BrettPhos Pd G3 - 95%, high purity , CAS No.1470372-59-8

  • ≥95%
Item Number
B167368
Grouped product items
SKUSizeAvailabilityPrice Qty
B167368-250mg
250mg
In stock
$65.90
B167368-1g
1g
In stock
$253.90
B167368-5g
5g
In stock
$1,083.90
B167368-10g
10g
In stock
$1,577.90

Discover BrettPhos Pd G3 by Aladdin Scientific in 95% for only $65.90. Available - in Ligands at Aladdin Scientific. Tags: .

Basic Description

Synonyms1470372-59-8 | Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) | MFCD22572666 | dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;methanesulfonic ac
Specifications & Purity95%
Storage TempRoom temperature,Argon charged
Shipped InNormal
Product Description

Description
BrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. BrettPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. Application
BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones. It may be used in the synthesis of following compounds: [Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]2 and AgOTf. [Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]2 and AgOTf. [Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf. Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]2.

Names and Identifiers

Pubchem Sid488202630
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488202630
IUPAC Name dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;methanesulfonic acid;palladium;2-phenylaniline
INCHI InChI=1S/C35H53O2P.C12H10N.CH4O3S.Pd/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h19-25,27-28H,9-18H2,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;;
InChi Key QUEIWHJXJNGIMT-UHFFFAOYSA-N
Canonical SMILES CC(C)C1=CC(=C(C(=C1)C(C)C)C2=C(C=CC(=C2P(C3CCCCC3)C4CCCCC4)OC)OC)C(C)C.CS(=O)(=O)O.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd]
Isomeric SMILES CC(C)C1=CC(=C(C(=C1)C(C)C)C2=C(C=CC(=C2P(C3CCCCC3)C4CCCCC4)OC)OC)C(C)C.CS(=O)(=O)O.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd]
WGK Germany 3
PubChem CID 117064810
Molecular Weight 906.50

Certificates

Certificate of Analysis(COA)

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11 results found

Lot NumberCertificate TypeDateItem
L2107009Certificate of AnalysisSep 19, 2023 B167368
G2306125Certificate of AnalysisJul 15, 2023 B167368
D2324124Certificate of AnalysisMay 09, 2023 B167368
B23081108Certificate of AnalysisFeb 18, 2023 B167368
B23081123Certificate of AnalysisFeb 18, 2023 B167368
B23081147Certificate of AnalysisFeb 18, 2023 B167368
B23081148Certificate of AnalysisFeb 18, 2023 B167368
B23081178Certificate of AnalysisFeb 18, 2023 B167368
B23081179Certificate of AnalysisFeb 18, 2023 B167368
B23081258Certificate of AnalysisFeb 18, 2023 B167368
I2220063Certificate of AnalysisOct 14, 2022 B167368

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Chemical and Physical Properties

Melt Point(°C)150-193 °C (decomposition)

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3

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