PMID:] [10.1016/j.jallcom.2021.162576]
13. Chenkai Deng, Shiqiang Hao, Kunjie Liu, Maxim S. Molokeev, Christopher Wolverton, Liubing Fan, Guojun Zhou, Da Chen, Jing Zhao, Quanlin Liu. (2021) Broadband light emitting zero-dimensional antimony and bismuth-based hybrid halides with diverse structures. Journal of Materials Chemistry C, 9 (44): (15942-15948). [PMID:] [10.1039/D1TC04198C]
14. Da Chen, Shiqiang Hao, Liubing Fan, Yangwu Guo, Jiyong Yao, Christopher Wolverton, Mercouri G. Kanatzidis, Jing Zhao, Quanlin Liu. (2021) Broad Photoluminescence and Second-Harmonic Generation in the Noncentrosymmetric Organic–Inorganic Hybrid Halide (C6H5(CH2)4NH3)4MX7·H2O (M = Bi, In, X = Br or I). CHEMISTRY OF MATERIALS, 33 (20): (8106–8111). [PMID:] [10.1021/acs.chemmater.1c02896]
15. Hang Ruan, Zhongnan Guo, Jiawei Lin, Kunjie Liu, Lingling Guo, Xin Chen, Jing Zhao, Quanlin Liu, Wenxia Yuan. (2021) Structure and Optical Properties of Hybrid-Layered-Double Perovskites (C8H20N2)2AgMBr8 (M = In, Sb, and Bi). INORGANIC CHEMISTRY, 60 (19): (14629–14635). [PMID:34523334] [10.1021/acs.inorgchem.1c01669]
16. Da Chen, Fulong Dai, Shiqiang Hao, Guojun Zhou, Quanlin Liu, Christopher Wolverton, Jing Zhao, Zhiguo Xia. (2020) Crystal structure and luminescence properties of lead-free metal halides (C6H5CH2NH3)3MBr6 (M = Bi and Sb). Journal of Materials Chemistry C, 8 (22): (7322-7329). [PMID:] [10.1039/D0TC00562B]
17. Zexin Liu, Xin Zhang, Cai Liu, Dongyang Li, Miaoxin Zhang, Fuxing Yin, Guoqing Xin, Gongkai Wang. (2020) Ferroconcrete-inspired design of a nonwoven graphene fiber fabric reinforced electrode for flexible fast-charging sodium ion storage devices. Journal of Materials Chemistry A, 8 (5): (2777-2788). [PMID:] [10.1039/C9TA12770D]
18. Haifen Xu, Zichen Xu, Jin Zhou, Ge Yan, Xiaowei Li, Shuping Zhuo. (2019) Hydrothermal fabrication of BiOBr/magnetic reduced graphene oxide composites with efficient visible light photocatalytic activity. CERAMICS INTERNATIONAL, 45 (15458). [PMID:] [10.1016/j.ceramint.2019.05.048]
19. Xunyi Dong, Emmanuel Acheampong Tsiwah, Tan Li, Junjie Hu, Zixiong Li, Yanxi Ding, Zhao Deng, Wenhui Chen, Like Xu, Peng Gao, Xiujian Zhao, Yi Xie. (2019) Trivalent ion mediated abnormal growth of all-inorganic perovskite nanocrystals and their divergent emission properties. Nanoscale, 11 (16): (7903-7912). [PMID:30964500] [10.1039/C9NR01764J]
20. Yu Guan, Jiang Wu, Yuyu Lin, Qizhen Liu, Yongfen Qi, Weiguo Pan, Ping He, Xuemei Qi, Run Wang, Zhonghao Ji. (2019) Solvent-exfoliation of transition-metal dichalcogenide MoS2 to provide more active sites for enhancing photocatalytic performance of BiOIO3/g-C3N4 photocatalyst. APPLIED SURFACE SCIENCE, 481 (838). [PMID:] [10.1016/j.apsusc.2019.03.177]

References

1. Zhijie Zhang, Xuesheng Wang, Huiling Tang, Deben Li, Jiayue Xu. (2023) Modulation of Fermi level gap and internal electric field over Cs3Bi2Br9@VO-In2O3 S-scheme heterojunction for boosted charge separation and CO2 photoconversion. CHINESE JOURNAL OF CATALYSIS, 55 (227). [PMID:] [10.1016/S1872-2067(23)64549-8]
2. Shuaiqi Zhao, Xiaolei Yang, Yumeng Ge, Hongbin Zhang, Jie Li, Keyu Han, Shiqing Xu, Gongxun Bai. (2023) Uniform incorporation of two-dimensional BiOBr into perovskite crystals and films to enhance photoluminescence. CERAMICS INTERNATIONAL, [PMID:] [10.1016/j.ceramint.2023.12.001]
3. Jiexiang Tong, Subin Xie, Jia-Tao Miao, Jing Luo, Ren Liu. (2024) A novel method to synthesize polyurethane-urea acrylate with high strength and toughness. PROGRESS IN ORGANIC COATINGS, 186 (16): (108006). [PMID:19706601] [10.1016/j.porgcoat.2023.108006]
4. Zhigang Li, Yuanjie Sun, Hongtao Zhao. (2023) Enhanced optical properties of lead-free double perovskite Cs2AgBiBr6 nanocrystals by doping of Na ions. SOLID STATE COMMUNICATIONS, 373-374 (115288). [PMID:] [10.1016/j.ssc.2023.115288]
5. An Hou, Liubing Fan, Yan Xiong, Jiawei Lin, Kunjie Liu, Mingyue Chen, Zhongnan Guo, Jing Zhao, Quanlin Liu. (2023) Zero-Dimensional Halides with ns2 Electron (Sb3+) Activation to Generate Broad Photoluminescence. INORGANIC CHEMISTRY, 62 (31): (12501–12509). [PMID:37478468] [10.1021/acs.inorgchem.3c01726]
6. Lan Ding, Yongping Ding, Fenghua Bai, Gonglai Chen, Shuwei Zhang, Xiaoxue Yang, Huiqin Li, Xiaojing Wang. (2023) In Situ Growth of Cs3Bi2Br9 Quantum Dots on Bi-MOF Nanosheets via Cosharing Bismuth Atoms for CO2 Capture and Photocatalytic Reduction. INORGANIC CHEMISTRY, 62 (5): (2289–2303). [PMID:36692474] [10.1021/acs.inorgchem.2c04041]
7. Jian Ma, Congjie Liang, Changjiang Yu, Huaming Li, Hui Xu, Yingjie Hua, Chongtai Wang. (2023) BiOBr microspheres anchored with Cu2O nanoparticles and rGO: A Z-scheme heterojunction photocatalyst for efficient reduction of Cr(VI) under visible light irradiation. APPLIED SURFACE SCIENCE, 609 (155247). [PMID:] [10.1016/j.apsusc.2022.155247]
8. Zihao Cui, Yaqiang Wu, Shuhui Zhang, Hui Fu, Guoqiang Chen, Zaizhu Lou, Xiaolei Liu, Qianqian Zhang, Zeyan Wang, Zhaoke Zheng, Hefeng Cheng, Yuanyuan Liu, Ying Dai, Baibiao Huang, Peng Wang. (2023) Insight into a strategy to improve charge carrier migration in lead-free bismuth-based halide perovskite for efficient selective oxidation of thioanisole under visible light. CHEMICAL ENGINEERING JOURNAL, 451 (138927). [PMID:] [10.1016/j.cej.2022.138927]
9. Lijun Wu, Song Zheng, Heng Lin, Shun Zhou, Ahmed Mahmoud Idris, Jin Wang, Sheng Li, Zhengquan Li. (2023) In-situ assembling 0D/2D Z-scheme heterojunction of Lead-free Cs2AgBiBr6/Bi2WO6 for enhanced photocatalytic CO2 reduction. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 629 (233). [PMID:36081204] [10.1016/j.jcis.2022.08.152]
10. Lan Ding, Fenghua Bai, Burenbayaer Borjigin, Yuning Li, Huiqin Li, Xiaojing Wang. (2022) Embedding Cs2AgBiBr6 QDs into Ce-UiO-66-H to in situ construct a novel bifunctional material for capturing and photocatalytic reduction of CO2. CHEMICAL ENGINEERING JOURNAL, 446 (137102). [PMID:] [10.1016/j.cej.2022.137102]
11. Zihao Cui, Peng Wang, Yaqiang Wu, Xiaolei Liu, Guoqiang Chen, Peng Gao, Qianqian Zhang, Zeyan Wang, Zhaoke Zheng, Hefeng Cheng, Yuanyuan Liu, Ying Dai, Baibiao Huang. (2022) Space-confined growth of lead-free halide perovskite Cs3Bi2Br9 in MCM-41 molecular sieve as an efficient photocatalyst for CO2 reduction at the gas−solid condition under visible light. APPLIED CATALYSIS B-ENVIRONMENTAL, 310 (121375). [PMID:] [10.1016/j.apcatb.2022.121375]
12. Anjli Sharma, Sanjeev Kumar Kanth, Shishi Xu, Ni Han, Lei Zhu, Lele Fan, Chao Liu, Qinfang Zhang. (2022) Visible light driven g-C3N4/Bi4NbO8X (XCl, Br) heterojunction photocatalyst for the degradation of organic pollutants. JOURNAL OF ALLOYS AND COMPOUNDS, 895 (162576). [PMID:] [10.1016/j.jallcom.2021.162576]
13. Chenkai Deng, Shiqiang Hao, Kunjie Liu, Maxim S. Molokeev, Christopher Wolverton, Liubing Fan, Guojun Zhou, Da Chen, Jing Zhao, Quanlin Liu. (2021) Broadband light emitting zero-dimensional antimony and bismuth-based hybrid halides with diverse structures. Journal of Materials Chemistry C, 9 (44): (15942-15948). [PMID:] [10.1039/D1TC04198C]
14. Da Chen, Shiqiang Hao, Liubing Fan, Yangwu Guo, Jiyong Yao, Christopher Wolverton, Mercouri G. Kanatzidis, Jing Zhao, Quanlin Liu. (2021) Broad Photoluminescence and Second-Harmonic Generation in the Noncentrosymmetric Organic–Inorganic Hybrid Halide (C6H5(CH2)4NH3)4MX7·H2O (M = Bi, In, X = Br or I). CHEMISTRY OF MATERIALS, 33 (20): (8106–8111). [PMID:] [10.1021/acs.chemmater.1c02896]
15. Hang Ruan, Zhongnan Guo, Jiawei Lin, Kunjie Liu, Lingling Guo, Xin Chen, Jing Zhao, Quanlin Liu, Wenxia Yuan. (2021) Structure and Optical Properties of Hybrid-Layered-Double Perovskites (C8H20N2)2AgMBr8 (M = In, Sb, and Bi). INORGANIC CHEMISTRY, 60 (19): (14629–14635). [PMID:34523334] [10.1021/acs.inorgchem.1c01669]
16. Da Chen, Fulong Dai, Shiqiang Hao, Guojun Zhou, Quanlin Liu, Christopher Wolverton, Jing Zhao, Zhiguo Xia. (2020) Crystal structure and luminescence properties of lead-free metal halides (C6H5CH2NH3)3MBr6 (M = Bi and Sb). Journal of Materials Chemistry C, 8 (22): (7322-7329). [PMID:] [10.1039/D0TC00562B]
17. Zexin Liu, Xin Zhang, Cai Liu, Dongyang Li, Miaoxin Zhang, Fuxing Yin, Guoqing Xin, Gongkai Wang. (2020) Ferroconcrete-inspired design of a nonwoven graphene fiber fabric reinforced electrode for flexible fast-charging sodium ion storage devices. Journal of Materials Chemistry A, 8 (5): (2777-2788). [PMID:] [10.1039/C9TA12770D]
18. Haifen Xu, Zichen Xu, Jin Zhou, Ge Yan, Xiaowei Li, Shuping Zhuo. (2019) Hydrothermal fabrication of BiOBr/magnetic reduced graphene oxide composites with efficient visible light photocatalytic activity. CERAMICS INTERNATIONAL, 45 (15458). [PMID:] [10.1016/j.ceramint.2019.05.048]
19. Xunyi Dong, Emmanuel Acheampong Tsiwah, Tan Li, Junjie Hu, Zixiong Li, Yanxi Ding, Zhao Deng, Wenhui Chen, Like Xu, Peng Gao, Xiujian Zhao, Yi Xie. (2019) Trivalent ion mediated abnormal growth of all-inorganic perovskite nanocrystals and their divergent emission properties. Nanoscale, 11 (16): (7903-7912). [PMID:30964500] [10.1039/C9NR01764J]
20. Yu Guan, Jiang Wu, Yuyu Lin, Qizhen Liu, Yongfen Qi, Weiguo Pan, Ping He, Xuemei Qi, Run Wang, Zhonghao Ji. (2019) Solvent-exfoliation of transition-metal dichalcogenide MoS2 to provide more active sites for enhancing photocatalytic performance of BiOIO3/g-C3N4 photocatalyst. APPLIED SURFACE SCIENCE, 481 (838). [PMID:] [10.1016/j.apsusc.2019.03.177]

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Bismuth(III) bromide - anhydrous, powder, 99.998.Corrosive substance% trace metals basis, high purity , CAS No.7787-58-8

Basic Description

Names and Identifiers

Certificates

Certificate of Analysis(COA)

Chemical and Physical Properties

Safety and Hazards(GHS)

Related Documents

Citations of This Product

References

Solution Calculators

Molarity Calculator

Dilution Calculator

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SKU	Size	Availability	Price	Qty
B434024-1g	1g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$71.90
B434024-5g	5g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$259.90