| SKU | Size | Availability | Price | Qty |
|---|---|---|---|---|
| B431394-100ml | 100ml | Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding. | $199.90 |
| Synonyms | Boron trifluoride etherate|109-63-7|Borontrifluorideetherate|ethoxyethane;trifluoroborane|Boron trifluoride ethyl ether|Boron trifluoride-diethyl etherate|ethoxyethane; trifluoroborane|174674-80-7|BF3.Et2O|boron trifluoride diethyl ether|boron trifluoride |
|---|---|
| Specifications & Purity | Distillation grade, ≥46.5% BF3 basis |
| Storage Temp | Store at 2-8°C |
| Shipped In | Wet ice |
| Grade | Distillation grade |
| Product Description | Application Catalyst in the synthesis of polyol chains. Reagent for the coupling of imines to allylstannanes and 4′-nitrobenzenesulfenanilide to alkenes and alkynes. |
| IUPAC Name | ethoxyethane;trifluoroborane |
|---|---|
| INCHI | InChI=1S/C4H10O.BF3/c1-3-5-4-2;2-1(3)4/h3-4H2,1-2H3; |
| InChi Key | KZMGYPLQYOPHEL-UHFFFAOYSA-N |
| Canonical SMILES | B(F)(F)F.CCOCC |
| Isomeric SMILES | B(F)(F)F.CCOCC |
| WGK Germany | 1 |
| PubChem CID | 8000 |
| UN Number | 2604 |
| Packing Group | I |
| Molecular Weight | 141.93 |
| Beilstein | 3909607 |
| Reaxy-Rn | 3909607 |
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| Refractive Index | 1.348 |
|---|---|
| Flash Point(°F) | 137.3 °F - closed cup |
| Flash Point(°C) | <22℃ |
| Boil Point(°C) | 125.7°C |
| Melt Point(°C) | -60.4°C |
| Pictogram(s) | GHS08, GHS05, GHS07, GHS02 |
|---|---|
| Signal | Danger |
| Hazard Statements | H314:Causes severe skin burns and eye damage H302:Harmful if swallowed H318:Causes serious eye damage H226:Flammable liquid and vapor H332:Harmful if inhaled H330:Fatal if inhaled H372:Causes damage to organs through prolonged or repeated exposure |
| Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P284:[In case of inadequate ventilation] Wear respiratory protection. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P330:Rinse mouth. P320:Specific treatment is urgent (see ... on this label). P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. P319:Get medical help if you feel unwell. |
| WGK Germany | 1 |
| Reaxy-Rn | 3909607 |
| Class | 8, 3 |
| Merck Index | 1350 |
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| 1. T Saitoh,T Ichikawa,Y Horiguchi,J Toda,T Sano. (2001-08-23) A synthesis of 3-phenyl-1,2,3,4-tetrahydroisoquinoline and 2-phenyl-1,2,4,5-tetrahydro-3H-3-benzazepine via Pummerer-type cyclization: enhancing effect of boron trifluoride diethyl etherate on the cyclization.. Chemical & pharmaceutical bulletin, 49 ((8)): (979-984). [PMID:11515589] |
| 2. Myriam Roussel,Stéphane Moutard,Bruno Perly,Martine Lefeuvre,Thierry Benvegnu,Daniel Plusquellec. (2003-02-01) Beta-anomeric selectivity in the glycosidation of D-mannofuranurono-6,3-lactone catalyzed by boron trifluoride diethyl etherate.. Carbohydrate research, 338 ((4)): (375-378). [PMID:12559736] |
| 3. Kiyoshi Ikeda,Yasuhiro Torisawa,Takao Nishi,Junichi Minamikawa,Kiyoshi Tanaka,Masayuki Sato. (2003-06-24) Glycosylation of sialyl acetates with a novel catalyst combination: bismuth triflate and BF3.OEt2 system.. Bioorganic & medicinal chemistry, 11 ((14)): (3073-3076). [PMID:12818669] |
| 4. M S F Lie Ken Jie,M M L Lau,C N W Lam,M S Alam,J O Metzger,U Biermann. (2003-09-23) Novel halo-oxo-allenic fatty ester derivatives from epoxidized methyl santalbate (methyl trans-11-octadecen-9-ynoate).. Chemistry and physics of lipids, 125 ((2)): (93-101). [PMID:14499468] |
| 5. Bjart Frode Lutnaes,Geir Kildahl-Andersen,Jostein Krane,Synnøve Liaaen-Jensen. (2004-07-22) Delocalized carotenoid cations in relation to the soliton model.. Journal of the American Chemical Society, 126 ((29)): (8981-8990). [PMID:15264829] |
| 6. Barry M Trost,Jiayi Xu. (2007-10-30) The O-acylation of ketone enolates by allyl 1H-imidazole-1-carboxylate mediated with boron trifluoride etherate: a convenient procedure for the synthesis of substituted allyl enol carbonates.. The Journal of organic chemistry, 72 ((24)): (9372-9375). [PMID:17963405] |
| 7. Brajendra K Sharma,Zengshe Liu,Atanu Adhvaryu,Sevim Z Erhan. (2008-04-11) One-pot synthesis of chemically modified vegetable oils.. Journal of agricultural and food chemistry, 56 ((9)): (3049-3056). [PMID:18399638] |
| 8. Yong-Gang Xiang,Xiang-Wu Wang,Xiao Zheng,Yuan-Ping Ruan,Pei-Qiang Huang. (2009-11-12) One-pot cross-coupling of N-acyl N,O-acetals with alpha,beta-unsaturated compounds.. Chemical communications (Cambridge, England), ((45)(45)): (7045-7047). [PMID:19904389] |
| 9. Tito Akindele,Ken-ichi Yamada,Takumi Sejima,Masaru Maekawa,Yasutomo Yamamoto,Mayu Nakano,Kiyoshi Tomioka. (2010-02-02) Stereoselective radical addition of an acetal to sterically tuned enantiomerically pure N-sulfinyl imines.. Chemical & pharmaceutical bulletin, 58 ((2)): (265-269). [PMID:20118594] |
| 10. Meng-Yang Chang,Chung-Han Lin,Yeh-Long Chen,Ching-Yao Chang,Ru-Ting Hsu. (2010-03-03) BF3-promoted synthesis of diarylhexahydrobenzo[f]isoquinoline.. Organic letters, 12 ((6)): (1176-1179). [PMID:20192201] |
| 11. Devendra J Vyas,Roland Fröhlich,Martin Oestreich. (2010-09-10) Stereochemical surprises in the Lewis acid-mediated allylation of isatins.. The Journal of organic chemistry, 75 ((19)): (6720-6723). [PMID:20825233] |
| 12. Mariana Macias-Alonso,Jacek W Morzycki,Martin A Iglesias-Arteaga. (2010-12-21) Studies on the BF3·Et2O catalyzed Baeyer-Villiger reaction of spiroketalic steroidal ketones.. Steroids, 76 ((3)): (317-323). [PMID:21167855] |
| 13. Hui Xu,Xiao Xiao,Xue-Fei Zhao,Yong Guo,Xiao-Jun Yao. (2011-06-03) Unexpectedly convenient and stereoselective synthesis of 4α-acyloxy-2-chloropodophyllotoxins in the presence of BF₃ ·Et₂O.. Bioorganic & medicinal chemistry letters, 21 ((13)): (4008-4012). [PMID:21632246] |
| 14. Omar Viñas-Bravo,Roxana Martinez-Pascual,José Luis Vega-Baez,Víctor Gómez-Calvario,Jesús Sandoval-Ramírez,Sara Montiel-Smith,Socorro Meza-Reyes,Alejandra López-De Rosas,Mónica Martínez-Montiel,Mayra Reyes,José A Ruiz. (2011-11-09) Rapid conversion of spirostans into furostan skeletons at room temperature.. Steroids, 77 ((1-2)): (59-66). [PMID:22061618] |
| 15. Karen M Ruíz-Pérez,Margarita Romero-Ávila,Verónica Tinajero-Delgado,Marcos Flores-Álamo,Martín A Iglesias-Arteaga. (2012-03-28) BF₃·Et₂O-induced stereoselective aldol reaction with benzaldehyde, and steroid sapogenins and its application to a convenient synthesis of dinorcholanic lactones.. Steroids, 77 ((7)): (819-828). [PMID:22449388] |
| 16. Wen Jen Lin,Wan Yi Hsu. (2015-02-11) Pegylation effect of chitosan based polyplex on DNA transfection.. Carbohydrate polymers, 120 (7-14). [PMID:25662681] |
| 17. Na Kong,Manishkumar R Shimpi,Olof Ramström,Mingdi Yan. (2015-03-10) Carbohydrate conjugation through microwave-assisted functionalization of single-walled carbon nanotubes using perfluorophenyl azides.. Carbohydrate research, 405 (33-38). [PMID:25746392] |
| 18. Krzysztof Babiuch,Aydan Dag,Jiacheng Zhao,Hongxu Lu,Martina H Stenzel. (2015-06-10) Carbohydrate-Specific Uptake of Fucosylated Polymeric Micelles by Different Cancer Cell Lines.. Biomacromolecules, 16 ((7)): (1948-1957). [PMID:26057004] |
| 19. Christopher A DeRosa,Caroline Kerr,Ziyi Fan,Milena Kolpaczynska,Alexander S Mathew,Ruffin E Evans,Guoqing Zhang,Cassandra L Fraser. (2015-10-20) Tailoring Oxygen Sensitivity with Halide Substitution in Difluoroboron Dibenzoylmethane Polylactide Materials.. ACS applied materials & interfaces, 7 ((42)): (23633-23643). [PMID:26480236] |
| 20. Francesca Salis,Ana B Descalzo,Elena Benito-Peña,María C Moreno-Bondi,Guillermo Orellana. (2018-04-18) Highly Fluorescent Magnetic Nanobeads with a Remarkable Stokes Shift as Labels for Enhanced Detection in Immunoassays.. Small (Weinheim an der Bergstrasse, Germany), 14 ((20)): (e1703810-e1703810). [PMID:29665269] |
| 21. Masanobu Yamamoto,Leonard Blaschek,Elena Subbotina,Shinya Kajita,Edouard Pesquet. (2020-07-22) Importance of Lignin Coniferaldehyde Residues for Plant Properties and Sustainable Uses.. ChemSusChem, 13 ((17)): (4400-4408). [PMID:32692480] |
| 22. Marcel S F Lie Ken Jie,Corey N W Lam. (2004-11-24) Reaction of mono-epoxidized conjugated linoleic acid ester with boron trifluoride etherate complex.. Lipids, 39 ((6)): (583-587). [PMID:15554159] |
| 23. U C Reddy,S Bondalapati,Anil K Saikia. (2009-02-17) Stereoselective one-pot, three-component synthesis of 4-aryltetrahydropyran via Prins-Friedel-Crafts reaction.. The Journal of organic chemistry, 74 ((6)): (2605-2608). [PMID:19216514] |
| 24. Ryotaro Nakaya,Shigeo Yasuda,Hideki Yorimitsu,Koichiro Oshima. (2011-06-23) (1-Alkynyl)dicarbonylcyclopentadienyliron complexes as electron-rich alkynes in organic synthesis: BF3-mediated [2+2] cycloaddition/ring-opening providing (2-alkenyl-1-imino)iron complexes.. Chemistry (Weinheim an der Bergstrasse, Germany), 17 ((31)): (8559-8561). [PMID:21695739] |
| 25. George R Pettit,Ricardo F Mendonça,John C Knight,Robin K Pettit. (2011-09-09) The cephalostatins. 21. Synthesis of bis-steroidal pyrazine rhamnosides (1).. Journal of natural products, 74 ((9)): (1922-1930). [PMID:21899266] |
