Bismuth iodide - 99.99% metals basis, high purity , CAS No.7787-64-6

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Item Number
B119017
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Metal salt

Basic Description

SynonymsBismuth iodide | Bismuth(III) iodide | 7787-64-6 | Bismuth triiodide | triiodobismuthane | Bismuthine, triiodo- | Bismuth iodide (BiI3) | 12262-07-6 | bismuth;triiodide | triiodobismuthine | MFCD00010894 | BiI3 | UNII-BGX9X3FOLL | EINECS 232-127-4 | NSC 103681 | Bismuth iodide, BiI3 | B
Specifications & Purity99.99% metals basis
Storage TempArgon charged
Shipped InNormal
GradePrimorTrace™

Names and Identifiers

IUPAC Name triiodobismuthane
INCHI InChI=1S/Bi.3HI/h;3*1H/q+3;;;/p-3
InChi Key KOECRLKKXSXCPB-UHFFFAOYSA-K
Canonical SMILES I[Bi](I)I
Isomeric SMILES I[Bi](I)I
WGK Germany 3
PubChem CID 111042
UN Number 3260
Molecular Weight 589.69
Reaxy-Rn 3903094

Certificates

Certificate of Analysis(COA)

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24 results found

Lot NumberCertificate TypeDateItem
E2430138Certificate of AnalysisMay 22, 2024 B119017
E2430145Certificate of AnalysisMay 22, 2024 B119017
E2430146Certificate of AnalysisMay 22, 2024 B119017
G2219147Certificate of AnalysisApr 07, 2024 B119017
G2219146Certificate of AnalysisApr 07, 2024 B119017
G2219145Certificate of AnalysisApr 07, 2024 B119017
G2219143Certificate of AnalysisApr 07, 2024 B119017
L2103476Certificate of AnalysisSep 19, 2023 B119017
L2103474Certificate of AnalysisSep 19, 2023 B119017
L2103471Certificate of AnalysisSep 19, 2023 B119017
L2103470Certificate of AnalysisSep 19, 2023 B119017
L2103466Certificate of AnalysisSep 19, 2023 B119017
C1810027Certificate of AnalysisJul 12, 2023 B119017
G2130057Certificate of AnalysisMay 10, 2023 B119017
G2130055Certificate of AnalysisMay 09, 2023 B119017
E2324550Certificate of AnalysisApr 21, 2023 B119017
E2324547Certificate of AnalysisApr 21, 2023 B119017
E2324541Certificate of AnalysisApr 21, 2023 B119017
E2324535Certificate of AnalysisApr 21, 2023 B119017
E2324534Certificate of AnalysisApr 21, 2023 B119017
D2423073Certificate of AnalysisApr 21, 2023 B119017
E1920187Certificate of AnalysisJan 04, 2023 B119017
C2125079Certificate of AnalysisDec 15, 2022 B119017
K1816020Certificate of AnalysisJun 27, 2022 B119017

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Chemical and Physical Properties

SolubilityInsoluble in water. Highly soluble in ethanol, benzene, toluene and xylene, hydrochloric acid and in hydriodic acid.
SensitivityLight & Moisture Sensitive
Boil Point(°C)500 °C
Melt Point(°C)408°C

Safety and Hazards(GHS)

Pictogram(s) GHS05
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

Precautionary Statements

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3
Reaxy-Rn 3903094
Merck Index 1269

Related Documents

Citations of This Product

1. Huiyan Huang, Guoshu Dai, Xinghua Wu, Yuheng Wu, Aixiang Wei, Zhen Liu.  (2024)  Lead-free, highly-stable methyl ammonium bismuth halide perovskite memristors for mimicking biological synapses.  MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING,  172  (108073).  [PMID:]
2. Dedong Guo, Shuheng Dong, Qingzhou Wang, Huixin Yu, Eun-Seong Kim, Qing Xu, Ho-Kun Sung, Zhao Yao, Yuanyue Li, Nam-Young Kim.  (2023)  Enhanced sensitivity and detection range of a flexible pressure sensor utilizing a nano-cracked PVP hierarchical nanofiber membrane formed by BiI3 sublimation.  CHEMICAL ENGINEERING JOURNAL,  476  (146464).  [PMID:12786946]
3. Anfeng Li, Manman Yang, Aoxi He, Peng Tang, Xia Hao, Lili Wu, Wenbo Tian, Dingyu Yang, Jingquan Zhang.  (2023)  Doping Modification of Cs3Bi2I9 Single Crystals for High-Performance X-Ray Detectors.  Physica Status Solidi-Rapid Research Letters,    (2300306).  [PMID:]
4. Shuaifei Mao, Mingqing Cui, Sheng Jiang, Pengfei Zhao, Jie Lao, Chunli Jiang, Chunhua Luo, Bobo Tian, Hechun Lin, Jadranka Travas-sejdic, Hui Peng, Chun-Gang Duan.  (2023)  Dual-modal artificial synapse based on a lead-free halide Cu2AgBiI6 for image processing and information encryption.  CHEMICAL ENGINEERING JOURNAL,  472  (145086).  [PMID:]
5. Sellan Premkumar, Thankappan Thrupthika, Maheswari Palanivel, Dan Liu, Devaraj Nataraj, Wei Lei, Jianzhou Gui.  (2023)  Preparation of nano dumbbell-shaped silver bismuth iodide perovskite hybrids and their enhanced photocurrent properties.  NEW JOURNAL OF CHEMISTRY,  47  (24): (11669-11674).  [PMID:]
6. Manman Yang, Anfeng Li, Xia Hao, LiLi Wu, Wenbo Tian, Dingyu Yang, Jingquan Zhang.  (2023)  Highly Sensitive X-Ray Detector Made of Large Lead-Free Perovskite Cs3Bi2I9 Single Crystals with Anisotropic Response.  Advanced Optical Materials,  11  (15): (2203066).  [PMID:]
7. Anfeng Li, Manman Yang, Peng Tang, Xia Hao, Lili Wu, Wenbo Tian, Dingyu Yang, Jingquan Zhang.  (2023)  Composition Engineering Growth of Cs3Bi2I9 Single Crystals with Low Defect Density for X-ray Detectors.  ACS Applied Materials & Interfaces,  15  (19): (23390–23401).  [PMID:37146248]
8. Chen Wei, Sun Hui, Jin Yingrong, Yang Hualin, He Yi, Zhu Xinghua.  (2023)  Preparation of bismuth-based perovskite Cs3Bi2I6Br3 single crystal for X-ray detector application.  JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,  34  (6): (1-9).  [PMID:]
9. Zhan Wei, Ling Ding, Na Sun, Le-Yang Dang, Hao-Ran Sun, Jie-Cai Han, Jia-Qi Zhu, Gui-Gen Wang.  (2023)  Lead-free CsBi3I10 perovskite based photo-enhanced triboelectric nanogenerator.  Nano Energy,  108  (108209).  [PMID:]
10. Shindume Lomboleni Hamukwaya, Huiying Hao, Melvin Mununuri Mashingaidze, Tingting Zhong, Shu Tang, Jingjing Dong, Jie Xing, Hao Liu.  (2022)  Potassium Iodide-Modified Lead-Free Cs3Bi2I9 Perovskites for Enhanced High-Efficiency Solar Cells.  Nanomaterials,  12  (21): (3751).  [PMID:36364527]
11. Chuang Ma, Haojin Li, Ming Chen, Yucheng Liu, Kui Zhao, Shengzhong (Frank) Liu.  (2022)  Water-Resistant Lead-Free Perovskitoid Single Crystal for Efficient X-Ray Detection.  ADVANCED FUNCTIONAL MATERIALS,  32  (30): (2202160).  [PMID:]
12. Jianyu Zhang, Anfeng Li, Bohan Li, Manman Yang, Xia Hao, Lili Wu, Dewei Zhao, Gengpei Xia, Zefeng Ren, Wenbo Tian, Dingyu Yang, Jingquan Zhang.  (2022)  Top-Seed Solution-Based Growth of Perovskite Cs3Bi2I9 Single Crystal for High Performance X-ray Detection.  ACS Photonics,  (2): (641–651).  [PMID:]
13. Da Chen, Shiqiang Hao, Liubing Fan, Yangwu Guo, Jiyong Yao, Christopher Wolverton, Mercouri G. Kanatzidis, Jing Zhao, Quanlin Liu.  (2021)  Broad Photoluminescence and Second-Harmonic Generation in the Noncentrosymmetric Organic–Inorganic Hybrid Halide (C6H5(CH2)4NH3)4MX7·H2O (M = Bi, In, X = Br or I).  CHEMISTRY OF MATERIALS,  33  (20): (8106–8111).  [PMID:]
14. Kunjie Liu, Chenkai Deng, Chunxiao Li, Xusheng Zhang, Jindong Cao, Jiyong Yao, Jing Zhao, Xingxing Jiang, Zheshuai Lin, Quanlin Liu.  (2021)  Hybrid Metal-Halide Infrared Nonlinear Optical Crystals of (TMEDA)MI5 (M = Sb, Bi) with High Stability.  Advanced Optical Materials,  (24): (2101333).  [PMID:]
15. Xin Xiao,Rong Hao,Min Liang,Xiaoxi Zuo,Junmin Nan,Laisheng Li,Weide Zhang.  (2012-07-24)  One-pot solvothermal synthesis of three-dimensional (3D) BiOI/BiOCl composites with enhanced visible-light photocatalytic activities for the degradation of bisphenol-A..  Journal of hazardous materials,  233-234  (122-130).  [PMID:22818177]

References

1. S Dolapchieva,K Ichev,W Ovtscharoff.  (1985-01-01)  Bismuth iodide impregnation of the peripheral nerve fibres..  Zeitschrift fur mikroskopisch-anatomische Forschung,  99  ((5)): (804-812).  [PMID:2420083]
2. R R Jia,C P Wu,S Wu,Y X Yang,Y R Chen,Y Q Jia.  (2006-04-04)  Synthesis and characterization of aspartic acid complexes of antimony and bismuth triiodide..  Amino acids,  31  ((1)): (85-90).  [PMID:16583320]
3. Wenhua Bi,Nicolas Mercier.  (2008-11-15)  Reversible dynamic isomerism change in the solid state, from Bi4I16 clusters to BiI4 1D chains in L-cystine based hybrids: templating effect of cations in iodobismuthate network formation..  Chemical communications (Cambridge, England),    ((44)): (5743-5745).  [PMID:19009067]
4. Jie Sun,Qiuhua Nie,Xunsi Wang,Shixun Dai,Tiefeng Xu,Guoxiang Wang.  (2011-05-10)  Glass formation and properties of Ge-Te-BiI3 far infrared transmitting chalcohalide glasses..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  79  ((5)): (904-908).  [PMID:21550299]
5. Minhua Su,Chun He,Linfei Zhu,Zhenjie Sun,Chun Shan,Qiong Zhang,Dong Shu,Rongliang Qiu,Ya Xiong.  (2012-06-20)  Enhanced adsorption and photocatalytic activity of BiOI-MWCNT composites towards organic pollutants in aqueous solution..  Journal of hazardous materials,  229-230  (72-82).  [PMID:22709852]
6. Nathan T Hahn,Son Hoang,Jeffrey L Self,C Buddie Mullins.  (2012-08-16)  Spray pyrolysis deposition and photoelectrochemical properties of n-type BiOI nanoplatelet thin films..  ACS nano,  ((9)): (7712-7722).  [PMID:22891667]
7. F M Abdel-Gawad.  (1998-04-16)  Ion-pair formation of Bi(III)-iodide with some nitrogenous drugs and its application to pharmaceutical preparations..  Journal of pharmaceutical and biomedical analysis,  16  ((5)): (793-799).  [PMID:9535191]
8. Mirko Scholz,Kawon Oum,Thomas Lenzer.  (2017-12-21)  Pronounced exciton and coherent phonon dynamics in BiI3..  Physical chemistry chemical physics : PCCP,  20  ((16)): (10677-10685).  [PMID:29260159]
9. Huiyan Huang, Guoshu Dai, Xinghua Wu, Yuheng Wu, Aixiang Wei, Zhen Liu.  (2024)  Lead-free, highly-stable methyl ammonium bismuth halide perovskite memristors for mimicking biological synapses.  MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING,  172  (108073).  [PMID:]
10. Dedong Guo, Shuheng Dong, Qingzhou Wang, Huixin Yu, Eun-Seong Kim, Qing Xu, Ho-Kun Sung, Zhao Yao, Yuanyue Li, Nam-Young Kim.  (2023)  Enhanced sensitivity and detection range of a flexible pressure sensor utilizing a nano-cracked PVP hierarchical nanofiber membrane formed by BiI3 sublimation.  CHEMICAL ENGINEERING JOURNAL,  476  (146464).  [PMID:12786946]
11. Anfeng Li, Manman Yang, Aoxi He, Peng Tang, Xia Hao, Lili Wu, Wenbo Tian, Dingyu Yang, Jingquan Zhang.  (2023)  Doping Modification of Cs3Bi2I9 Single Crystals for High-Performance X-Ray Detectors.  Physica Status Solidi-Rapid Research Letters,    (2300306).  [PMID:]
12. Shuaifei Mao, Mingqing Cui, Sheng Jiang, Pengfei Zhao, Jie Lao, Chunli Jiang, Chunhua Luo, Bobo Tian, Hechun Lin, Jadranka Travas-sejdic, Hui Peng, Chun-Gang Duan.  (2023)  Dual-modal artificial synapse based on a lead-free halide Cu2AgBiI6 for image processing and information encryption.  CHEMICAL ENGINEERING JOURNAL,  472  (145086).  [PMID:]
13. Sellan Premkumar, Thankappan Thrupthika, Maheswari Palanivel, Dan Liu, Devaraj Nataraj, Wei Lei, Jianzhou Gui.  (2023)  Preparation of nano dumbbell-shaped silver bismuth iodide perovskite hybrids and their enhanced photocurrent properties.  NEW JOURNAL OF CHEMISTRY,  47  (24): (11669-11674).  [PMID:]
14. Manman Yang, Anfeng Li, Xia Hao, LiLi Wu, Wenbo Tian, Dingyu Yang, Jingquan Zhang.  (2023)  Highly Sensitive X-Ray Detector Made of Large Lead-Free Perovskite Cs3Bi2I9 Single Crystals with Anisotropic Response.  Advanced Optical Materials,  11  (15): (2203066).  [PMID:]
15. Anfeng Li, Manman Yang, Peng Tang, Xia Hao, Lili Wu, Wenbo Tian, Dingyu Yang, Jingquan Zhang.  (2023)  Composition Engineering Growth of Cs3Bi2I9 Single Crystals with Low Defect Density for X-ray Detectors.  ACS Applied Materials & Interfaces,  15  (19): (23390–23401).  [PMID:37146248]
16. Chen Wei, Sun Hui, Jin Yingrong, Yang Hualin, He Yi, Zhu Xinghua.  (2023)  Preparation of bismuth-based perovskite Cs3Bi2I6Br3 single crystal for X-ray detector application.  JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,  34  (6): (1-9).  [PMID:]
17. Zhan Wei, Ling Ding, Na Sun, Le-Yang Dang, Hao-Ran Sun, Jie-Cai Han, Jia-Qi Zhu, Gui-Gen Wang.  (2023)  Lead-free CsBi3I10 perovskite based photo-enhanced triboelectric nanogenerator.  Nano Energy,  108  (108209).  [PMID:]
18. Shindume Lomboleni Hamukwaya, Huiying Hao, Melvin Mununuri Mashingaidze, Tingting Zhong, Shu Tang, Jingjing Dong, Jie Xing, Hao Liu.  (2022)  Potassium Iodide-Modified Lead-Free Cs3Bi2I9 Perovskites for Enhanced High-Efficiency Solar Cells.  Nanomaterials,  12  (21): (3751).  [PMID:36364527]
19. Chuang Ma, Haojin Li, Ming Chen, Yucheng Liu, Kui Zhao, Shengzhong (Frank) Liu.  (2022)  Water-Resistant Lead-Free Perovskitoid Single Crystal for Efficient X-Ray Detection.  ADVANCED FUNCTIONAL MATERIALS,  32  (30): (2202160).  [PMID:]
20. Jianyu Zhang, Anfeng Li, Bohan Li, Manman Yang, Xia Hao, Lili Wu, Dewei Zhao, Gengpei Xia, Zefeng Ren, Wenbo Tian, Dingyu Yang, Jingquan Zhang.  (2022)  Top-Seed Solution-Based Growth of Perovskite Cs3Bi2I9 Single Crystal for High Performance X-ray Detection.  ACS Photonics,  (2): (641–651).  [PMID:]
21. Da Chen, Shiqiang Hao, Liubing Fan, Yangwu Guo, Jiyong Yao, Christopher Wolverton, Mercouri G. Kanatzidis, Jing Zhao, Quanlin Liu.  (2021)  Broad Photoluminescence and Second-Harmonic Generation in the Noncentrosymmetric Organic–Inorganic Hybrid Halide (C6H5(CH2)4NH3)4MX7·H2O (M = Bi, In, X = Br or I).  CHEMISTRY OF MATERIALS,  33  (20): (8106–8111).  [PMID:]
22. Kunjie Liu, Chenkai Deng, Chunxiao Li, Xusheng Zhang, Jindong Cao, Jiyong Yao, Jing Zhao, Xingxing Jiang, Zheshuai Lin, Quanlin Liu.  (2021)  Hybrid Metal-Halide Infrared Nonlinear Optical Crystals of (TMEDA)MI5 (M = Sb, Bi) with High Stability.  Advanced Optical Materials,  (24): (2101333).  [PMID:]
23. Xin Xiao,Rong Hao,Min Liang,Xiaoxi Zuo,Junmin Nan,Laisheng Li,Weide Zhang.  (2012-07-24)  One-pot solvothermal synthesis of three-dimensional (3D) BiOI/BiOCl composites with enhanced visible-light photocatalytic activities for the degradation of bisphenol-A..  Journal of hazardous materials,  233-234  (122-130).  [PMID:22818177]

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