Borane tetrahydrofuran complex solution - 1.0 M in THF,contains 0.005 M sodium borohydride as stabilizer, high purity , CAS No.14044-65-6

  • 1.0 M in THF,contains 0.005 M sodium borohydride as stabilizer
Item Number
B110263
Grouped product items
SKUSizeAvailabilityPrice Qty
B110263-25ml
25ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$19.90
B110263-100ml
100ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$54.90
B110263-500ml
500ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$189.90
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B (Boron) Compounds

Basic Description

SynonymsTetrahydrofuran borane | Trihydro(tetrahydrofuran)boron | BORANE-THF (1:1) | Borane-THF complex (1:1)
Specifications & Purity1.0 M in THF,contains 0.005 M sodium borohydride as stabilizer
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

Borane tetrahydrofuran complex (BH3-THF) is widely used as a reducing agent in organic synthesis. It is also used as a reagent in hydroboration reactions.
BH3-THF can be used as a reducing agent for the reduction of various functional groups such as carboxylic acids, aldehydes, ketones, esters, acid chlorides, nitriles, epoxides, amides, lactones, oximes, and imines into corresponding alcohols and amines. Grignard reagents, arylmercury, arylthalium, and allyl and propargyllithium compounds react with BH3−THF to give organoboranes, which can be oxidized to the corresponding alcohols, phenols, and 1,3-diols.
It can also be used:
To synthesize the chiral borane catalyst, which is used in the enantioselective halo-aldol reaction.
To prepare 9-unsubstituted acridines by reduction of corresponding acridones.
To reduce nylon surface amide groups to secondary amines.

Names and Identifiers

INCHI InChI=1S/C4H8O.B/c1-2-4-5-3-1;/h1-4H2;
InChi Key UWTDFICHZKXYAC-UHFFFAOYSA-N
Canonical SMILES [B].C1CCOC1
Isomeric SMILES [B].C1CCOC1
WGK Germany 3
PubChem CID 11062302
UN Number 3399
Molecular Weight 85.94
Beilstein 3668402
Reaxy-Rn 3668402

Certificates

Certificate of Analysis(COA)

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15 results found

Lot NumberCertificate TypeDateItem
I2402530Certificate of AnalysisAug 27, 2024 B110263
I2402533Certificate of AnalysisAug 27, 2024 B110263
I2402538Certificate of AnalysisAug 27, 2024 B110263
I2402553Certificate of AnalysisAug 27, 2024 B110263
I2403017Certificate of AnalysisAug 27, 2024 B110263
C2405203Certificate of AnalysisFeb 24, 2024 B110263
L2319128Certificate of AnalysisDec 16, 2023 B110263
L2319496Certificate of AnalysisDec 16, 2023 B110263
H2329026Certificate of AnalysisJul 08, 2023 B110263
H2329027Certificate of AnalysisJul 08, 2023 B110263
H2329028Certificate of AnalysisJul 08, 2023 B110263
G2222097Certificate of AnalysisJun 18, 2022 B110263
G2222098Certificate of AnalysisJun 18, 2022 B110263
C2323027Certificate of AnalysisNov 25, 2021 B110263
L22151206Certificate of AnalysisNov 25, 2021 B110263

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Chemical and Physical Properties

SolubilityMiscible and reacts violently with water.
SensitivityHeat,Air,Moisture sensitive.
Flash Point(°F)1.4 °F
Flash Point(°C)-17 °C
Boil Point(°C)35℃

Safety and Hazards(GHS)

Pictogram(s) GHS07,   GHS02
Signal Danger
Hazard Statements

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H260:In contact with water releases flammable gases which may ignite spontaneously

H225:Highly Flammable liquid and vapor

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P223:Do not allow contact with water.

P231+P232:Handle under inert gas/... Protect from moisture.

P370+P378:In case of fire: Use ... to extinguish.

P422:Store contents under ...

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

WGK Germany 3
Reaxy-Rn 3668402

Related Documents

Citations of This Product

1. Yongjie Zhang, Huayi Li, Yu Zhang, Qian Li, Zhi Ma, Jin-Yong Dong, Youliang Hu.  (2014)  Synthesis and Properties of Polyethylene-Bound Antioxidants.  MACROMOLECULAR CHEMISTRY AND PHYSICS,  215  (8): (763-775).  [PMID:] [10.1002/macp.201300749]

References

1. Yongjie Zhang, Huayi Li, Yu Zhang, Qian Li, Zhi Ma, Jin-Yong Dong, Youliang Hu.  (2014)  Synthesis and Properties of Polyethylene-Bound Antioxidants.  MACROMOLECULAR CHEMISTRY AND PHYSICS,  215  (8): (763-775).  [PMID:] [10.1002/macp.201300749]

Solution Calculators