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Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) - 98%, high purity , CAS No.1375325-71-5

≥98%

CAS#: 1375325-71-5
Formula: C₂₄H₃₇ClNPPd
Molecular Weight: 512.41
MDL number: MFCD21608496
PubChem CID: 60201440

Item Number

C153833

Grouped product items
SKU	Size	Availability	Price
C153833-250mg	250mg	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$26.90
C153833-1g	1g	In stock	$84.90
C153833-5g	5g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$339.90

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Element classified compounds Palladium catalyst

Basic Description

Synonyms	P(t-Bu)3 Pd G2
Specifications & Purity	98%
Storage Temp	Argon charged
Shipped In	Normal
Product Description	P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides). P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies: . Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides. . Stille cross-couplings reactions of aryl chloride. . Synthesis of chloropeptin I, via Stille cross-coupling reaction. . Heck reaction. . Negishi cross-coupling reactions.

Names and Identifiers

IUPAC Name	chloropalladium(1+);2-phenylaniline;tritert-butylphosphane
INCHI	InChI=1S/C12H10N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9H,13H2;1-9H3;1H;/q-1;;;+2/p-1
InChi Key	DZNFQIYYEXFFGV-UHFFFAOYSA-M
Canonical SMILES	CC(C)(C)P(C(C)(C)C)C(C)(C)C.C1=CC=C([C-]=C1)C2=CC=CC=C2N.Cl[Pd+]
Isomeric SMILES	CC(C)(C)P(C(C)(C)C)C(C)(C)C.C1=CC=C([C-]=C1)C2=CC=CC=C2N.Cl[Pd+]
WGK Germany	3
PubChem CID	60201440
Molecular Weight	512.41
Reaxy-Rn	22750896

Certificates

Certificate of Analysis(COA)

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6 results found

Lot Number	Certificate Type	Date	Item
F2418351	Certificate of Analysis	Jun 12, 2024	C153833
F2418352	Certificate of Analysis	Jun 12, 2024	C153833
F2418353	Certificate of Analysis	Jun 12, 2024	C153833
F2418354	Certificate of Analysis	Jun 12, 2024	C153833
F2418355	Certificate of Analysis	Jun 12, 2024	C153833
F2418356	Certificate of Analysis	Jun 12, 2024	C153833

Sensitivity

Air and moisture sensitive

Melt Point(°C)

167-170°C

Safety and Hazards(GHS)

Pictogram(s)	GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H413:May cause long lasting harmful effects to aquatic life H302:Harmful if swallowed H228:Flammable solid H312:Harmful in contact with skin H332:Harmful if inhaled H290:May be corrosive to metals
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P501:Dispose of contents/container to ... P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P234:Keep only in original container. P390:Absorb spillage to prevent material damage. P406:Store in corrosive resistant/... container with a resistant inner liner. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P317:Get emergency medical help. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help.
WGK Germany	3
Reaxy-Rn	22750896

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