Click Here for 5% Off Your First Aladdin Purchase!
Call +1 (833) 552-7181 or Contact us Earn $25 in coupons on your first order with Aladdin!
Toggle Nav
My Cart
Search
Advanced Search
Menu
Sign In
྾
main product photo

Cerium(III) chloride heptahydrate - purum p.a., ≥98.Corrosive substance.0% (AT), high purity , CAS No.18618-55-8

  • purum p.a.
Item Number
C432245
Grouped product items
SKUSizeAvailabilityPrice Qty
C432245-100g
100g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$193.90
C432245-500g
500g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$770.90
Add to Wish List Compare
Bulk Order  SDS  DATASHEET

Basic Description

SynonymsCerium trichloride heptahydrate, Cerous chloride heptahydrate
Specifications & Puritypurum p.a., ≥98.Corrosive substance.0% (AT)
Gradepurum p.a.
Product Description

General Description

Cerium(III) chloride heptahydrate is a mild Lewis acid. It participates in the allylation of aldehydes. Cerium(III) chloride heptahydrate in combination with sodium iodide supported on silica gel efficiently promotes Michael-type addition. Cerium(III) chloride heptahydrate in the presence of sodium iodide acts as an efficient catalyst for the Michael addition of 1,3-dicarbonyl compounds to α,β-unsaturated ketones and α,β-unsaturated aldehydes.


Application

Cerium(III) chloride heptahydrate was used for the preparation of undoped ceria nanoparticles. It may be used in the preparation of 2-indolyl-1-nitroalkane derivatives and CeO 2 -supported Co catalysts.

Names and Identifiers

WGK Germany 3
PubChem CID 375946670
Molecular Weight 372.58

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Chemical and Physical Properties

Melt Point(°C)848°C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS05
Signal Danger
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

WGK Germany 3

Related Documents

 SDS

 Specification Sheet

References

1. Giuseppe Bartoli,Marcella Bosco,Arianna Giuliani,Enrico Marcantoni,Alessandro Palmieri,Marino Petrini,Letizia Sambri.  (2004-02-14)  Investigation into the allylation reactions of aldehydes promoted by the CeCl3.7H2O-NaI system as a Lewis acid..  The Journal of organic chemistry,  69  ((4)): (1290-1297).  [PMID:14961683]
2. Giuseppe Bartoli,Marcella Bosco,Sandra Giuli,Arianna Giuliani,Laura Lucarelli,Enrico Marcantoni,Letizia Sambri,Elisabetta Torregiani.  (2005-02-26)  Efficient preparation of 2-indolyl-1-nitroalkane derivatives employing nitroalkenes as versatile Michael acceptors: new practical linear approach to alkyl 9h-beta-carboline-4-carboxylate..  The Journal of organic chemistry,  70  ((5)): (1941-1944).  [PMID:15730329]
3. Michael Reuman,Sandra Beish,Jeremy Davis,Mark J Batchelor,Martin C Hutchings,David F C Moffat,Peter J Connolly,Ronald K Russell.  (2008-01-04)  Scalable synthesis of the VEGF-R2 kinase inhibitor JNJ-17029259 using ultrasound-mediated addition of MeLi-CeCl3 to a nitrile..  The Journal of organic chemistry,  73  ((3)): (1121-1123).  [PMID:18171079]
4. Masami Kawagoe,Kiyoshi Ishikawa,Shou-Cun Wang,Kiwamu Yoshikawa,Szilvia Arany,Xiao-Ping Zhou,Jing-Shu Wang,Yasuharu Ueno,Yukio Koizumi,Takashi Kameda,Souichi Koyota,Toshihiro Sugiyama.  (2008-03-06)  Acute effects on the lung and the liver of oral administration of cerium chloride on adult, neonatal and fetal mice..  Journal of trace elements in medicine and biology : organ of the Society for Minerals and Trace Elements (GMS),  22  ((1)): (59-65).  [PMID:18319142]
5. Qinghua Meng,Yanhui Sun,Virginie Ratovelomanana-Vidal,Jean Pierre Genêt,Zhaoguo Zhang.  (2008-04-24)  CeCl3.7H2O: an effective additive in Ru-catalyzed enantioselective hydrogenation of aromatic alpha-ketoesters..  The Journal of organic chemistry,  73  ((10)): (3842-3847).  [PMID:18429633]
6. Shaoliang Chen,Andrea Olbrich,Rosemarie Langenfeld-Heyser,Eberhard Fritz,Andrea Polle.  (2008-10-08)  Quantitative X-ray microanalysis of hydrogen peroxide within plant cells..  Microscopy research and technique,  72  ((1)): (49-60).  [PMID:18837436]
7. Yanfang Wu,Yahua Chen,Yanjun Yi,Zhenguo Shen.  (2008-12-17)  Responses to copper by the moss Plagiomnium cuspidatum: hydrogen peroxide accumulation and the antioxidant defense system..  Chemosphere,  74  ((9)): (1260-1265).  [PMID:19070885]
8. Qufei Ling,Fashui Hong.  (2009-01-09)  Antioxidative role of cerium against the toxicity of lead in the liver of silver crucian carp..  Fish physiology and biochemistry,  36  ((3)): (367-376).  [PMID:19130280]
9. Na Li,Yanmei Duan,Min Zhou,Chao Liu,Fashui Hong.  (2009-04-28)  The effects of lanthanoid on the structure–function of lactate dehydrogenase from mice heart..  Biological trace element research,  132  ((1-3)): (164-175).  [PMID:19396407]
10. Na Li,Yanmei Duan,Chao Liu,Fashui Hong.  (2009-10-21)  The mechanism of CeCl3 on the activiation of alanine aminotransferase from mice..  Biological trace element research,  136  ((2)): (187-196).  [PMID:19841873]
11. Florian J Wegehaupt,Beatrice Sener,Thomas Attin,Patrick R Schmidlin.  (2010-04-20)  Application of cerium chloride to improve the acid resistance of dentine..  Archives of oral biology,  55  ((6)): (441-446).  [PMID:20399417]
12. Min Fei,Na Li,Yuguan Ze,Jie Liu,Sisi Wang,Xiuaolan Gong,Yanmei Duan,Xiaoyang Zhao,Han Wang,Fashui Hong.  (2010-04-22)  The mechanism of liver injury in mice caused by lanthanoids..  Biological trace element research,  140  ((3)): (317-329).  [PMID:20407842]
13. Giuseppe Bartoli,Roberto Cipolletti,Giustino Di Antonio,Riccardo Giovannini,Silvia Lanari,Mauro Marcolini,Enrico Marcantoni.  (2010-06-10)  A convergent approach to (R)-Tiagabine by a regio- and stereocontrolled hydroiodination of alkynes..  Organic & biomolecular chemistry,  8  ((15)): (3509-3517).  [PMID:20532411]
14. Haiquan Zhao,Zhe Cheng,Renping Hu,Jie Chen,Mengmeng Hong,Min Zhou,Xiaolan Gong,Ling Wang,Fashui Hong.  (2010-07-09)  Oxidative injury in the brain of mice caused by lanthanid..  Biological trace element research,  142  ((2)): (174-189).  [PMID:20614199]
15. Yuguan Ze,Jie Cheng,Jingwei Cai,Zhe Cheng,Renping Hu,Fashui Hong.  (2010-10-20)  The impairment of liver DNA conformation and liver apoptosis of mice caused by CeCl3..  Biological trace element research,  143  ((1)): (437-445).  [PMID:20957448]
16. Jie Cheng,Na Li,Zhe Cheng,Renping Hua,Jingwei Cai,Wenhui Si,Fashui Hong.  (2011-01-05)  Splenocyte apoptotic pathway in mice following oral exposure to cerium trichloride..  Chemosphere,  83  ((4)): (612-617).  [PMID:21195450]
17. Zhe Cheng,Na Li,Jie Cheng,Renping Hu,Guodong Gao,Yaling Cui,Xiaolan Gong,Ling Wang,Fashui Hong.  (2011-03-09)  Signal pathway of hippocampal apoptosis and cognitive impairment of mice caused by cerium chloride..  Environmental toxicology,  27  ((12)): (707-718).  [PMID:21384496]
18. Haiquan Zhao,Jie Cheng,Jingwei Cai,Zhe Cheng,Yaling Cui,Guodong Gao,Renping Hu,Xiaolan Gong,Ling Wang,Fashui Hong.  (2011-04-20)  Liver injury and its molecular mechanisms in mice caused by exposure to cerium chloride..  Archives of environmental contamination and toxicology,  62  ((1)): (154-164).  [PMID:21503700]
19. Motokazu Nakayama,Naofumi Shigemune,Takashi Tsugukuni,Hajime Tokuda,Takahisa Miyamoto.  (2011-05-10)  Difference of EGCg adhesion on cell surface between Staphylococcus aureus and Escherichia coli visualized by electron microscopy after novel indirect staining with cerium chloride..  Journal of microbiological methods,  86  ((1)): (97-103).  [PMID:21549162]
20. Na Li,Jie Cheng,Zhe Cheng,Renping Hu,Jingwei Cai,Guodong Gao,Yaling Cui,Ling Wang,Fashui Hong.  (2011-06-10)  Molecular mechanism of inflammatory response in mouse liver caused by exposure to CeCl₃..  Environmental toxicology,  28  ((6)): (349-358).  [PMID:21656643]
21. Bing Li,Yi Xie,Zhe Cheng,Jie Cheng,Rengping Hu,Yaling Cui,Xiaolan Gong,Weide Shen,Fashui Hong.  (2011-11-15)  Effects of added CeCl3 on resistance of fifth-instar larvae of silkworm to Bombyx mori nucleopolyhedrovirus infection..  Biological trace element research,  146  ((3)): (318-324).  [PMID:22076733]
22. Bing Li,Yi Xie,Zhe Cheng,Jie Cheng,Rengping Hu,Xuezi Sang,Suxin Gui,Qingqing Sun,Xiaolan Gong,Yaling Cui,Weide Shen,Fashui Hong.  (2012-06-19)  Cerium chloride improves protein and carbohydrate metabolism of fifth-instar larvae of Bombyx mori under phoxim toxicity..  Biological trace element research,  150  ((1-3)): (214-220).  [PMID:22707218]
23. Dipankar Dhara,Krishnanka S Gayen,Saikat Khamarui,Palash Pandit,Sukla Ghosh,Dilip K Maiti.  (2012-11-02)  CeCl3·7H2O catalyzed C-C and C-N bond-forming cascade cyclization with subsequent side-chain functionalization and rearrangement: a domino approach to pentasubstituted pyrrole analogues..  The Journal of organic chemistry,  77  ((22)): (10441-10449).  [PMID:23113545]
24. Xiaoming Tao,Wanfang Li,Xiaoming Li,Xiaomin Xie,Zhaoguo Zhang.  (2012-12-25)  Diastereo- and enantioselective asymmetric hydrogenation of α-amido-β-keto phosphonates via dynamic kinetic resolution..  Organic letters,  15  ((1)): (72-75).  [PMID:23259640]
25. Po-Jung Jimmy Huang,Feng Wang,Juewen Liu.  (2015-06-11)  Cleavable Molecular Beacon for Hg(2+) Detection Based on Phosphorothioate RNA Modifications..  Analytical chemistry,  87  ((13)): (6890-6895).  [PMID:26060876]
26. Recep Gök,Pia Bechtloff,Michael Ziegler,Hans-Georg Schmarr,Ulrich Fischer,Peter Winterhalter.  (2019-05-16)  Synthesis of Deuterium-Labeled 1,1,6-Trimethyl-1,2-dihydronaphthalene (TDN) and Quantitative Determination of TDN and Isomeric Vitispiranes in Riesling Wines by a Stable-Isotope-Dilution Assay..  Journal of agricultural and food chemistry,  67  ((22)): (6414-6422).  [PMID:31088051]
27. Xin Li,Rongliu Hu,Wenxue Zhu,Jinling Fan,Xinyue Pang,Na Wang,Liping Wang,Lipeng Yang,Chunyan Zhao,Chenyang He.  (2012-11-20)  MRT letter: localization of endogenous hydrogen peroxide by modified processes of sample preparation for transmission electron microscope in Escherichia coli..  Microscopy research and technique,  76  ((2)): (121-125).  [PMID:23161475]

Solution Calculators

Privacy Policy Website Terms of Use Return policy Terms and Conditions of Sale Cookie Policy Sales Policy
Products are chemical reagents for research use only and are not intended for human use. We do not sell to patients.
Copyright © 2023-present Aladdin Scientific Corp . All rights reserved.