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Bismuth(III) trifluoromethanesulfonate - 98%, high purity , CAS No.88189-03-1

2 Citations

≥98%

CAS#: 88189-03-1
Formula: C₃BiF₉O₉S₃
Molecular Weight: 656.19
MDL number: MFCD02093669
PubChem CID: 9917655

Item Number

B113622

Grouped product items
SKU	Size	Availability	Price
B113622-1g	1g	In stock	$10.90
B113622-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$18.90
B113622-25g	25g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$45.90
B113622-100g	100g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$159.90

Discover Bismuth(III) trifluoromethanesulfonate by Aladdin Scientific in 98% for only $10.90. Available - in Ligands at Aladdin Scientific. Tags: Sulfur containing compounds.

View related series

Sulfur containing compounds

Basic Description

Synonyms	MFCD02093669 \| 51KD8E1741 \| bismuth (III) triflate \| Bismuth(III) trifluoromethanesulfonate \| FT-0676865 \| UNII-51KD8E1741 \| bismuth;trifluoromethanesulfonate \| Bismuth(3+) trifluoromethanesulfonate \| F15443 \| NYENCOMLZDQKNH-UHFFFAOYSA-K \| Bismuth triflat
Specifications & Purity	≥98%
Storage Temp	Argon charged
Shipped In	Normal
Product Description	application： Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides. Bismuth(III) trifluoromethanesulfonate may be used as a catalyst in the following processes: • deprotection of acetals • cleavage of 2-tert-butoxy derivatives of thiophenes and furans • allylation of acetals to form homoallyl ethers It may also be used as a substitute to corrosive triflic acid in Friedel-Crafts (FC) acylation and sulfonylation of arenes.

Names and Identifiers

IUPAC Name	bismuth;trifluoromethanesulfonate
INCHI	InChI=1S/3CHF3O3S.Bi/c32-1(3,4)8(5,6)7;/h3(H,5,6,7);/q;;;+3/p-3
InChi Key	NYENCOMLZDQKNH-UHFFFAOYSA-K
Canonical SMILES	C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Bi+3]
Isomeric SMILES	C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Bi+3]
WGK Germany	3
PubChem CID	9917655
Molecular Weight	656.19

Certificates

Certificate of Analysis(COA)

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6 results found

Lot Number	Certificate Type	Date	Item
C2419053	Certificate of Analysis	Mar 12, 2024	B113622
C2419054	Certificate of Analysis	Mar 12, 2024	B113622
B2310363	Certificate of Analysis	Feb 16, 2023	B113622
F23051255	Certificate of Analysis	Oct 22, 2021	B113622
G2322037	Certificate of Analysis	Oct 22, 2021	B113622
H2219150	Certificate of Analysis	Oct 22, 2021	B113622

Solubility

Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide

Sensitivity

Hygroscopic.

Melt Point(°C)

300°C

Safety and Hazards(GHS)

Pictogram(s)	GHS05
Signal	Danger
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
WGK Germany	3

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Muhammad Umair Ahmad, Guoying Zhao, Shahid Hussain. (2023) Trifloaluminate Ionic Liquids Supported UIO-67 as Lewis Acidic Catalyst for Excellent Synthesis of Alkyl Levulinates. ChemistrySelect, 8 (43): (e202302665). [PMID:16835267] [10.1002/slct.202302665]
2. Yuan Lei, Guang Yang, Qiang Huang, Jibo Dou, Lijing Dai, Fengjie Deng, Meiying Liu, Xiancai Li, Xiaoyong Zhang, Yen Wei. (2022) Facile synthesis of ionic liquid modified silica nanoparticles for fast removal of anionic organic dyes with extremely high adsorption capacity. JOURNAL OF MOLECULAR LIQUIDS, 347 (117966). [PMID:] [10.1016/j.molliq.2021.117966]

References

1. Hongbo Qin,Noriyuki Yamagiwa,Shigeki Matsunaga,Masakatsu Shibasaki. (2006-12-06) Bismuth-catalyzed direct substitution of the hydroxy group in alcohols with sulfonamides, carbamates, and carboxamides.. Angewandte Chemie (International ed. in English), 46 ((3)): (409-413). [PMID:17146812]
2. Raffaele Cucciniello,Maria Ricciardi,Rosa Vitiello,Martino Di Serio,Antonio Proto,Carmine Capacchione. (2016-11-24) Synthesis of Monoalkyl Glyceryl Ethers by Ring Opening of Glycidol with Alcohols in the Presence of Lewis Acids.. ChemSusChem, 9 ((23)): (3272-3275). [PMID:27880034]
3. Maria Ricciardi,Fabrizio Passarini,Ivano Vassura,Antonio Proto,Carmine Capacchione,Raffaele Cucciniello,Daniele Cespi. (2017-04-05) Glycidol, a Valuable Substrate for the Synthesis of Monoalkyl Glyceryl Ethers: A Simplified Life Cycle Approach.. ChemSusChem, 10 ((10)): (2291-2300). [PMID:28376258]
4. Muhammad Umair Ahmad, Guoying Zhao, Shahid Hussain. (2023) Trifloaluminate Ionic Liquids Supported UIO-67 as Lewis Acidic Catalyst for Excellent Synthesis of Alkyl Levulinates. ChemistrySelect, 8 (43): (e202302665). [PMID:16835267] [10.1002/slct.202302665]
5. Yuan Lei, Guang Yang, Qiang Huang, Jibo Dou, Lijing Dai, Fengjie Deng, Meiying Liu, Xiancai Li, Xiaoyong Zhang, Yen Wei. (2022) Facile synthesis of ionic liquid modified silica nanoparticles for fast removal of anionic organic dyes with extremely high adsorption capacity. JOURNAL OF MOLECULAR LIQUIDS, 347 (117966). [PMID:] [10.1016/j.molliq.2021.117966]

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