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Borane dimethyl sulfide complex - 2.0 M solution in THF, high purity , CAS No.13292-87-0
Basic Description Synonyms 13292-87-0|Dimethyl sulfide borane|Borane-dimethyl sulfide|borane dimethylsulfide|borane dimethyl sulfide|BMS|(Dimethyl sulfide)trihydroboron|MFCD00013189|boron;methylsulfanylmethane|borane DMS|borane Me2S|DMS Borane|borane methylsulfide|borane dimethylsu Specifications & Purity 2.0 M solution in THF Storage Temp Store at 2-8°C,Argon charged Shipped In Wet ice Product Description Borane dimethyl sulfide complex is a stable source of borane used in hydroboration reduction reactions in organic synthesis. Studies indicate that Borane dimethyl sulfide complex can selectively suppress &alpha-hydroxyesters. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides. Reactant used as a regioselective reducing agent Reactant involved in: &bull Hydroboration / oxidation Synthesis of cage compounds
Names and Identifiers INCHI InChI=1S/C2H6S.B/c1-3-2;/h1-2H3; InChi Key MCQRPQCQMGVWIQ-UHFFFAOYSA-N Canonical SMILES [B].CSC Isomeric SMILES [B].CSC WGK Germany 3 PubChem CID 9833925 Molecular Weight 75.97 Beilstein 3663489
Chemical and Physical Properties Sensitivity Air & Moisture Sensitive Flash Point(°F) -31 °F Flash Point(°C) -35 °C
Safety and Hazards(GHS) Pictogram(s) GHS06 , GHS05 , GHS02 Signal Danger Hazard Statements H315: Causes skin irritation
H335: May cause respiratory irritation
H260: In contact with water releases flammable gases which may ignite spontaneously
H318: Causes serious eye damage
H225: Highly Flammable liquid and vapor
H301+H311: Toxic if swallowed or in contact with skin
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P223: Do not allow contact with water.
P231+P232: Handle under inert gas/... Protect from moisture.
P370+P378: In case of fire: Use ... to extinguish.
P422: Store contents under ...
P210: Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.
WGK Germany 3
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