Bismuth(III) trifluoromethanesulfonate - 98%, high purity , CAS No.88189-03-1

2 Citations
  • ≥98%
Item Number
B113622
Grouped product items
SKUSizeAvailabilityPrice Qty
B113622-1g
1g
In stock
$10.90
B113622-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$18.90
B113622-25g
25g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$45.90
B113622-100g
100g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$159.90

Discover Bismuth(III) trifluoromethanesulfonate by Aladdin Scientific in 98% for only $10.90. Available - in Ligands at Aladdin Scientific. Tags: Sulfur containing compounds.

View related series
Sulfur containing compounds

Basic Description

SynonymsMFCD02093669 | 51KD8E1741 | bismuth (III) triflate | Bismuth(III) trifluoromethanesulfonate | FT-0676865 | UNII-51KD8E1741 | bismuth;trifluoromethanesulfonate | Bismuth(3+) trifluoromethanesulfonate | F15443 | NYENCOMLZDQKNH-UHFFFAOYSA-K | Bismuth triflat
Specifications & Purity98%
Storage TempArgon charged
Shipped InNormal
Product Description

application:

Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.

Bismuth(III) trifluoromethanesulfonate may be used as a catalyst in the following processes:


• deprotection of acetals

• cleavage of 2-tert-butoxy derivatives of thiophenes and furans

• allylation of acetals to form homoallyl ethers

It may also be used as a substitute to corrosive triflic acid in Friedel-Crafts (FC) acylation and sulfonylation of arenes.

Names and Identifiers

IUPAC Name bismuth;trifluoromethanesulfonate
INCHI InChI=1S/3CHF3O3S.Bi/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
InChi Key NYENCOMLZDQKNH-UHFFFAOYSA-K
Canonical SMILES C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Bi+3]
Isomeric SMILES C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Bi+3]
WGK Germany 3
PubChem CID 9917655
Molecular Weight 656.19

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

6 results found

Lot NumberCertificate TypeDateItem
C2419053Certificate of AnalysisMar 12, 2024 B113622
C2419054Certificate of AnalysisMar 12, 2024 B113622
B2310363Certificate of AnalysisFeb 16, 2023 B113622
F23051255Certificate of AnalysisOct 22, 2021 B113622
G2322037Certificate of AnalysisOct 22, 2021 B113622
H2219150Certificate of AnalysisOct 22, 2021 B113622

Chemical and Physical Properties

SolubilitySoluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide
SensitivityHygroscopic.
Melt Point(°C)300°C

Safety and Hazards(GHS)

Pictogram(s) GHS05
Signal Danger
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

WGK Germany 3

Related Documents

Citations of This Product

1. Muhammad Umair Ahmad, Guoying Zhao, Shahid Hussain.  (2023)  Trifloaluminate Ionic Liquids Supported UIO-67 as Lewis Acidic Catalyst for Excellent Synthesis of Alkyl Levulinates.  ChemistrySelect,  (43): (e202302665).  [PMID:16835267]
2. Yuan Lei, Guang Yang, Qiang Huang, Jibo Dou, Lijing Dai, Fengjie Deng, Meiying Liu, Xiancai Li, Xiaoyong Zhang, Yen Wei.  (2022)  Facile synthesis of ionic liquid modified silica nanoparticles for fast removal of anionic organic dyes with extremely high adsorption capacity.  JOURNAL OF MOLECULAR LIQUIDS,  347  (117966).  [PMID:]

References

1. Hongbo Qin,Noriyuki Yamagiwa,Shigeki Matsunaga,Masakatsu Shibasaki.  (2006-12-06)  Bismuth-catalyzed direct substitution of the hydroxy group in alcohols with sulfonamides, carbamates, and carboxamides..  Angewandte Chemie (International ed. in English),  46  ((3)): (409-413).  [PMID:17146812]
2. Raffaele Cucciniello,Maria Ricciardi,Rosa Vitiello,Martino Di Serio,Antonio Proto,Carmine Capacchione.  (2016-11-24)  Synthesis of Monoalkyl Glyceryl Ethers by Ring Opening of Glycidol with Alcohols in the Presence of Lewis Acids..  ChemSusChem,  ((23)): (3272-3275).  [PMID:27880034]
3. Maria Ricciardi,Fabrizio Passarini,Ivano Vassura,Antonio Proto,Carmine Capacchione,Raffaele Cucciniello,Daniele Cespi.  (2017-04-05)  Glycidol, a Valuable Substrate for the Synthesis of Monoalkyl Glyceryl Ethers: A Simplified Life Cycle Approach..  ChemSusChem,  10  ((10)): (2291-2300).  [PMID:28376258]
4. Muhammad Umair Ahmad, Guoying Zhao, Shahid Hussain.  (2023)  Trifloaluminate Ionic Liquids Supported UIO-67 as Lewis Acidic Catalyst for Excellent Synthesis of Alkyl Levulinates.  ChemistrySelect,  (43): (e202302665).  [PMID:16835267]
5. Yuan Lei, Guang Yang, Qiang Huang, Jibo Dou, Lijing Dai, Fengjie Deng, Meiying Liu, Xiancai Li, Xiaoyong Zhang, Yen Wei.  (2022)  Facile synthesis of ionic liquid modified silica nanoparticles for fast removal of anionic organic dyes with extremely high adsorption capacity.  JOURNAL OF MOLECULAR LIQUIDS,  347  (117966).  [PMID:]

Solution Calculators