The store will not work correctly when cookies are disabled.
Chloro(1-naphthyl)bis(triphenylphosphine)nickel(II) - 97%, high purity , CAS No.54806-25-6
Basic Description
Synonyms | 54806-25-6|Naphthalen-1-ylbis(triphenylphosphoranyl)nickel(IV) chloride|1H-naphthalen-1-ide;nickel(2+);triphenylphosphanium;chloride|(naphthalen-1-yl)bis(triphenyl-??-phosphanyl)nickelylium chloride|CHLORO(1-NAPHTHYL)BIS(TRIPHENYLPHOSPHINE)NICKEL(II)|AKOS |
Specifications & Purity | 97% |
Storage Temp | Store at 2-8°C,Argon charged |
Shipped In | Wet ice |
Product Description | Description Nickel Catalyst for Carbon-Nitrogen Coupling |
---|
Names and Identifiers
IUPAC Name | 1H-naphthalen-1-ide;nickel(2+);triphenylphosphanium;chloride |
INCHI | InChI=1S/2C18H15P.C10H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-10-8-4-3-7-9(10)5-1;;/h2*1-15H;1-7H;1H;/q;;-1;;+2/p+1 |
InChi Key | OQTKZOVRPFQUDT-UHFFFAOYSA-O |
Canonical SMILES | C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C2[C-]=CC=CC2=C1.[Cl-].[Ni+2] |
Isomeric SMILES | C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C2[C-]=CC=CC2=C1.[Cl-].[Ni+2] |
WGK Germany | 3 |
PubChem CID | 73554003 |
Molecular Weight | 745.88 |
---|
Chemical and Physical Properties
Safety and Hazards(GHS)
Pictogram(s) | GHS08, GHS07 |
Signal | Danger |
Hazard Statements | H317:May cause an allergic skin reaction H350:May cause cancer |
Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P203:Obtain, read and follow all safety instructions before use. P318:if exposed or concerned, get medical advice. |
WGK Germany | 3 |
---|
References
1. Jin-Hua Huang, Lian-Ming Yang,. (2011-06-22) Nickel-catalyzed amination of aryl phosphates through cleaving aryl C-O bonds.. Organic letters, 13 ((14)): ( 3750-3753 ). [PMID:21688805] |
Solution Calculators
Molarity Calculator
Determine the necessary mass, volume, or concentration for preparing a solution.
Dilution Calculator
Determine the dilution needed to prepare a stock solution.
Reconstitution Calculator