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Borane dimethyl sulfide complex - 5.0 M in diethyl ether, high purity , CAS No.13292-87-0 2 Citations
Basic Description Synonyms Dimethyl sulfide borane | (Dimethyl sulfide)trihydroboron | borane Me2S | BMS | borane DMS | borane methylsulfide | borane dimethyl sulfide | borane dimethylsulfide | DMS Borane | Borane-dimethyl sulfide | boron;methylsulfanylmethane | MFCD00013189 Specifications & Purity 5.0 M in diethyl ether Storage Temp Store at 2-8°C,Protected from light,Argon charged Shipped In Wet ice Product Description Borane dimethyl sulfide complex is a stable source of borane used in hydroboration reduction reactions in organic synthesis. Studies indicate that Borane dimethyl sulfide complex can selectively suppress &alpha-hydroxyesters. Usually used as a regioselective reducing agent,involved in hydroboration / oxidation and synthesis of cage compounds.
Names and Identifiers INCHI InChI=1S/C2H6S.B/c1-3-2;/h1-2H3; InChi Key MCQRPQCQMGVWIQ-UHFFFAOYSA-N Canonical SMILES [B].CSC Isomeric SMILES [B].CSC WGK Germany 3 PubChem CID 9833925 Molecular Weight 75.97 Beilstein 3663489
Chemical and Physical Properties Sensitivity Heat,Light,Air,Moisture sensitive. Flash Point(°F) -31 °F Flash Point(°C) -35 °C
Safety and Hazards(GHS) Pictogram(s) GHS06 , GHS05 , GHS02 Signal Danger Hazard Statements H315: Causes skin irritation
H335: May cause respiratory irritation
H260: In contact with water releases flammable gases which may ignite spontaneously
H318: Causes serious eye damage
H225: Highly Flammable liquid and vapor
H301+H311: Toxic if swallowed or in contact with skin
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P223: Do not allow contact with water.
P231+P232: Handle under inert gas/... Protect from moisture.
P370+P378: In case of fire: Use ... to extinguish.
P422: Store contents under ...
P210: Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.
WGK Germany 3
Citations of This Product 1. Shibin Wu, Keru Song, Jianwen Wang, Siyu Huang, Fengyue Shi, Guangdong Zhao. (2023) Microstructure and phase evolution behavior of SiZrBC ceramic precursors synthesized via sol–gel method. JOURNAL OF SOLID STATE CHEMISTRY, 321 (123910). [PMID: ] 2. Bijie Wang, Yujie Song, Xiao Zhang, Ke Chen, Ming Liu, Xiao Hu, Liu He, Qing Huang. (2022) Polymer derived SiBCN(O) ceramics with tunable element content. CERAMICS INTERNATIONAL, 48 (10280). [PMID: ]
References 1. Shibin Wu, Keru Song, Jianwen Wang, Siyu Huang, Fengyue Shi, Guangdong Zhao. (2023) Microstructure and phase evolution behavior of SiZrBC ceramic precursors synthesized via sol–gel method. JOURNAL OF SOLID STATE CHEMISTRY, 321 (123910). [PMID: ] 2. Bijie Wang, Yujie Song, Xiao Zhang, Ke Chen, Ming Liu, Xiao Hu, Liu He, Qing Huang. (2022) Polymer derived SiBCN(O) ceramics with tunable element content. CERAMICS INTERNATIONAL, 48 (10280). [PMID: ]
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