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Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver - 99.95% metals basis, high purity , CAS No.873297-19-9
Discover Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver by Aladdin Scientific in 99.95% metals basis for only $309.90. Available - in Ligands at Aladdin Scientific. Tags: .
Basic Description Synonyms [(IPr)AgCl] Specifications & Purity 99.95% metals basis Storage Temp Room temperature Shipped In Normal Product Description Product class
M-C, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands
Reaction type
Alkynylation, Allylic Alkylation, Cyclopropanation
Chemical properties
Theoretical metal content
Applications & references
Silver catalyzed alkene cyclopropanation.
Reference: Tetrah. 2009, 65, 1790 (DOI: 10.1016/j.tet.2008.10.114)
Alkynylation of isatins with phenylacteylene in water.
Reference: Green Chem. 2011, 13, 549 (DOI: 10.1039/C0GC00807A)
Allylic alkylation using in situ formed Pd(NHC)(phosphine) complexes.
Reference: J. Organomet. Chem. 2007, 692, 5754 (DOI:10.1016/j.jorganchem.2007.10.012)
Names and Identifiers INCHI 1S/C27H36N2.Ag.ClH/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;;1H/q;+1;/p-1 InChi Key GNVDTUAJUVJOFQ-UHFFFAOYSA-M Canonical SMILES CC(C)c1cccc(C(C)C)c1N2C=CN(\C2=Ag/Cl)c3c(cccc3C(C)C)C(C)C Isomeric SMILES CC(C)C1=C(C(=CC=C1)C(C)C)N2C=CN([C]2)C3=C(C=CC=C3C(C)C)C(C)C.Cl[Ag] WGK Germany 3 PubChem CID 49788523 Molecular Weight 531.92
Chemical and Physical Properties
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