Serotonin receptor affinities of psychoactive phenalkylamine analogues.

Basic Information

ID: ALA1121407

Journal: J Med Chem

Title: Serotonin receptor affinities of psychoactive phenalkylamine analogues.

Authors: Glennon RA, Liebowitz SM, Anderson GM.

Abstract: Employing a rat fundus model, the serotonin (5-HT) receptor affinities of 45 phenalkylamine analogues were determined. Phenethylamine and phenylisopropylamine possess relatively low receptor affinities; in general, mono-, di-, and trimethoxylation enhance affinity. Of the disubstituted compounds, methoxyl groups at the 2 and 5 positions are optimal for imparting a high affinity. 4-Methylation, 4-ethylation and 4-bromination also enhance receptor affinity, while N,N-dimethylation of the terminal amine decreases affinity. alpha-Methylation of phenethylamines has little effect on affinity when racemates are examined. Introduction of a benzylic keto group can either increase or decrease affinity, depending upon the presence of other aromatic substituents. The most behaviorally active compounds were found to possess the highest 5-HT receptor affinities, while less active compounds were found to possess lower affinities.

CiteXplore: 7365744

DOI: 10.1021/jm00177a017

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