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Bromotrimethylsilane - contains copper as stabilizer, 98%, high purity , CAS No.2857-97-8

≥98%(GC)
stabilized with copper

CAS#: 2857-97-8
Formula: C₃H₉BrSi
Molecular Weight: 153.09
Beilstein Registry Number: 1731135
EC Number: 220-672-0
MDL number: MFCD00000048
PubChem CID: 76113

Item Number

B109499

Grouped product items
SKU	Size	Availability	Price
B109499-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$26.90
B109499-25g	25g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$69.90
B109499-100g	100g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$175.90
B109499-250g	250g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$395.90
B109499-500g	500g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$711.90

Discover Bromotrimethylsilane by Aladdin Scientific in contains copper as stabilizer, 98% for only $26.90. Available - in Ligands at Aladdin Scientific. Tags: .

Basic Description

Synonyms	Bromotrimethylsilane\|2857-97-8\|Trimethylbromosilane\|Trimethylsilyl bromide\|Silane, bromotrimethyl-\|bromo(trimethyl)silane\|Trimethylsilicon bromide\|bromotrimethyl silane\|TMBS\|trimethylsilylbromide\|JHH5G299BX\|NSC-139857\|tmsbr\|TMS bromide\|bromotrimethylsilan
Specifications & Purity	contains copper as stabilizer, 98%
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice

Names and Identifiers

IUPAC Name	bromo(trimethyl)silane
INCHI	InChI=1S/C3H9BrSi/c1-5(2,3)4/h1-3H3
InChi Key	IYYIVELXUANFED-UHFFFAOYSA-N
Canonical SMILES	C[Si](C)(C)Br
Isomeric SMILES	C[Si](C)(C)Br
WGK Germany	3
PubChem CID	76113
UN Number	2920
Packing Group	II
Molecular Weight	153.09
Beilstein	1731135
Reaxy-Rn	1731135

Certificates

Certificate of Analysis(COA)

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14 results found

Lot Number	Certificate Type	Date	Item
A2203189	Certificate of Analysis	Oct 09, 2023	B109499
A2203190	Certificate of Analysis	Oct 09, 2023	B109499
A2203191	Certificate of Analysis	Oct 09, 2023	B109499
A2203192	Certificate of Analysis	Oct 09, 2023	B109499
D2419071	Certificate of Analysis	Oct 09, 2023	B109499
I2403054	Certificate of Analysis	Oct 09, 2023	B109499
K2315051	Certificate of Analysis	Oct 09, 2023	B109499
K2225209	Certificate of Analysis	Nov 28, 2022	B109499
L2001134	Certificate of Analysis	Sep 22, 2022	B109499
J2331018	Certificate of Analysis	Sep 22, 2022	B109499
L2001133	Certificate of Analysis	Sep 22, 2022	B109499
L2001132	Certificate of Analysis	Sep 22, 2022	B109499
L1817012	Certificate of Analysis	Aug 05, 2022	B109499
I2319070	Certificate of Analysis	Dec 15, 2021	B109499

Solubility

Miscible with carbon tetrachloride, chloroform, dichloroethane, acetonitrile, toluene, dichloromethane and hexane.

Sensitivity

Light sensitive.Hygroscopic.

Refractive Index

1.424

Flash Point(°F)

77 °F

Flash Point(°C)

32 °C

Boil Point(°C)

79°C

Melt Point(°C)

-43°C

Safety and Hazards(GHS)

Pictogram(s)	GHS05, GHS02
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage H318:Causes serious eye damage H225:Highly Flammable liquid and vapor H226:Flammable liquid and vapor
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	3
Reaxy-Rn	1731135
Class	8 (3)

References

1. J L Hughes,E J Leopold. (1995-09-01) Cleavage and deprotection of peptide resins using chloro- and bromotrialkylsilanes.. Peptide research, 8 ((5)): (298-300). [PMID:8589553]
2. J T Sparrow,O D Monera. (1996-09-01) Improvements to the TMSBr method of peptide resin deprotection and cleavage: application to large peptides.. Peptide research, 9 ((5)): (218-222). [PMID:9000246]
3. A Otaka. (2000-02-03) [Development of new deprotecting methodologies for peptides and application to studies on signaling mechanism].. Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 120 ((1)): (54-67). [PMID:10655782]
4. M Montejo,F Partal Ureña,F Márquez,J J López González. (2005-06-22) The vibrational spectra of (CH3)3SiX (S=H, F, Br) molecules, revisited Transferable scale factor sets for methylsilane derivatives.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 62 ((4-5)): (1058-1069). [PMID:15967707]
5. Takahiro Saito,Yoshihiro Nishimoto,Makoto Yasuda,Akio Baba. (2006-10-27) Direct coupling reaction between alcohols and silyl compounds: enhancement of Lewis acidity of Me3SiBr using InCl3.. The Journal of organic chemistry, 71 ((22)): (8516-8522). [PMID:17064028]
6. Syed Tasadaque A Shah,Patrick J Guiry. (2008-06-06) The chemoselective and efficient deprotection of silyl ethers using trimethylsilyl bromide.. Organic & biomolecular chemistry, 6 ((12)): (2168-2172). [PMID:18528578]
7. Veronika Mäde,Kathrin Bellmann-Sickert,Anette Kaiser,Jens Meiler,Annette G Beck-Sickinger. (2014-08-27) Position and length of fatty acids strongly affect receptor selectivity pattern of human pancreatic polypeptide analogues.. ChemMedChem, 9 ((11)): (2463-2474). [PMID:25156249]
8. M Nomizu,Y Inagaki,T Yamashita,A Ohkubo,A Otaka,N Fujii,P P Roller,H Yajima. (1991-02-01) Two-step hard acid deprotection/cleavage procedure for solid phase peptide synthesis.. International journal of peptide and protein research, 37 ((2)): (145-152). [PMID:2019476]
9. W F Steelant,E A Bruyneel,M M Mareel,E G Van den Eeckhout. (1995-05-01) Capillary gas chromatography of hexadecylphosphocholine in Caco-2T cells and cell culture media.. Analytical biochemistry, 227 ((1)): (246-250). [PMID:7668387]
10. Scott Miners,Hayley Moulding,Rohan de Silva,Seth Love. (2014-02-14) Reduced vascular endothelial growth factor and capillary density in the occipital cortex in dementia with Lewy bodies.. Brain pathology (Zurich, Switzerland), 24 ((4)): (334-343). [PMID:24521289]

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