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Cesium fluoride - purum p.a., ≥98.0%, high purity , CAS No.13400-13-0

36 Citations
Item Number
C431924
Grouped product items
SKUSizeAvailabilityPrice Qty
C431924-10g
10g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$86.90
C431924-50g
50g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$300.90
C431924-250g
250g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$1,281.90
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Basic Description

SynonymsAKOS015903973 | Cesium fluoride, purum p.a., >=98.0% | BP-12084 | fluorocesium | cesiumfluoride | cesium-fluoride | caesiumfluoride | DTXSID30893927 | T76A371HJR | cesium floride | cesium flouride | Cesium fluoride (CsF) | CESIUM FLUORIDE [MI] | Dicesium
Specifications & Puritypurum p.a., ≥98%
Gradepurum p.a.
Product Description

Application

Reactant for: Preparation of building blocks for synthesis of fluoroallylic compounds Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds Nucleophilic aromatic substitution (SNAr) reactions Used in the successful synthesis of a single-crystal Dion-Jacobson phase, CsLaTa 2 O 7 , that has applications in photocatalysis and superconductivity.


Other Notes

Catalyst for the reaction of silyl enol ethers with carbonyl compounds

Names and Identifiers

IUPAC Name cesium;fluoride
INCHI InChI=1S/Cs.FH/h;1H/q+1;/p-1
InChi Key XJHCXCQVJFPJIK-UHFFFAOYSA-M
Canonical SMILES [F-].[Cs+]
Isomeric SMILES [F-].[Cs+]
WGK Germany 3
RTECS FK9650000
PubChem CID 25953
UN Number 3288
Packing Group III
Molecular Weight 151.9
Reaxy-Rn 6184400

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Chemical and Physical Properties

Boil Point(°C)1251°C
Melt Point(°C)682 °C

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS08,   GHS05,   GHS07
Signal Danger
Hazard Statements

H315:Causes skin irritation

H301:Toxic if swallowed

H311:Toxic in contact with skin

H331:Toxic if inhaled

H314:Causes severe skin burns and eye damage

H318:Causes serious eye damage

H361:Suspected of damaging fertility or the unborn child

H301+H311+H331:Toxic if swallowed, in contact with skin or if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P361+P364:Take off immediately all contaminated clothing and wash it before reuse.

P203:Obtain, read and follow all safety instructions before use.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P316:IF SWALLOWED: Get emergency medical help immediately.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P318:if exposed or concerned, get medical advice.

P317:Get emergency medical help.

P332+P317:If skin irritation occurs: Get medical help.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3
RTECS FK9650000
Reaxy-Rn 6184400
Class 6.1
Merck Index 2012
RIDADR UN 3288 6.1 / PGIII

Related Documents

 SDS

 Specification Sheet

Citations of This Product

How to Cite Aladdin Scientific Products?
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2. Yi Qin, Lingxiang Chu, Tao Yang, Jing Wan, Qiang Zhou, Yanqing Ye, Huaijun Tang, Zhengliang Wang.  (2024)  Spectroscopic properties and thermal stability of a Mn4+-doped polyfluoride phosphor for application in solid-state lighting.  JOURNAL OF LUMINESCENCE,  267  (120388).  [PMID:] [10.1016/j.jlumin.2023.120388]
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4. Yanzhao Gao, Xianglei Meng, Shiqi Huang, Hui Wu, Liantao Jiang, Yu Zhou, Yuting Song, Yanyan Diao.  (2024)  Effects of MgO doping in Pd/γ-Al2O3 catalysts forthe hydrogenation of perfluoro olefin.  Molecular Catalysis,  552  (14): (113652).  [PMID:24382891] [10.1016/j.mcat.2023.113652]
5. Sisi Liang, Liping Song, Wendong Nie, Zihao Wang, Dejian Chen, Fulin Lin, Haomiao Zhu.  (2023)  Utilizing the Unique Redox Reaction Between Transition Metal Ions to Improve Mn4+ Doping Concentration and Achieve a High-Performance Red-Emitting Cs2NbF6: Mn4+ Phosphor.  Advanced Optical Materials,    (2301502).  [PMID:18000879] [10.1002/adom.202301502]
6. Junze Tong, Long Li, Haiqing Su, Feng Hong, Edwin Yue Bun Pun, Hai Lin.  (2023)  Novel Mn4+-activated fluoride red phosphors induced by alkaline metal ions replacement: Green synthesis, luminescence enhancement, high stability and application in warm WLED.  CERAMICS INTERNATIONAL,  49  (36162).  [PMID:] [10.1016/j.ceramint.2023.08.295]
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9. Konglan Chen, Shiyu Jia, Xueliang Zhang, Zifan Shao, Yayun Zhou, Ting Fan, Ting Yu, Tingting Deng.  (2023)  Stable Polyhedron-Cluster-Based Rigid Fluoride Framework toward Zero-Thermal-Quenching Near-Infrared Emission for Prolonged LED Applications.  INORGANIC CHEMISTRY,  62  (20): (7964–7975).  [PMID:37164943] [10.1021/acs.inorgchem.3c00789]
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12. Xueshuang Jiang, Yubo Long, Kaijin Chen, Qiaoxi Yu, Long Jiang, Zhenguo Chi, Siwei Liu, Jiarui Xu, Yi Zhang.  (2023)  Preparation, characterization, and bio-degradation studies of high-performance bio-based polyimides based on bicyclic diamines derived from citric acid.  Journal of Materials Chemistry C,  11  (3): (1082-1094).  [PMID:] [10.1039/D2TC03639H]
13. Song Qing, Xi Zhang, Tao Yang, Lingxiang Chu, Yayun Zhou, Jing Wan, Zhengliang Wang, Huaijun Tang, Qiang Zhou.  (2022)  Luminescence properties of Cr3+-doped near-infrared emissive fluoroyttrates for light-emitting diodes.  DALTON TRANSACTIONS,  51  (37): (14214-14220).  [PMID:36062936] [10.1039/D2DT02096C]
14. Ru-Ling Tang, Xin Lian, Xiao-Hui Li, Lei Huai, Wenlong Liu, Sheng-Ping Guo.  (2022)  From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**.  CHEMISTRY-A EUROPEAN JOURNAL,  28  (53): (e202201588).  [PMID:35726960] [10.1002/chem.202201588]
15. Zhihai Wu, Yichen Zhang, Bintao Du, Keyang Yang, Jun Wu, Tianyi Dai, Chengkun Dong, Jun Xia, Anlang Wu, Zhenfu Zhao.  (2022)  Disordered metasurface-enhanced perovskite composite films with ultra-stable and wide color gamut used for backlit displays.  Nano Energy,  100  (107436).  [PMID:] [10.1016/j.nanoen.2022.107436]
16. Chunyan Wang, Jihuai Wu, Shibo Wang, Xuping Liu, Xiaobing Wang, Zhongliang Yan, Liqiang Chen, Xiao Liu, Guodong Li, Weihai Sun, Zhang Lan.  (2021)  Alkali Metal Fluoride-Modified Tin Oxide for n–i–p Planar Perovskite Solar Cells.  ACS Applied Materials & Interfaces,  13  (42): (50083–50092).  [PMID:34648264] [10.1021/acsami.1c16519]
17. Zhihai Wu, Bintao Du, Guodong Tong, Hao Zhang, Yichen Zhang, Jun Xia, Zhenfu Zhao.  (2022)  Highly luminescent and stable inorganic perovskite micro-nanocomposites for crucial information encryption and decryption.  CHEMICAL ENGINEERING JOURNAL,  428  (131016).  [PMID:] [10.1016/j.cej.2021.131016]
18. Hongkun Liu, Bingbing Zhang, Ling Li, Ying Wang.  (2021)  Exploring Deep-UV Nonlinear Optical Materials with Enhanced Second Harmonic Generation Response and Birefringence in Fluoroaluminoborate Crystals.  ACS Applied Materials & Interfaces,  13  (26): (30853–30860).  [PMID:34157839] [10.1021/acsami.1c07442]
19. Xiaohuan Chang, Junjie Fu, Dongxing Kou, Wenhui Zhou, Zhengji Zhou, Shengjie Yuan, Yafang Qi, Zhi Zheng, Sixin Wu.  (2021)  Synergistic incorporation of NaF and CsF PDT for high efficiency kesterite solar cells: unveiling of grain interior and grain boundary effects.  Journal of Materials Chemistry A,  9  (1): (413-422).  [PMID:] [10.1039/D0TA08224D]
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25. Dan Li, Zhixiang Zeng, Di Lu, Feng Nie, Lele Wen, Lijing Zhu.  (2019)  Synthesis and Application of a Conjugated Polydianion-Based Single-Ion Conducting Polymer for High-Performance Solid Lithium-Ion Batteries.  ChemElectroChem,  6  (10): (2707-2714).  [PMID:] [10.1002/celc.201900553]
26. Chunyan Jiang, Mingying Peng, Alok M. Srivastava, Lihua Li, Mikhail G. Brik.  (2018)  Mn4+-Doped Heterodialkaline Fluorogermanate Red Phosphor with High Quantum Yield and Spectral Luminous Efficacy for Warm-White-Light-Emitting Device Application.  INORGANIC CHEMISTRY,  57  (23): (14705–14714).  [PMID:30451499] [10.1021/acs.inorgchem.8b02488]
27. Jiaqi Xu, Qilang Lin, Yan Yu, Dongyang Chen, Zhuoliang Ye.  (2017)  Facile synthesis of fluorinated poly(arylene ether)s with pendant sulfonic acid groups for proton exchange membranes.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  42  (27100).  [PMID:] [10.1016/j.ijhydene.2017.09.032]
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29. Pifu Gong, Siyang Luo, Ke Xiao, Qian Huang, Yi Yang, Hongwei Huang, Yicheng Wu, Chuangtian Chen, Zheshuai Lin.  (2017)  Structure and Characterization of a Zero-Dimensional Alkali Tin Dihalides Compound Cs3Sn3F2Cl7 with the [Sn2F2Cl4]2– Clusters.  INORGANIC CHEMISTRY,  56  (5): (3081–3086).  [PMID:28225268] [10.1021/acs.inorgchem.7b00036]
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