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Chloro(1-naphthyl)bis(triphenylphosphine)nickel(II) - 97%, high purity , CAS No.54806-25-6

  • ≥97%
Item Number
C471297
Grouped product items
SKUSizeAvailabilityPrice Qty
C471297-100mg
100mg
In stock
$54.90
C471297-250mg
250mg
In stock
$100.90
C471297-1g
1g
In stock
$320.90
C471297-5g
5g
In stock
$1,200.90
View related series
Metal catalyst

Basic Description

Synonyms54806-25-6|Naphthalen-1-ylbis(triphenylphosphoranyl)nickel(IV) chloride|1H-naphthalen-1-ide;nickel(2+);triphenylphosphanium;chloride|(naphthalen-1-yl)bis(triphenyl-??-phosphanyl)nickelylium chloride|CHLORO(1-NAPHTHYL)BIS(TRIPHENYLPHOSPHINE)NICKEL(II)|AKOS
Specifications & Purity97%
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

Description

Nickel Catalyst for Carbon-Nitrogen Coupling

Names and Identifiers

IUPAC Name 1H-naphthalen-1-ide;nickel(2+);triphenylphosphanium;chloride
INCHI InChI=1S/2C18H15P.C10H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-10-8-4-3-7-9(10)5-1;;/h2*1-15H;1-7H;1H;/q;;-1;;+2/p+1
InChi Key OQTKZOVRPFQUDT-UHFFFAOYSA-O
Canonical SMILES C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C2[C-]=CC=CC2=C1.[Cl-].[Ni+2]
Isomeric SMILES C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C2[C-]=CC=CC2=C1.[Cl-].[Ni+2]
WGK Germany 3
PubChem CID 73554003
Molecular Weight 745.88

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

8 results found

Lot NumberCertificate TypeDateItem
F2308301Certificate of AnalysisMay 06, 2023 C471297
F2308303Certificate of AnalysisMay 06, 2023 C471297
F2308304Certificate of AnalysisMay 06, 2023 C471297
F2308305Certificate of AnalysisMay 06, 2023 C471297
F2308306Certificate of AnalysisMay 06, 2023 C471297
F2308307Certificate of AnalysisMay 06, 2023 C471297
F2308308Certificate of AnalysisMay 06, 2023 C471297
F2308310Certificate of AnalysisMay 06, 2023 C471297

Chemical and Physical Properties

Melt Point(°C)187-191 °C

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS07
Signal Danger
Hazard Statements

H317:May cause an allergic skin reaction

H350:May cause cancer

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P203:Obtain, read and follow all safety instructions before use.

P318:if exposed or concerned, get medical advice.

WGK Germany 3

Related Documents

References

1. Jin-Hua Huang, Lian-Ming Yang,.  (2011-06-22)  Nickel-catalyzed amination of aryl phosphates through cleaving aryl C-O bonds..  Organic letters,  13  ((14)): ( 3750-3753 ).  [PMID:21688805]

Solution Calculators