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Cobalt(II) acetate tetrahydrate - reagent grade, high purity , CAS No.6147-53-1

  • 试剂级
Item Number
C433113
Grouped product items
SKUSizeAvailabilityPrice Qty
C433113-50g
50g
In stock
$59.90
C433113-250g
250g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$89.90
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Salt

Basic Description

SynonymsCobalt(II) acetate tetrahydrate|6147-53-1|Cobaltous acetate tetrahydrate|Cobalt acetate tetrahydrate|Cobalt diacetate tetrahydrate|cobalt (II) acetate tetrahydrate|cobalt(2+);diacetate;tetrahydrate|Cobalt( cento) acetate tetrahydrate|7648Z91O1N|Octan koba
Specifications & PurityReagent grade
Grade试剂级
Product Description

Cobalt(II) acetate tetrahydrate, commonly used as bleach and drying agent, can be produced by reacting cobalt (II) carbonate and acetic acid. It undergoes decomposition on heating up to 500°C under non-isothermal conditions. Its crystals exhibit monoclinic crystal system having space group P 2 1 / c . Cobalt(II) acetate tetrahydrate undergoes hydrothermal reaction with 1,3,5-benzenetricarboxylic acid (BTCH 3 ) to afford Co 3 (BTC) 2 .12H 2 O.


Application

Cobalt(II) acetate tetrahydrate may be used in the preparation of [Co 3 (OH) 2 (H 2 O) 2 (aptet) 4 ] (aptet = 4-aminophenyltetrazolate) and new tetradentate cobalt(II)-Schiff base complex. Cobalt(II) acetate tetrahydrate may be used as a cobalt source in the synthesis of cobalt nanoparticles and cobalt oxide thin films. It may also be used to prepare cobalt(II)-aminophenyltetrazolate coordination polymer and tricobalt complexes with mixed μ-acetato and μ-pyrazolato ligands. Cobalt(II) acetate tetrahydrate enhances the reaction rate of oxidation of 1,4-dihydropyridines using hydrogen peroxide to the corresponding pyridine derivatives.

Names and Identifiers

IUPAC Name cobalt(2+);diacetate;tetrahydrate
INCHI InChI=1S/2C2H4O2.Co.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2
InChi Key ZBYYWKJVSFHYJL-UHFFFAOYSA-L
Canonical SMILES CC(=O)[O-].CC(=O)[O-].O.O.O.O.[Co+2]
Isomeric SMILES CC(=O)[O-].CC(=O)[O-].O.O.O.O.[Co+2]
WGK Germany 2
RTECS AG3325000
PubChem CID 61372
UN Number 3077
Packing Group III
Molecular Weight 249.08
Beilstein 3731397

Certificates

Certificate of Analysis(COA)

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2 results found

Lot NumberCertificate TypeDateItem
G2328068Certificate of AnalysisAug 10, 2023 C433113
G2328065Certificate of AnalysisAug 04, 2023 C433113

Chemical and Physical Properties

SensitivityMoisture sensitive

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS09,   GHS07
Signal Danger
Hazard Statements

H341:Suspected of causing genetic defects

H317:May cause an allergic skin reaction

H334:May cause allergy or asthma symptoms or breathing difficulties if inhaled

H400:Very toxic to aquatic life

H410:Very toxic to aquatic life with long lasting effects

H360:May damage fertility or the unborn child

H350:May cause cancer

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P284:[In case of inadequate ventilation] Wear respiratory protection.

P281:Use personal protective equipment as required.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P203:Obtain, read and follow all safety instructions before use.

P318:if exposed or concerned, get medical advice.

P342+P316:If experiencing respiratory symptoms: Get emergence medical help immediately.

WGK Germany 2
RTECS AG3325000
Class 9
RIDADR UN 3077 9 / PGIII

Related Documents

References

1. Tiffany M Smith,Michael Tichenor,Yuan-Zhu Zhang,Kim R Dunbar,Jon Zubieta.  (2014-04-01)  Hydrothermal synthesis, structure and magnetic properties of a three-dimensional cobalt(II) - aminophenyltetrazolate coordination polymer..  Dalton transactions (Cambridge, England : 2003),  43  ((19)): (7263-7268).  [PMID:24681873]
2. Vijayan Thamilarasan,Arumugam Jayamani,Nallathambi Sengottuvelan.  (2014-12-03)  Synthesis, molecular structure, biological properties and molecular docking studies on Mn(II), Co(II) and Zn(II) complexes containing bipyridine-azide ligands..  European journal of medicinal chemistry,  89  (266-278).  [PMID:25462243]
3. Kyu-Nam Jung,Soo Min Hwang,Min-Sik Park,Ki Jae Kim,Jae-Geun Kim,Shi Xue Dou,Jung Ho Kim,Jong-Won Lee.  (2015-01-08)  One-dimensional manganese-cobalt oxide nanofibres as bi-functional cathode catalysts for rechargeable metal-air batteries..  Scientific reports,  (7665-7665).  [PMID:25563733]

Solution Calculators