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Chloro(dimethyl)phenylsilane - 98%, high purity , CAS No.768-33-2
Basic Description Synonyms CHLORODIMETHYLPHENYLSILANE|768-33-2|chlorodimethyl(phenyl)silane|Phenyldimethylchlorosilane|Silane, chlorodimethylphenyl-|Dimethylphenylchlorosilane|chloro-dimethyl-phenylsilane|Chloro(dimethyl)phenylsilane|DMPSCl|Phenyl dimethylchlorosilane|dimethylpheny Specifications & Purity 98% Storage Temp Argon charged Product Description Description
Used in a synthesis of enantioenriched allenylsilanes via an ortho-ester Claisen rearrangement of chiral, silylpropargylic alcohols.
Names and Identifiers IUPAC Name chloro-dimethyl-phenylsilane INCHI InChI=1S/C8H11ClSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7H,1-2H3 InChi Key KWYZNESIGBQHJK-UHFFFAOYSA-N Canonical SMILES C[Si](C)(C1=CC=CC=C1)Cl Isomeric SMILES C[Si](C)(C1=CC=CC=C1)Cl WGK Germany 3 PubChem CID 13029 Molecular Weight 170.71 Beilstein 606292 Reaxy-Rn 606292
Chemical and Physical Properties Sensitivity Hygroscopic Refractive Index 1.5070 to 1.5100 Flash Point(°F) 143.6 °F Flash Point(°C) 82°C(Lit.) Boil Point(°C) 192-193°C
Safety and Hazards(GHS) Pictogram(s) GHS05 Signal Danger Hazard Statements H314: Causes severe skin burns and eye damage
Precautionary Statements P280: Wear protective gloves/protective clothing/eye protection/face protection.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P305+P354+P338: IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P302+P361+P354: IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.
P316: Get emergency medical help immediately.
WGK Germany 3 Reaxy-Rn 606292
References 1. Ryan A Brawn, James S Panek,. (2007-06-15) Preparation and use of enantioenriched allenylsilanes for the stereoselective synthesis of homopropargylic ethers.. Organic letters, 9 ((14)): ( 2689-2692 ). [PMID:17559219 ]
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C2309738