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Borane dimethyl sulfide complex - 9.8M in Dimethylthioamidine, high purity , CAS No.13292-87-0(Dimethylthioamidine)

9.8M in Dimethylthioamidine

CAS#: 13292-87-0(Dimethylthioamidine)
Formula: (CH₃)₂S·BH₃
Molecular Weight: 75.97
Beilstein Registry Number: 3663489
EC Number: 236-313-6
PubChem CID: 9833925

Item Number

B431899

Grouped product items
SKU	Size	Availability	Price
B431899-25ml	25ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$145.90
B431899-4×25ml	4×25ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$525.90
B431899-500ml	500ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$1,118.90

Basic Description

Synonyms	13292-87-0\|Dimethyl sulfide borane\|Borane-dimethyl sulfide\|borane dimethylsulfide\|borane dimethyl sulfide\|BMS\|(Dimethyl sulfide)trihydroboron\|MFCD00013189\|boron;methylsulfanylmethane\|borane DMS\|borane Me2S\|DMS Borane\|borane methylsulfide\|borane dimethylsu
Specifications & Purity	9.8M in Dimethylthioamidine
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice
Product Description	Borane dimethyl sulfide complex (BMS) is a commonly used reagent and a mediator for hydroboration reaction for the preparation of organoborane compounds, which are utilized as key intermediates in organic synthesis. BMS is also employed as a reducing agent for the reduction of various functional groups such as aldehydes, ketones, epoxides, esters, and carboxylic acids to corresponding alcohols. Application Borane-dimethyl sulfide (BH 3 Me 2 S) can be used as a reagent: For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate. For the conversion of ozonides to alcohols. In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C 3 -symmetric tripodal hydroxyamide as a ligand. For the hydroboration reduction and other applications. With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. Other Notes 10.0-10.2 M as BH 3 . May contain excess methyl sulfide.

Names and Identifiers

INCHI	InChI=1S/C2H6S.B/c1-3-2;/h1-2H3;
InChi Key	MCQRPQCQMGVWIQ-UHFFFAOYSA-N
Canonical SMILES	[B].CSC
Isomeric SMILES	[B].CSC
WGK Germany	3
PubChem CID	9833925
Molecular Weight	75.97
Beilstein	3663489

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3 results found

Lot Number	Certificate Type	Date	Item
B2427024	Certificate of Analysis	Jan 19, 2024	B431899
B2427025	Certificate of Analysis	Jan 19, 2024	B431899
B2427026	Certificate of Analysis	Jan 19, 2024	B431899

Safety and Hazards(GHS)

Pictogram(s)	GHS06, GHS08, GHS05, GHS02
Signal	Danger
Hazard Statements	H315:Causes skin irritation H335:May cause respiratory irritation H260:In contact with water releases flammable gases which may ignite spontaneously H318:Causes serious eye damage H225:Highly Flammable liquid and vapor H301+H311:Toxic if swallowed or in contact with skin
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P223:Do not allow contact with water. P231+P232:Handle under inert gas/... Protect from moisture. P370+P378:In case of fire: Use ... to extinguish. P422:Store contents under ... P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.
WGK Germany	3

FAQs and Articles

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Boranes (Dimethylsulfide Borane, Borane-Tetrahydrofuran Complex)

Categories: Technical articles

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Reducing agent C-H Functionalization Boronic Acids and Derivatives Boranes

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