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Chloro(dimethyl)phenylsilane - 96%, high purity , CAS No.768-33-2
Basic Description
| Synonyms | CHLORODIMETHYLPHENYLSILANE|768-33-2|chlorodimethyl(phenyl)silane|Phenyldimethylchlorosilane|Silane, chlorodimethylphenyl-|Dimethylphenylchlorosilane|chloro-dimethyl-phenylsilane|Chloro(dimethyl)phenylsilane|DMPSCl|Phenyl dimethylchlorosilane|dimethylpheny |
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| Specifications & Purity | 96% |
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| Storage Temp | Argon charged |
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| Shipped In | Normal |
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| Product Description | Used in a synthesis of enantioenriched allenylsilanes via an ortho-ester Claisen rearrangement of chiral, silylpropargylic alcohols. |
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Names and Identifiers
| IUPAC Name | chloro-dimethyl-phenylsilane |
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| INCHI | InChI=1S/C8H11ClSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7H,1-2H3 |
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| InChi Key | KWYZNESIGBQHJK-UHFFFAOYSA-N |
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| Canonical SMILES | C[Si](C)(C1=CC=CC=C1)Cl |
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| Isomeric SMILES | C[Si](C)(C1=CC=CC=C1)Cl |
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| WGK Germany | 3 |
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| PubChem CID | 13029 |
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| Molecular Weight | 170.71 |
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| Beilstein | 606292 |
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| Reaxy-Rn | 606292 |
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Chemical and Physical Properties
| Solubility | Miscible with tetrahydrofuran, ether and hexane. |
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| Sensitivity | Hygroscopic |
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| Refractive Index | 1.5070 to 1.5100 |
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| Flash Point(°F) | 143.6 °F |
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| Flash Point(°C) | 82°C(Lit.) |
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| Boil Point(°C) | 192-193°C |
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Safety and Hazards(GHS)
| Pictogram(s) | GHS05 |
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| Signal | Danger |
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| Hazard Statements | H314:Causes severe skin burns and eye damage |
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| Precautionary Statements | P280:Wear protective gloves/protective clothing/eye protection/face protection. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. |
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| WGK Germany | 3 |
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| Reaxy-Rn | 606292 |
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