Skip to the beginning of the images gallery

Chloro(triphenylphosphine)gold(I) - 98%, high purity , CAS No.14243-64-2

≥98%

CAS#: 14243-64-2
Formula: [(C₆H₅)₃P]AuCl
Molecular Weight: 495.71
EC Number: 238-117-6
MDL number: MFCD00009588
PubChem CID: 10874691

Item Number

C118793

Grouped product items
SKU	Size	Availability	Price
C118793-100mg	100mg	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$24.90
C118793-250mg	250mg	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$47.90
C118793-1g	1g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$145.90
C118793-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$558.90

Discover Chloro(triphenylphosphine)gold(I) by Aladdin Scientific in 98% for only $24.90. Available - in Ligands at Aladdin Scientific. Tags: Element classified compounds, Transition metal compounds.

View related series

Element classified compounds Transition metal compounds

Basic Description

Synonyms	14243-64-2\|Chloro(triphenylphosphine)gold(I)\|chlorogold;triphenylphosphane\|Chloro(triphenylphosphine)gold\|Triphenylphosphinechlorogold\|MFCD00009588\|Triphenylphosphine gold chloride\|chlorogold; triphenylphosphane\|Chloro(triphenylphosphane)gold(I)\|AuCl(PPh3
Specifications & Purity	98%
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice
Product Description	Chloro(triphenylphosphine)gold(I) is a common reagent in gold chemistry. It catalyzes certain rearrangement reactions in organic synthesis. It is also used to prepare 1-methylthyminato-N3-triphenylphosphinegold(I) by reacting with 1-methylthymine. It acts as a precursor for the synthesis of gold(I) and gold(III) organometallic compounds.

Names and Identifiers

IUPAC Name	chlorogold;triphenylphosphane
INCHI	InChI=1S/C18H15P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1
InChi Key	IFPWCRBNZXUWGC-UHFFFAOYSA-M
Canonical SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Au]
Isomeric SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Au]
WGK Germany	3
PubChem CID	10874691
Molecular Weight	495.71
Reaxy-Rn	14384071

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

5 results found

Lot Number	Certificate Type	Date	Item
F2228153	Certificate of Analysis	Apr 02, 2024	C118793
F2228154	Certificate of Analysis	Apr 02, 2024	C118793
F2228159	Certificate of Analysis	Apr 02, 2024	C118793
H2104044	Certificate of Analysis	May 11, 2023	C118793
H2104050	Certificate of Analysis	May 11, 2023	C118793

Solubility

Soluble in methylene chloride, acetonitrile, benzene and acetone. Insoluble in water and ethanol.

Sensitivity

Light sensitive;Moisture sensitive

Melt Point(°C)

245.0 to 249.0 °C

Safety and Hazards(GHS)

Pictogram(s)	GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell.
WGK Germany	3
Reaxy-Rn	14384071

References

1. Jihan Talib,Jennifer L Beck,Stephen F Ralph. (2006-06-23) A mass spectrometric investigation of the binding of gold antiarthritic agents and the metabolite [Au(CN)2]- to human serum albumin.. Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 11 ((5)): (559-570). [PMID:16791640]
2. Gregory L Hamilton,Eun Joo Kang,Miriam Mba,F Dean Toste. (2007-07-28) A powerful chiral counterion strategy for asymmetric transition metal catalysis.. Science (New York, N.Y.), 317 ((5837)): (496-499). [PMID:17656720]
3. Xia Zhao,Zhenzhen Zhong,Lingling Peng,Wenxiong Zhang,Jianbo Wang. (2009-06-18) Au(PPh(3))Cl-AgSbF(6)-catalyzed rearrangement of propargylic 1,3-dithianes: formation of 8-membered 1,3-bisthio-substituted cyclic allenes.. Chemical communications (Cambridge, England), ((18)(18)): (2535-2537). [PMID:19532881]
4. Ming Zhang,Ablimit Abdukader,Yong Fu,Chengjian Zhu. (2012-03-08) Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions.. Molecules (Basel, Switzerland), 17 ((3)): (2812-2822). [PMID:22395409]
5. Simbarashe Ngwerume,William Lewis,Jason E Camp. (2012-12-29) Development of a gold-multifaceted catalysis approach to the synthesis of highly substituted pyrroles: mechanistic insights via Huisgen cycloaddition studies.. The Journal of organic chemistry, 78 ((3)): (920-934). [PMID:23270303]
6. Katherine A Parrish,Mary King,Marshall R Ligare,Grant E Johnson,Heriberto Hernández. (2018-09-28) Role of sterics in phosphine-ligated gold clusters.. Physical chemistry chemical physics : PCCP, 21 ((4)): (1689-1699). [PMID:30260357]
7. Luiza G Tunes,Roberta E Morato,Adriana Garcia,Vinicius Schmitz,Mario Steindel,José D Corrêa-Junior,Hélio F Dos Santos,Frédéric Frézard,Mauro V de Almeida,Heveline Silva,Nilmar S Moretti,André L B de Barros,Rubens L do Monte-Neto. (2020-04-15) Preclinical Gold Complexes as Oral Drug Candidates to Treat Leishmaniasis Are Potent Trypanothione Reductase Inhibitors.. ACS infectious diseases, 6 ((5)): (1121-1139). [PMID:32283915]
8. Sang Ick Lee,Soo Min Kim,Mi Ra Choi,Sun Young Kim,Young Keun Chung,Won-Sik Han,Sang Ook Kang. (2006-12-02) Au(I)-catalyzed cyclization of enynes bearing an olefinic cycle.. The Journal of organic chemistry, 71 ((25)): (9366-9372). [PMID:17137363]
9. Elena Barreiro,José S Casas,María D Couce,Agustín Sánchez,Angeles Sánchez-Gonzalez,José Sordo,José M Varela,Ezequiel M Vázquez López. (2007-09-18) Synthesis, structure and cytotoxicity of triphenylphosphinegold(I) sulfanylpropenoates.. Journal of inorganic biochemistry, 102 ((2)): (184-192). [PMID:17870173]

Solution Calculators

Molarity Calculator

Determine the necessary mass, volume, or concentration for preparing a solution.

Dilution Calculator

Determine the dilution needed to prepare a stock solution.