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ID: ALA1146997

Journal: Bioorg Med Chem Lett

Title: Synthesis of phospholipase A2 inhibitory biflavonoids.

Authors: Chen J, Chang HW, Kim HP, Park H.

Abstract: A series of C-C biflavones was designed to investigate the relationship between structural array of different flavone-flavone subunit linkage and the inhibitory activity against phospholipase A2 (PLA2). Among six classes of C-C biflavones designed, four classes of C-C biflavones, which have flavone-flavone subunit linkages at A ring-A ring, A ring-B ring, B ring-B ring, and B ring-C ring, were synthesized. The synthetic biflavones exhibited somewhat different inhibitory activities against sPLA2-IIA. Among them, the biflavone a having a C-C 4'-4' linkage showed comparable inhibitory activity with that of the natural biflavonoid, ochnaflavone, and 7-fold stronger activity than that of amentoflavone. Further chemical modification is being carried out in order to obtain the chemically optimized biflavonoids.

CiteXplore: 16504502

DOI: 10.1016/j.bmcl.2006.01.117