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Chlorobis(cyclooctene)rhodium(I),dimer - 98%, high purity , CAS No.12279-09-3

≥98%

CAS#: 12279-09-3
Formula: C₃₂H₅₆Cl₂Rh₂
Molecular Weight: 717.5
MDL number: MFCD00013287
PubChem CID: 53384308

Item Number

C118535

Grouped product items
SKU	Size	Availability	Price
C118535-100mg	100mg	In stock	$58.90
C118535-500mg	500mg	In stock	$178.90
C118535-1g	1g	In stock	$321.90

Discover Chlorobis(cyclooctene)rhodium(I),dimer by Aladdin Scientific in 98% for only $58.90. Available - in Ligands at Aladdin Scientific. Tags: Element classified compounds, Transition metal compounds.

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Element classified compounds Transition metal compounds

Basic Description

Synonyms	cyclooctene;rhodium;dichloride \| Chlorobis(cyclooctene)rhodium(I) Dimer \| C2253 \| AMY19666 \| MFCD00013287
Specifications & Purity	98%
Storage Temp	Store at -20°C
Shipped In	Ice chest + Ice pads
Product Description	Precusor for rhodium(I) and used as a precatalyst in a variety of reactions including aryl- and vinyl-C-H bond activation, hydroiminoacylation, cycloisomerization, and C-C bond activation

Names and Identifiers

IUPAC Name	cyclooctene;rhodium;dichloride
INCHI	InChI=1S/4C8H14.2ClH.2Rh/c41-2-4-6-8-7-5-3-1;;;;/h41-2H,3-8H2;21H;;/p-2/b42-1-;;;;
InChi Key	ZFCBAJWXKUDJSW-XFCUKONHSA-L
Canonical SMILES	C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1.[Cl-].[Cl-].[Rh].[Rh]
Isomeric SMILES	C1CC/C=C\CCC1.C1CC/C=C\CCC1.C1CC/C=C\CCC1.C1CC/C=C\CCC1.[Cl-].[Cl-].[Rh].[Rh]
WGK Germany	3
PubChem CID	53384308
Molecular Weight	717.5
Reaxy-Rn	16520626

Certificates

Certificate of Analysis(COA)

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Find and download the COA for your product by matching the lot number on the packaging.

12 results found

Lot Number	Certificate Type	Date	Item
G2201224	Certificate of Analysis	Apr 03, 2024	C118535
G2201225	Certificate of Analysis	Apr 03, 2024	C118535
G2201226	Certificate of Analysis	Apr 03, 2024	C118535
K2120181	Certificate of Analysis	Aug 15, 2023	C118535
H2314048	Certificate of Analysis	Nov 26, 2022	C118535
H2314051	Certificate of Analysis	Nov 26, 2022	C118535
H2314053	Certificate of Analysis	Nov 26, 2022	C118535
H2314063	Certificate of Analysis	Nov 26, 2022	C118535
H2314065	Certificate of Analysis	Nov 26, 2022	C118535
H2314066	Certificate of Analysis	Nov 26, 2022	C118535
B1414064	Certificate of Analysis	Nov 14, 2022	C118535
I1425062	Certificate of Analysis	May 07, 2022	C118535

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Sensitivity

Air Sensitive,Heat Sensitive

Melt Point(°C)

190°C

Safety and Hazards(GHS)

Pictogram(s)	GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H302:Harmful if swallowed H312:Harmful in contact with skin H332:Harmful if inhaled
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P317:Get emergency medical help. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell.
WGK Germany	3
Reaxy-Rn	16520626

References

1. K L Tan,R G Bergman,J A Ellman. (2001-07-18) Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions.. Journal of the American Chemical Society, 123 ((11)): (2685-2686). [PMID:11456947]
2. Jay A Labinger,John E Bercaw. (2002-05-31) Understanding and exploiting C-H bond activation.. Nature, 417 ((6888)): (507-514). [PMID:12037558]
3. Fumitoshi Kakiuchi,Shinji Murai. (2002-10-16) Catalytic C-h/olefin coupling.. Accounts of chemical research, 35 ((10)): (826-834). [PMID:12379135]
4. Vincent Ritleng,Claude Sirlin,Michel Pfeffer. (2002-05-09) Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H activation and addition on unsaturated substrates: reactions and mechanistic aspects.. Chemical reviews, 102 ((5)): (1731-1770). [PMID:11996548]

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