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Borane dimethyl sulfide complex - 2.0 M solution in THF, high purity , CAS No.13292-87-0 2 Citations
Basic Description Synonyms BMS | MCQRPQCQMGVWIQ-UHFFFAOYSA-N | Dimethyl sulphide borane | Dimethyl sulfide borane | borane methylsulphide | boron dimethyl sulfide | FT-0652013 | Borane dimethyl sulfide complex 2.0 M in THF | UNII-93TWS7F2GX | (Dimethyl sulfide)trihydroboron | (Meth Specifications & Purity 2.0 M solution in THF Storage Temp Store at 2-8°C,Argon charged Shipped In Wet ice Product Description Borane dimethyl sulfide complex is a stable source of borane used in hydroboration reduction reactions in organic synthesis. Studies indicate that Borane dimethyl sulfide complex can selectively suppress &alpha-hydroxyesters. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides. Reactant used as a regioselective reducing agent Reactant involved in: &bull Hydroboration / oxidation Synthesis of cage compounds
Names and Identifiers INCHI InChI=1S/C2H6S.B/c1-3-2;/h1-2H3; InChi Key MCQRPQCQMGVWIQ-UHFFFAOYSA-N Canonical SMILES [B].CSC Isomeric SMILES [B].CSC WGK Germany 3 PubChem CID 9833925 Molecular Weight 75.97 Beilstein 3663489
Chemical and Physical Properties Sensitivity Air & Moisture Sensitive Flash Point(°F) -31 °F Flash Point(°C) -35 °C
Safety and Hazards(GHS) Pictogram(s) GHS06 , GHS05 , GHS02 Signal Danger Hazard Statements H315: Causes skin irritation
H335: May cause respiratory irritation
H260: In contact with water releases flammable gases which may ignite spontaneously
H318: Causes serious eye damage
H225: Highly Flammable liquid and vapor
H301+H311: Toxic if swallowed or in contact with skin
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P223: Do not allow contact with water.
P231+P232: Handle under inert gas/... Protect from moisture.
P370+P378: In case of fire: Use ... to extinguish.
P422: Store contents under ...
P210: Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.
WGK Germany 3
Citations of This Product 1. Shibin Wu, Keru Song, Jianwen Wang, Siyu Huang, Fengyue Shi, Guangdong Zhao. (2023) Microstructure and phase evolution behavior of SiZrBC ceramic precursors synthesized via sol–gel method. JOURNAL OF SOLID STATE CHEMISTRY, 321 (123910). [PMID: ] 2. Bijie Wang, Yujie Song, Xiao Zhang, Ke Chen, Ming Liu, Xiao Hu, Liu He, Qing Huang. (2022) Polymer derived SiBCN(O) ceramics with tunable element content. CERAMICS INTERNATIONAL, 48 (10280). [PMID: ]
References 1. Shibin Wu, Keru Song, Jianwen Wang, Siyu Huang, Fengyue Shi, Guangdong Zhao. (2023) Microstructure and phase evolution behavior of SiZrBC ceramic precursors synthesized via sol–gel method. JOURNAL OF SOLID STATE CHEMISTRY, 321 (123910). [PMID: ] 2. Bijie Wang, Yujie Song, Xiao Zhang, Ke Chen, Ming Liu, Xiao Hu, Liu He, Qing Huang. (2022) Polymer derived SiBCN(O) ceramics with tunable element content. CERAMICS INTERNATIONAL, 48 (10280). [PMID: ]
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