Borane dimethyl sulfide complex - 2.0 M solution in THF, high purity , CAS No.13292-87-0

  • 2.0 M solution in THF
Item Number
B130054
Grouped product items
SKUSizeAvailabilityPrice Qty
B130054-100ml
100ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$58.90
B130054-500ml
500ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$220.90

Basic Description

SynonymsBMS | MCQRPQCQMGVWIQ-UHFFFAOYSA-N | Dimethyl sulphide borane | Dimethyl sulfide borane | borane methylsulphide | boron dimethyl sulfide | FT-0652013 | Borane dimethyl sulfide complex 2.0 M in THF | UNII-93TWS7F2GX | (Dimethyl sulfide)trihydroboron | (Meth
Specifications & Purity2.0 M solution in THF
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

Borane dimethyl sulfide complex is a stable source of borane used in hydroboration reduction reactions in organic synthesis. Studies indicate that Borane dimethyl sulfide complex can selectively suppress &alpha-hydroxyesters.
Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides. Reactant used as a regioselective reducing agent Reactant involved in: &bull Hydroboration / oxidation Synthesis of cage compounds

Names and Identifiers

INCHI InChI=1S/C2H6S.B/c1-3-2;/h1-2H3;
InChi Key MCQRPQCQMGVWIQ-UHFFFAOYSA-N
Canonical SMILES [B].CSC
Isomeric SMILES [B].CSC
WGK Germany 3
PubChem CID 9833925
Molecular Weight 75.97
Beilstein 3663489

Certificates

Certificate of Analysis(COA)

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Find and download the COA for your product by matching the lot number on the packaging.

8 results found

Lot NumberCertificate TypeDateItem
A2422277Certificate of AnalysisNov 20, 2024 B130054
A2422279Certificate of AnalysisNov 20, 2024 B130054
A2422287Certificate of AnalysisNov 20, 2024 B130054
G2216102Certificate of AnalysisJan 12, 2024 B130054
F2118290Certificate of AnalysisMar 15, 2023 B130054
G2216076Certificate of AnalysisJul 01, 2022 B130054
G2216103Certificate of AnalysisJul 01, 2022 B130054
D2028099Certificate of AnalysisFeb 23, 2022 B130054

Chemical and Physical Properties

SensitivityAir & Moisture Sensitive
Flash Point(°F)-31 °F
Flash Point(°C)-35 °C

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS05,   GHS02
Signal Danger
Hazard Statements

H315:Causes skin irritation

H335:May cause respiratory irritation

H260:In contact with water releases flammable gases which may ignite spontaneously

H318:Causes serious eye damage

H225:Highly Flammable liquid and vapor

H301+H311:Toxic if swallowed or in contact with skin

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P223:Do not allow contact with water.

P231+P232:Handle under inert gas/... Protect from moisture.

P370+P378:In case of fire: Use ... to extinguish.

P422:Store contents under ...

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

WGK Germany 3

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Citations of This Product

1. Shibin Wu, Keru Song, Jianwen Wang, Siyu Huang, Fengyue Shi, Guangdong Zhao.  (2023)  Microstructure and phase evolution behavior of SiZrBC ceramic precursors synthesized via sol–gel method.  JOURNAL OF SOLID STATE CHEMISTRY,  321  (123910).  [PMID:] [10.1016/j.jssc.2023.123910]
2. Bijie Wang, Yujie Song, Xiao Zhang, Ke Chen, Ming Liu, Xiao Hu, Liu He, Qing Huang.  (2022)  Polymer derived SiBCN(O) ceramics with tunable element content.  CERAMICS INTERNATIONAL,  48  (10280).  [PMID:] [10.1016/j.ceramint.2021.12.246]
3. Bijie Wang, Ke Chen, Tianhao Li, Xun Sun, Ming Liu, Lingwei Yang, Xiao (Matthew) Hu, Jian Xu, Liu He, Qing Huang, Linbin Jiang, Yujie Song.  (2021)  High-Temperature Resistant Polyborosilazanes with Tailored Structures.  Polymers,  13  (3): (467).  [PMID:33535636] [10.3390/polym13030467]
4. Hui-Ling Duan, Xu Deng, Jun Wang, Li Fan, Yu-Cheng Yang, Zhi-Qi Zhang.  (2020)  Ethanolamine- and amine-functionalized porous cyclodextrin polymers for efficient removal of anionic dyes from water.  EUROPEAN POLYMER JOURNAL,  133  (109762).  [PMID:] [10.1016/j.eurpolymj.2020.109762]

References

1. Shibin Wu, Keru Song, Jianwen Wang, Siyu Huang, Fengyue Shi, Guangdong Zhao.  (2023)  Microstructure and phase evolution behavior of SiZrBC ceramic precursors synthesized via sol–gel method.  JOURNAL OF SOLID STATE CHEMISTRY,  321  (123910).  [PMID:] [10.1016/j.jssc.2023.123910]
2. Bijie Wang, Yujie Song, Xiao Zhang, Ke Chen, Ming Liu, Xiao Hu, Liu He, Qing Huang.  (2022)  Polymer derived SiBCN(O) ceramics with tunable element content.  CERAMICS INTERNATIONAL,  48  (10280).  [PMID:] [10.1016/j.ceramint.2021.12.246]
3. Bijie Wang, Ke Chen, Tianhao Li, Xun Sun, Ming Liu, Lingwei Yang, Xiao (Matthew) Hu, Jian Xu, Liu He, Qing Huang, Linbin Jiang, Yujie Song.  (2021)  High-Temperature Resistant Polyborosilazanes with Tailored Structures.  Polymers,  13  (3): (467).  [PMID:33535636] [10.3390/polym13030467]
4. Hui-Ling Duan, Xu Deng, Jun Wang, Li Fan, Yu-Cheng Yang, Zhi-Qi Zhang.  (2020)  Ethanolamine- and amine-functionalized porous cyclodextrin polymers for efficient removal of anionic dyes from water.  EUROPEAN POLYMER JOURNAL,  133  (109762).  [PMID:] [10.1016/j.eurpolymj.2020.109762]

Solution Calculators