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Chromium(0) hexacarbonyl - 99%, high purity , CAS No.13007-92-6
Basic Description Synonyms CHROMIUM CARBONYL|13007-92-6|Chromium(0) hexacarbonyl|carbon monoxide;chromium|Chromium carbonyl (Cr(CO)6)|CHROMIUM CARBONYL [MI]|920F3EJX2P|DTXSID6024830|Chromium(0) hexacarbonyl, 98%|AKOS015903778|hexakis(methanidylidyneoxidanium) chromium|CS-0111881|FT Specifications & Purity 99% Shipped In Normal Product Description Precursor to a prenylatedcarbene complex which promotes a net [5+5] cycloaddition of alkynylbenzaldehydes to give phenanthrenes.
Names and Identifiers Pubchem Sid 488182970 Pubchem Sid Url https://pubchem.ncbi.nlm.nih.gov/substance/488182970 IUPAC Name carbon monoxide;chromium INCHI InChI=1S/6CO.Cr/c6*1-2; InChi Key KOTQLLUQLXWWDK-UHFFFAOYSA-N Canonical SMILES [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Cr] Isomeric SMILES [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Cr] WGK Germany 3 RTECS GB5075000 PubChem CID 25589 UN Number 3281 Packing Group I Molecular Weight 220.06
Chemical and Physical Properties Solubility Soluble in ether, chloroform, tetrahydropyran and methylene chloride. Insoluble in water Sensitivity Light and HeatSensitive Boil Point(°C) 220°C Melt Point(°C) 150°C
Safety and Hazards(GHS) Pictogram(s) GHS06 Signal Danger Hazard Statements H301: Toxic if swallowed
H331: Toxic if inhaled
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P270: Do not eat, drink or smoke when using this product.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P330: Rinse mouth.
P301+P316: IF SWALLOWED: Get emergency medical help immediately.
P316: Get emergency medical help immediately.
WGK Germany 3 RTECS GB5075000 Class 6.1
References 1. Suneetha Menon, Dilip Sinha-Mahapatra, James W Herndon,. (2008-09-05) Synthesis of phenanthrene derivatives through the net [5+5]-cycloaddition of prenylated carbene complexes with 2-alkynylbenzaldehyde derivatives.. Tetrahedron, 63 ((36)): ( 8788-8793 ). [PMID:18769535 ]
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